n-Butylboronic acid 正丁基硼酸

CAS 4426-47-5 MFCD00002106

化学结构图

4426-47-5
SMILES: CCCCB(O)O

化学属性

Mol. FormulaC4H11BO2
Mol. Weight101.94
Melting Point90-92°C
TSCANo
SolubilityCA 2.5 G/100 ML
Density0.914
Stability对空气敏感,易吸潮
Boiling Point189.2°C at 760 mmHg
Flash Point68.2°C

别名和识别编码

Chemical Namen-Butylboronic acid
CAS Number4426-47-5
Alfabeta NameBUTYLBORONICACID 1-
MDL NumberMFCD00002106
Reaxys-RN1733489
PubChem Substance ID87563550
Synonym Butylboronic acid {LY} Butylboronic acid {} {LY} Butylboronic acid {} {} {LY} Butylboronic acid {} {} {} {LY} Butylboronic acid {} {} {} {} {LY} Butylboronic acid {} {} {} {} {} {LY} Butylboronic acid {} {} {} {} {} {} {LY} Butylboronic acid {} {} {} {} {} {} {} {LY} Butylboronic acid {} {} {} {} {} {} {} {} {LY} Butylboronic acid {} {} {} {} {} {} {} {} {} {LY} Butylboronic acid {} {} {} {} {} {} {} {} {} {} {LY} Butylboronic acid {} {} {} {} {} {} {} {} {} {} {} {LY} Butylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} Butylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Butylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Butylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Butylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Butylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Butyl
EC Number224-607-7
Beilstein Registry Number1733489
Chemical Name Translation正丁基硼酸
InChIKeyQPKFVRWIISEVCW-UHFFFAOYSA-N
LabNetwork Molecule IDLN00138859
InChIInChI=1S/C4H11BO2/c1-2-3-4-5(6)7/h6-7H,2-4H2,1H3
Canonical SMILESCCCCB(O)O
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分类

  • {SNA} Alkyl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents
  • {SNA} Acylation Reagents, Analytical Reagents, Analytical/Chromatography, Derivatization Reagents, Derivatization Reagents GC, Reagents for Acylation
  • {SA} Alkyl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents

相关文献及参考

  • Beilstein: 4,IV,4383
  • In combination with (S)-(-)-ɑ,ɑ-Diphenyl­prolinol, L09217, or its enantiomer (9218), oxazaborolidine catalysts are generated in situ, for use in highly enantioselective reductions: Tetrahedron Lett., 33, 4141 (1992). The same system has been employed in the synthesis of chiral monosubstituted oxiranes: Tetrahedron Lett., 34, 5227 (1993). See also (S)-2-Methyl-CBS-oxazaborolidine monohydrate, L09219, and Appendix 5.
  • Reagent for preparation of volatile derivatives of diols, e.g. carbohydrates, for GC and mass spectrometry: J. Chromat., 54, 193 (1971); J. Chromat. Sci., 9, 18 (1971); Gas Chromat., 129 (1968).

安全信息

Warnings IRRITANT
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition -20°C {LY} -20°C 0-6°C Air Sensitive & Hygroscopic {} {LY} -20°C {} {} {LY} -20°C {} {} {} {LY} -20°C {} {} {} {} {LY} -20°C {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Hazard Codes Xi
GHS Symbol

其他信息

  • 图谱信息:正丁基硼酸(4426-47-5)红外图谱(IR1) 正丁基硼酸(4426-47-5)红外图谱(IR2)
  • 正丁基硼酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0529 丁基硼酸(含有数量不等的酸酐)[用于酯化] Butylboronic Acid (contains varying amounts of Anhydride) [for Esterification] 1G 630元 2014/06/02 B0529 丁基硼酸(含有数量不等的酸酐)[用于酯化] Butylboronic Acid (contains varying amounts of Anhydride) [for Esterification] 25G 5010元 2014/06/02 B0529 丁基硼酸(含有数量不等的酸酐)[用于酯化] Butylboronic Acid (contains varying amounts of Anhydride) [for Esterification] 5G 1740元
  • Acros Organics:丁基硼酸 n-Butylboronic acid, 98%(4426-47-5)
  • MOL 文件:4426-47-5.mol
  • Alfa Aesar:正丁基硼酸,98% 1-Butylboronic acid, 98%(4426-47-5)
  • 敏感性:Air Sensitive & Hygroscopic
  • Sigma Aldrich:4426-47-5(sigmaaldrich)
  • F:3-10-23
  • TCI Shanghai:正丁基硼酸(含有数量不等的酸酐)[用于酯化] Butylboronic Acid (contains varying amounts of Anhydride) [for Esterification](4426-47-5)
  • MSDS 信息:n-Butylboronic acid(4426-47-5).msds

系列性分类


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