2-Isonitrosoacetophenone 2-异亚硝基苯乙酮

CAS 532-54-7 MFCD00002122

化学结构图

532-54-7
SMILES: O=C(/C=N/O)c1ccccc1

化学属性

Mol. FormulaC8H7NO2
Mol. Weight149.15
Melting Point123-125 °C
TSCAYes
Solubility可溶 IN COLD WATER
Boiling Point305.728 °C at 760 mmHg

别名和识别编码

Chemical Name2-Isonitrosoacetophenone
Synonym 2-Oxo-2-phenylacetaldehyde oxime {LY} 2-Oxo-2-phenylacetaldehyde oxime {} {LY} 2-Oxo-2-phenylacetaldehyde oxime {} {} {LY} 2-Oxo-2-phenylacetaldehyde oxime {} {} {} {LY} 2-Oxo-2-phenylacetaldehyde oxime {} {} {} {} {LY} 2-Oxo-2-phenylacetaldehyde oxime {} {} {} {} {} {LY} 2-Oxo-2-phenylacetaldehyde oxime {} {} {} {} {} {} {LY} 2-Oxo-2-phenylacetaldehyde oxime {} {} {} {} {} {} {} {LY} 2-Oxo-2-phenylacetaldehyde oxime {} {} {} {} {} {} {} {} {LY} 2-Oxo-2-phenylacetaldehyde oxime {} {} {} {} {} {} {} {} {} {LY} 2-Oxo-2-phenylacetaldehyde oxime {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} 2-Oxo-2-phenylacetaldehyde oxime {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Oxo-2-phenylacetaldehyde oxime {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Oxo-2-phenylacetaldehyde oxime {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Oxo-2-phenylacetaldehyde oxime {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Oxo-2-phenylacetaldehyde
Beilstein Registry Number2041691
PubChem Substance ID24895950
CAS Number532-54-7
EC Number208-539-5
MDL NumberMFCD00002122
Reaxys-RN2412106
Merck Number5191
Chemical Name Translation2-异亚硝基苯乙酮
InChIKeyMLNKXLRYCLKJSS-RMKNXTFCSA-N
Wiswesser Line NotationQNU1VR
Canonical SMILESO=C(/C=N/O)C1=CC=CC=C1
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分类

  • {SA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Oximes
  • {SNA} Analytical Reagents, Analytical/Chromatography, Spectroscopy, UV/Vis Reagents, UV/Visible (UV/VIS) Spectroscopy
  • Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks,

相关文献及参考

  • Merck 14 ,5191
  • Beil. 7 ,IV,2132
  • Aldrich MSDS 1 , 1114:D / Corp MSDS 1 (1), 2027:A / FT-IR 1 (2), 924:C / FT-IR 2 (3), 4008:C / IR-Spectra (2), 1246:B / IR-Spectra (3), 1428:F / NMR-Reference 2 (2), 972:C / RegBook 1 (2), 2689:E / Sax 6 , 1644 / Structure Index 1 , 423:C:5

安全信息

Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P332+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P301+P312+P330
  • P302+P350
  • P337+P313
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P312+P362+P364
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P304+P340+P312
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P305+P351+P338+P337+P313
  • P305+P351+P338
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
WGK Germany3
GHS Symbol
Signal word Warning
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H302+H312+H332
Hazard Codes Xn Xn,Xi Xi
RTECSMD3325000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
UN Number 2811
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NCNSA6 National Academy of Sciences, National Research Council,
   Chemical-Biological Coordination Center, Review.  (Washington, DC)
   Volume(issue)/page/year: 5,27,1953

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 75 mg/kg
TOXIC EFFECTS :
   Behavioral - coma
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 119,522,1957

其他信息

  • TCI Shanghai:异亚硝基苯乙酮 Isonitrosoacetophenone,>;98.0%(LC)(T)(532-54-7)
  • 图谱信息:2-异亚硝基苯乙酮(532-54-7)核磁图( 13 CNMR) 2-异亚硝基苯乙酮(532-54-7)质谱(MS) 2-异亚硝基苯乙酮(532-54-7)红外图谱(IR2) 2-异亚硝基苯乙酮(532-54-7)红外图谱(IR1)
  • Sigma Aldrich:532-54-7(sigmaaldrich)
  • Alfa Aesar:异亚硝基苯乙酮,97% Isonitrosoacetophenone, 97%(532-54-7)
  • 2-异亚硝基苯乙酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0181 异亚硝基苯乙酮 Isonitrosoacetophenone 10G 980元 2010/05/25 L02098 异亚硝基苯乙酮, 97% Isonitrosoacetophenone, 97% 50g 2352元 2010/05/25 L02098 异亚硝基苯乙酮, 97% Isonitrosoacetophenone, 97% 10g 588元
  • MOL 文件:532-54-7.mol
  • MSDS 信息:2-Isonitrosoacetophenone(532-54-7).msds

系列性分类


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