4-Bromo-2-Chlorophenol 2-氯-4-溴苯酚

CAS 3964-56-5 MFCD00002166

化学结构图

3964-56-5
SMILES: Oc1ccc(Br)cc1Cl

化学属性

Mol. FormulaC6H4BrClO
Mol. Weight207.45
Boiling Point232-235°C at 760 mmHg
Melting Point47-49°C
Flash Point113°C
TSCANo
Appearance 本品为无色结晶，m.p.47～49℃，微溶于水，溶于苯、甲苯等有机溶剂。

别名和识别编码

Chemical Name4-Bromo-2-Chlorophenol
CAS Number3964-56-5
Alfabeta NameBROMOCHLOROPHENOL 42---
MDL NumberMFCD00002166
PubChem Substance ID19859
EC Number223-572-5
Reaxys-RN2042867
Beilstein Registry Number2042867
Synonym 4-Bromo-2-chlorophenol {LY} 4-Bromo-2-chlorophenol {} {LY} 4-Bromo-2-chlorophenol {} {} {LY} 4-Bromo-2-chlorophenol {} {} {} {LY} 4-Bromo-2-chlorophenol {} {} {} {} {LY} 4-Bromo-2-chlorophenol {} {} {} {} {} {LY} 4-Bromo-2-chlorophenol {} {} {} {} {} {} {LY} 4-Bromo-2-chlorophenol {} {} {} {} {} {} {} {LY} 4-Bromo-2-chlorophenol {} {} {} {} {} {} {} {} {LY} 4-Bromo-2-chlorophenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromo-2-chlorophenol {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromo-2-chlorophenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromo-2-chlorophenol {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromo-2-chlorophenol {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromo-2-chlorophenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromo-2-chlorophenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromo-2-chlorophenol {} {} {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation2-氯-4-溴苯酚
LabNetwork Molecule IDLN00129763
InChIInChI=1S/C6H4BrClO/c7-4-1-2-6(9)5(8)3-4/h1-3,9H
Canonical SMILESOC1=CC=C(Br)C=C1Cl
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分类

  • {SNA} Building Blocks, C6 to C8, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols
  • Building Blocks, C6 to C8, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; alcohol; 1fragment
  • {Chemicalbook} 农药中间体: 杀虫剂中间体: 有机磷类杀虫剂

相关文献及参考

  • Beil. 6 ,II,187
  • Aldrich MSDS 1 , 242:B / Corp MSDS 1 (1), 516:C / FT-IR 2 (2), 1866:A / FT-IR 1 (1), 1090:A / IR-Spectra (3), 655:H / NMR-Reference 2 (1), 885:D / RegBook 1 (1), 1283:A / Structure Index 1 , 195:C:7 / Vapor Phase 3 , 1026:B
  • Short: III/20b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20b Year: 1988 Keyword: NQR ISBN: 3-540-18483-X ISBN: 978-3-540-18483-6 Internet Resource: DOI:10.1007/b86664 RefComment: IX,717 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard Codes 9
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
UN Number 3077
Packing GroupIII
Storage condition RT, stored under nitrogen {LY} RT, stored under nitrogen {} {LY} RT, stored under nitrogen {} {} {LY} RT, stored under nitrogen {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • TCI Shanghai:4-溴-2-氯苯酚 4-Bromo-2-chlorophenol,>;97.0%(GC)(3964-56-5)
  • Acros Organics:4-溴-2-氯苯酚 4-Bromo-2-chlorophenol,99%(3964-56-5)
  • 4-溴-2-氯苯酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1819 4-溴-2-氯苯酚 4-Bromo-2-chlorophenol 25G 720元 2014/06/02 B1819 4-溴-2-氯苯酚 4-Bromo-2-chlorophenol 5G 253元 2010/06/21 173530050 4-溴-2-氯苯酚 4-Bromo-2-chlorophenol 99% 5 GR 339元
  • 上游原料:溴 --> 4-溴苯酚 --> 2-氯苯酚
  • 用途二:2-氯-4-溴苯酚是三元不对称有机磷杀虫剂丙溴磷的中间体。
  • Hazard Note:Irritant
  • 下游产品:丙溴磷 --> O,O-二乙基-O-(2-氯-4-溴苯基)硫代磷酸酯 --> 4-溴-2,6-二氯酚
  • 方法一:其制备方法是由邻氯苯酚溴化得到2-氯-4-溴苯酚。 将邻氯苯酚和溶剂定量抽入搪瓷反应釜中，在搅拌、负压、冷却条件下，向釜内缓慢滴加一定量的溴素，温度控制在8～12℃，溴素加毕后，在常温继续反应2h，然后维持在常温下，慢慢加入定量的30%碱液中和反应物，搅拌0.5h后将物料抽到分层器，静置4h以上，下层即为55％～60%2-氯-4-溴酚钠水溶液，酸化即得2-氯-4-溴苯酚。
  • MOL 文件:3964-56-5.mol
  • Sigma Aldrich:3964-56-5(sigmaaldrich)
  • Alfa Aesar:4-溴-2-氯苯酚,98% 4-Bromo-2-chlorophenol, 98%(3964-56-5)
  • 用途一:用作农药丙溴磷的中间体，也可用于其他有机合成
  • MSDS 信息:4-Bromo-2-chlorophenol(3964-56-5).msds

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Phenols 酚类
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Phenols 酚类
  6. C6 to C8 - Phenols
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Aromatic alcohols 芳香醇
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers

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