2-Isonitrosopropiophenone 2-异亚硝基苯丙酮

CAS 119-51-7 MFCD00002115

化学结构图

119-51-7
SMILES: C/C(=N\O)C(=O)c1ccccc1

化学属性

Mol. FormulaC9H9NO2
Mol. Weight163.17
Melting Point113-115 °C
Density1.422
Boiling Point290.25 °C at 760 mmHg

别名和识别编码

Chemical Name2-Isonitrosopropiophenone
Synonym 2-(Hydroxyimino)-1-phenylpropan-1-one {LY} 2-(Hydroxyimino)-1-phenylpropan-1-one {} {LY} 2-(Hydroxyimino)-1-phenylpropan-1-one {} {} {LY} 2-(Hydroxyimino)-1-phenylpropan-1-one {} {} {} {LY} 2-(Hydroxyimino)-1-phenylpropan-1-one {} {} {} {} {LY} 2-(Hydroxyimino)-1-phenylpropan-1-one {} {} {} {} {} {LY} 2-(Hydroxyimino)-1-phenylpropan-1-one {} {} {} {} {} {} {LY} 2-(Hydroxyimino)-1-phenylpropan-1-one {} {} {} {} {} {} {} {LY} 2-(Hydroxyimino)-1-phenylpropan-1-one {} {} {} {} {} {} {} {} {LY} 2-(Hydroxyimino)-1-phenylpropan-1-one {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} 2-(Hydroxyimino)-1-phenylpropan-1-one {} {} {} {} {} {} {} {} {} {} {LY} 2-(Hydroxyimino)-1-phenylpropan-1-one {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Hydroxyimino)-1-phenylpropan-1-one {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Hydroxyimino)-1-phenylpropan-1-one {} {} {}
MDL NumberMFCD00002115
PubChem Substance ID87574457
CAS Number119-51-7
EC Number204-329-2
Beilstein Registry Number509304
Reaxys-RN509304
Chemical Name Translation2-异亚硝基苯丙酮
Wiswesser Line NotationQNUY1&VR
InChIKeyYPINLRNGSGGJJT-JXMROGBWSA-N
Canonical SMILESCC(=NO)C(=O)C1=CC=CC=C1
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Oximes
  • Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Oximes

相关文献及参考

  • 1. E. Baranoff, et al., , Cyclometalated Iridium(III) Complexes Based on Phenyl-Imidazole Ligand Inorg. Chem. 50 , 451-462, (2011)
  • 2. M. Jasinski, et al., , Synthesis of 2,3-dihydroimidazo[2,1-b]thiazole derivatives via cyclization of N-allylimidazoline-2-thiones J. Heterocycl. Chem. 47 , 1287-1293, (2010)
  • 3. M. Bakherad, et al., , Copper- and solvent-free Sonogashira coupling reactions of aryl halides with terminal alkynes catalyzed by 1-phenyl-1,2-propanedione-2-oxime thiosemicarbazone-functionalized polystyrene resin supported Pd(II) complex under aerobic conditions Appl. Catal. 390 , 135-140, (2010)
  • 4. P. Kwiatkowski, et al., , Novel chiral C2-symmetric bisimidazole-N-oxides as promising organocatalysts for enantioselective allylation of aromatic aldehydes Synlett 11 , 1757-1760, (2009)
  • 5. B. N. H. Kumar, et al., , Beckmann rearrangement of a-oximinoketones Indian J. Chem. B 47B , 963-965, (2008)
  • 6. L. A. Holowatz, et al., , Oral atorvastatin therapy restores cutaneous microvascular function by decreasing arginase activity in hypercholesterolaemic humans J. Physiol. 589 , 2093-2103, (2011)
  • Beil. 7 ,III,3464
  • FT-IR 2 (3), 4008:D / FT-IR 1 (2), 924:D / FT-NMR 1 (3), 491:C / IR-Spectra (3), 1428:G / NMR-Reference 2 (2), 972:D / RegBook 1 (2), 2689:F / Sigma FT-IR 1 (2), 668:D / Structure Index 1 , 423:D:5

安全信息

WGK Germany2
RTECSUH2975000
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word Warning
Hazard statements
  • H303 May be harmfully swallowed 吞食可能有害
Precautionary statements
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
GHS Symbol
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Hazard Codes Xn
Storage condition 2-8°C, sealed storage, away from moisture {LY} 2-8°C, sealed storage, away from moisture {} {LY} 2-8°C, sealed storage, away from moisture {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >4 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   28,313,1974

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4240 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   28,313,1974

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD691-490

其他信息

  • 2-异亚硝基苯丙酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0211 2-异亚硝基苯丙酮 2-Isonitrosopropiophenone 25G 644元 2010/06/21 205020250 2-异亚硝基苯丙酮 1-Phenyl-1,2-propanedione-2-oxime 99% 25 GR 720元 2010/06/21 205020100 2-异亚硝基苯丙酮 1-Phenyl-1,2-propanedione-2-oxime 99% 10 GR 408元
  • Acros Organics:1-苯基-1,2-丙二酮-2-肟 1-Phenyl-1,2-propanedione-2-oxime, 99%(119-51-7)
  • MSDS 信息:1-Phenyl-1,2-propanedione-2-oxime(119-51-7).msds
  • MOL 文件:119-51-7.mol
  • 图谱信息:2-异亚硝基苯丙酮(119-51-7)质谱(MS) 2-异亚硝基苯丙酮(119-51-7)核磁图( 1 HNMR) 2-异亚硝基苯丙酮(119-51-7)Raman光谱 2-异亚硝基苯丙酮(119-51-7)核磁图( 13 CNMR) 2-异亚硝基苯丙酮(119-51-7)红外图谱(IR2) 2-异亚硝基苯丙酮(119-51-7)红外图谱(IR1)
  • TCI Shanghai:1-苯基-1,2-丙二酮肟 2-Isonitrosopropiophenone,>;98.0%(GC)(119-51-7)
  • Sigma Aldrich:119-51-7(sigmaaldrich)
  • 海关编码:29280090

系列性分类


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