N,N-Diethylhydroxylamine N,N-二乙基羟胺

CAS 3710-84-7 MFCD00002126

化学结构图

3710-84-7
SMILES: CCN(O)CC

化学属性

Mol. FormulaC4H11NO
Mol. Weight89.14
Refractive index1.4170 to 1.4220
Boiling Point125-130 °C at 760 mmHg
Density0.867
Melting Point-26--25 °C
Vapor Density3.07 (vs air)
Vapor Pressure4 mmHg ( 0 °C)
Flash Point45°C(lit.)
TSCAYes
Solubility可溶
Appearance 无色透明液体。有氨味。 易溶于水，溶于乙醇、乙醚、氯仿、苯。
Stability易吸潮

别名和识别编码

Chemical NameN,N-Diethylhydroxylamine
Synonym N,N-Diethylhydroxylamine {LY} N,N-Diethylhydroxylamine {} {LY} N,N-Diethylhydroxylamine {} {} {LY} N,N-Diethylhydroxylamine {} {} {} {LY} N,N-Diethylhydroxylamine {} {} {} {} {LY} N,N-Diethylhydroxylamine {} {} {} {} {} {LY} N,N-Diethylhydroxylamine {} {} {} {} {} {} {LY} N,N-Diethylhydroxylamine {} {} {} {} {} {} {} {LY} N,N-Diethylhydroxylamine {} {} {} {} {} {} {} {} {LY} N,N-Diethylhydroxylamine {} {} {} {} {} {} {} {} {} {LY} N,N-Diethylhydroxylamine {} {} {} {} {} {} {} {} {} {} {LY} N,N-Diethylhydroxylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-Diethylhydroxylamine {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-Diethylhydroxylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-Diethylhydroxylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-Diethylhydroxylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-Diethylhydroxylamine {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00002126
CAS Number3710-84-7
PubChem Substance ID19463
EC Number223-055-4
Beilstein Registry Number1731349
Reaxys-RN1731349
Chemical Name TranslationN,N-二乙基羟胺
Wiswesser Line NotationQN2&2
LabNetwork Molecule IDLN00222545
Canonical SMILESON(CC)CC
InChIInChI=1S/C4H11NO/c1-3-5(6)4-2/h6H,3-4H2,1-2H3
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分类

  • {uni_hamburg} no charge; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Hydroxylamines, Nitrogen Compounds, Organic Building Blocks

产品应用

  • 1、 做为乙烯基单体，用于共轭烯烃的高效阻聚剂。
  • 2、 在液相或气相中对已有端聚种子的情况下，可作为高效端聚抑制剂。
  • 3、 是丁苯乳聚过程的非常优异的终止剂。
  • 4、是不饱和油类及树脂的抗氧化剂。
  • 5、 是光敏树脂、感光乳剂、合成树脂的良好稳定剂。
  • 6、在环境保护中是良好的光化学烟雾抑制剂。
  • 7、是锅炉给水和蒸汽换热设备的缓蚀剂。

相关文献及参考

  • Beilstein: 4,IV,3304
  • Short: EINECS
  • Short: III/35E
  • Reagent for selective reduction of quinones to hydroquinones: Tetrahedron Lett., 1695 (1975).
  • Perfluoroalkenes undergo a novel epoxidation with the reagent at room temperature: Chem. Commun., 763 (1996).

安全信息

GHS Symbol
WGK Germany1
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H312+H332
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSNC3500000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P302+P352
  • P302+P352+P312+P362+P364
  • P303+P361+P353
  • P304+P312
  • P304+P340
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P308+P311
  • P308+P316
  • P309+P311
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P317
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Packing GroupIII
UN Number 1993
Risk Statements
  • R10 Flammable 易燃
  • R20/21 Harmful by inhalation and in contact with skin 吸入及与皮肤接触有害
  • R21 Harmful in contact with skin 与皮肤接触有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R38 Irritating to skin 刺激皮肤
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R53 May cause long-term adverse effects in the aquatic environment 对水生环境有长期的有害作用
  • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Storage condition 2-8°C, sealed storage, away from moisture {LY} 2-8°C, sealed storage, away from moisture Flammables area Hygroscopic {} {LY} 2-8°C, sealed storage, away from moisture {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {} {L
Hazard Codes 3
Hazard Class3 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 100 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   KODAK* Kodak Company Reports.  (343 State St., Rochester, NY 14650)
   Volume(issue)/page/year: 21MAY1971

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1750 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,217,1969

TYPE OF TEST            : LD80 - Lethal Dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2150 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   34ZIAG "T

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   KODAK* Kodak Company Reports.  (343 State St., Rochester, NY 14650)
   Volume(issue)/page/year: 21MAY1971

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   KODAK* Kodak Company Reports.  (343 State St., Rochester, NY 14650)
   Volume(issue)/page/year: 21MAY1971

TYPE OF TES

TYPE OF TEST            : Dominant lethal test
ROUTE OF EXPOSURE       : Parenteral
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 180 mg/kg
REFERENCE :
   CAES** Reports Supported by the Pennwalt Corp. and the Center for Air
   Environment Studies at the Pennsylvania State University
   Volume(issue)/page/year: 492-78,1978

TYPE OF TEST            : Sex chromosome loss and nondisjunction
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 200 ppm
REFERENCE :
   CAES** Reports Supported by the Pennwalt Corp. and the Center for Air
   Environment Studies at the Pennsylvania State University
   Volume(issue)/page/year: 492-78,1978

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Human Leukocyte
DOSE/DURATION           : 4000 ppm
REFERENCE :
   ENVRAL Environmental Research.  (Academic Press, Inc., 1 E. First St.,
   Duluth, MN 55802) V.1-    1967-  Volume(issue)/page/year: 20,99,1979

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Parenteral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 18 mg/kg
SEX/DURATION            : male 1 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
REFERENCE :
   ENVRAL Environmental Research.  (Academic Press, Inc., 1 E. First St.,
   Duluth, MN 55802) V.1-    1967-  Volume(issue)/page/year: 20,99,1979

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Parenteral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 180 mg/kg
SEX/DURATION            : male 1 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Fertility - pre-implantation mortality (e.g. reduction in
   number of implants per female; total number of implants per corpora lutea)
REFERENCE :
   ENVRAL Environmental Research.  (Academic Press, Inc., 1 E. First St.,
   Duluth, MN 55802) V.1-    1967-  Volume(issue)/page/year: 20,99,1979

其他信息

  • 贮存时间延长，颜色会逐渐变黄，阳光直射、大气贮存，变色速度快。激烈摇动后会暂时混浊，数小时后自然澄清。有胺味，溶于水，溶于乙醇、乙醚、氯仿、苯等有机溶剂。
  • F:3
  • 蒸气密度:3.07 (vs air)
  • Acros Organics:N,N-二乙基羟胺 N,N-Diethylhydroxylamine, 97%(3710-84-7)
  • 二乙基羟胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D1178 N,N-二乙基羟胺(约85%的水溶液,约8.6mol/L) N,N-Diethylhydroxylamine (ca. 85% in Water, ca. 8.6mol/L) 25ML 194元 2014/06/02 D1178 N,N-二乙基羟胺(约85%的水溶液,约8.6mol/L) N,N-Diethylhydroxylamine (ca. 85% in Water, ca. 8.6mol/L) 500ML 736元 2014/06/02 D1339 N,N-二乙基羟胺 N,N-Diethylhydroxylamine 25ML 160元
  • MOL 文件:3710-84-7.mol
  • MSDS 信息:Diethyl hydroxylamine(3710-84-7).msds
  • 用途二:1、 做为乙烯基单体，用于共轭烯烃的高效阻聚剂。2、 在液相或气相中对已有端聚种子的情况下，可作为高效端聚抑制剂。3、 是丁苯乳聚过程的非常优异的终止剂。4、是不饱和油类及树脂的抗氧化剂。5、 是光敏树脂、感光乳剂、合成树脂的良好稳定剂。6、在环境保护中是良好的光化学烟雾抑制剂。7、是锅炉给水和蒸汽换热设备的缓蚀剂。
  • 敏感性:Hygroscopic
  • 蒸气压:4 mm Hg ( 0 °C)
  • Sigma Aldrich:3710-84-7(sigmaaldrich)
  • 上游原料:三乙胺 --> 过氧化氢 --> 焦磷酸钠
  • Alfa Aesar:N,N-二乙基羟胺,97% N,N-Diethylhydroxylamine, 97%(3710-84-7)
  • 海关编码:29280090
  • 用途一:用作乙烯基单体及共轭烯烃的高效阻聚剂，是丁苯乳聚过程的终止剂，是不饱和油类等的抗氧化剂
  • 图谱信息:二乙基羟胺(3710-84-7)核磁图( 13 CNMR) 二乙基羟胺(3710-84-7)质谱(MS) 二乙基羟胺(3710-84-7)核磁图( 1 HNMR) 二乙基羟胺(3710-84-7)Raman光谱 二乙基羟胺(3710-84-7)红外图谱(IR1)
  • TCI Shanghai:N,N-二乙基羟胺(约85%的水溶液,约8.6mol/L) N,N-Diethylhydroxylamine (ca. 85% in Water, ca. 8.6mol/L)(3710-84-7)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Hydroxylamines - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Hydroxylamines - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Hydrazones
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Hydroxylamines
  1. Functional Group 官能团索引
  2. hydroxylamine

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