2-Isopropoxyphenol 2-异丙氧基苯酚

CAS 4812-20-8 MFCD00002184

化学结构图

4812-20-8
SMILES: CC(C)OC1CCCCC1O

化学属性

Mol. FormulaC9H12O2
Mol. Weight152.19
Refractive indexn20/D 1.514(lit.)
Boiling Point100-102 °C at 11 mmHg
Density1.03
Flash Point87°(188°F)
TSCAYes
Appearance 2-异丙氧基苯酚为无色透明的油状液体，b.p. 100～102℃/1.46 kPa，n 1.5140，相对密度 1.030，不溶于水，溶于苯等有机溶剂。 D 20

别名和识别编码

Chemical Name2-Isopropoxyphenol
CAS Number4812-20-8
PubChem Substance ID20949
EC Number225-379-1
MDL NumberMFCD00002184
Beilstein Registry Number1937063
Synonym 2-Isopropoxyphenol {LY} 2-Isopropoxyphenol {} {LY} 2-Isopropoxyphenol {} {} {LY} 2-Isopropoxyphenol {} {} {} {LY} 2-Isopropoxyphenol {} {} {} {} {LY} 2-Isopropoxyphenol {} {} {} {} {} {LY} 2-Isopropoxyphenol {} {} {} {} {} {} {LY} 2-Isopropoxyphenol {} {} {} {} {} {} {} {LY} 2-Isopropoxyphenol {} {} {} {} {} {} {} {} {LY} 2-Isopropoxyphenol {} {} {} {} {} {} {} {} {} {LY} 2-Isopropoxyphenol {} {} {} {} {} {} {} {} {} {} {LY} 2-Isopropoxyphenol {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Isopropoxyphenol {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Isopropoxyphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Isopropoxyphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Isopropoxyphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Isopropoxyphenol {} {} {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation2-异丙氧基苯酚
LabNetwork Molecule IDLN00223403
InChIInChI=1S/C9H12O2/c1-7(2)11-9-6-4-3-5-8(9)10/h3-7,10H,1-2H3
Canonical SMILESOC1=CC=CC=C1OC(C)C
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分类

  • {Chemicalbook} 农药中间体: 杀虫剂中间体: 氨基甲酸酯类杀虫剂
  • {SNA} Building Blocks, C9 to C20+, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols
  • Building Blocks, C9 to C20+, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols

相关文献及参考

  • Beil. 6 ,III,4209
  • Aldrich MSDS 1 , 1117:A / Corp MSDS 1 (1), 2030:B / FT-IR 2 (2), 1840:B / FT-IR 1 (1), 1172:A / FT-NMR 1 (2), 248:A / IR-Spectra (3), 703:H / NMR-Reference 2 (1), 870:D / RegBook 1 (1), 1267:D / Structure Index 1 , 192:B:5 / Vapor Phase 3 , 1005:A

安全信息

GHS Symbol
WGK Germany3
Hazard Codes Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • 2-异丙氧基苯酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 209220050 2-异丙氧基苯酚 2-Isopropoxyphenol 97% 5 GR 537元 2010/06/21 209220250 2-异丙氧基苯酚 2-Isopropoxyphenol 97% 25 GR 1115元 2010/05/25 L07360 2-异丙氧基苯酚, 97% 2-Isopropoxyphenol, 97% 5g 267元
  • 上游原料:碳酸钾 --> 邻苯二酚 --> 稀盐酸 --> 2-溴丙烷 --> 2-氯丙烷
  • 图谱信息:2-异丙氧基苯酚(4812-20-8)核磁图( 13 CNMR) 2-异丙氧基苯酚(4812-20-8)核磁图( 1 HNMR) 2-异丙氧基苯酚(4812-20-8)质谱(MS) 2-异丙氧基苯酚(4812-20-8)红外图谱(IR1)
  • MSDS 信息:2-(1-Methylethoxy)phenol(4812-20-8).msds
  • 下游产品:残杀威
  • Alfa Aesar:2-异丙氧基苯酚,97% 2-Isopropoxyphenol, 97%(4812-20-8)
  • MOL 文件:4812-20-8.mol
  • Sigma Aldrich:4812-20-8(sigmaaldrich)
  • 用途一:2-异丙氧基苯酚又名2-(1-甲基乙氧基)苯酚，是合成氨基甲酸酯类杀虫剂残杀威的重要中间体。
  • 方法一:2-异丙氧基苯酚是由邻苯二酚和异丙基溴反应制得。 将异丙基溴慢慢滴加到正在回流的邻苯二酚、碳酸钾、丁酮和相转移催化剂的混合物中，继续回流一定的时间，然后蒸出绝大部分丁酮(85％)，加足量的水溶解固体盐，再以苯萃取，萃取液用稀氢氧化钠溶液萃取，该萃取液用稀盐酸中和后再用苯萃取，氯化钙干燥，蒸去绝大部分苯，减压蒸馏，收集100～102℃/1.46kPa的馏分，收率>;60％(回流32h产率>;60％，回流8h产率为54％)。若用异丙基氯代替异丙基溴，可以降低成本，但工艺上要采用高压釜反应，国内邻异丙氧基苯酚采用异丙基氯与邻苯二酚反应的工艺。
  • Acros Organics:2-异丙氧基苯酚 2-Isopropoxyphenol, 97%(4812-20-8)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Phenols 酚类
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Phenols 酚类
  6. C9 to C20+ - Phenols
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Aromatic alcohols 芳香醇

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