4-(Phenyldiazenyl);phenol 4-苯偶氮基苯酚

CAS 1689-82-3 MFCD00002330

化学结构图

1689-82-3
SMILES: Oc1ccc(/N=N/c2ccccc2)cc1

化学属性

Mol. FormulaC12H10N2O
Mol. Weight198.22
Melting Point150-152°C
TSCAYes
Boiling Point369.8°C at 760 mmHg
Appearance 橙色柱状固体。熔点155-157℃，沸点220-230℃(2.67kPa)。溶于醇、醚，溶于稀碱溶液及浓硫酸中呈黄色，微溶于热水，不溶于冷水。

别名和识别编码

Chemical Name4-(Phenyldiazenyl);phenol
Synonym 4-(Phenyldiazenyl)phenol {LY} 4-(Phenyldiazenyl)phenol {} {LY} 4-(Phenyldiazenyl)phenol {} {} {LY} 4-(Phenyldiazenyl)phenol {} {} {} {LY} 4-(Phenyldiazenyl)phenol {} {} {} {} {LY} 4-(Phenyldiazenyl)phenol {} {} {} {} {} {LY} 4-(Phenyldiazenyl)phenol {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-(Phenyldiazenyl)phenol {} {} {} {} {} {} {} {LY} 4-(Phenyldiazenyl)phenol {} {} {} {} {} {} {} {} {LY} 4-(Phenyldiazenyl)phenol {} {} {} {} {} {} {} {} {} {LY} 4-(Phenyldiazenyl)phenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-(Phenyldiazenyl)phenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-(Phenyldiazenyl)phenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-(Phenyldiazenyl)phenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-(Phenyldiazenyl)phenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-(Phenyldiazenyl)phenol {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00002330
CAS Number1689-82-3
EC Number216-880-6
Beilstein Registry Number957569
PubChem Substance ID15529
Reaxys-RN957569
Chemical Name Translation4-苯偶氮基苯酚
Wiswesser Line NotationQR DNUNR
InChIInChI=1S/C12H10N2O/c15-12-8-6-11(7-9-12)14-13-10-4-2-1-3-5-10/h1-9,15H
Canonical SMILESOC1=CC=C(N=NC2=CC=CC=C2)C=C1
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分类

  • {SNA} Adsorption Indicators, Analytical Reagents, Analytical/Chromatography, Hematology and Histology, Indicators, P, Stains & Dyes, A to Z, Stains and Dyes, Titration
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; alcohol; 1fragment
  • {SNA} Adsorption Indicators, Indicators, P, Stains & Dyes, A to Z, Stains and Dyes, Titration, 分析/色谱, 分析试剂, 细胞生物学, 血液学和组织学

相关文献及参考

  • Short: II/27B Title: Diamagnetic Susceptibility of Organic Compounds, Oils, Paraffins and Polyethylenes Author: Kumar, M.; Gupta, R. Editor: Gupta, Radha Raman Source: Landolt-Börnstein, New Series Volume: II/27B Year: 2008 Keyword: diamagnetic susceptibility; organic compounds ISBN: 978-3-540-44359-9 (print) ISBN: 978-3-540-45860-9 (online) Internet Resource: doi:10.1007/978-3-540-45860-9 RefComment: VIII, 503 p. With CD-ROM., Hardcover RefComment: Written for: Scientists and researchers in the fields of physics, chemistry, materials science RefComment: Supplement and Revised Editon to II/16 Abstract: The volume II/27 has been divided into three subvolumes according to the classes of compounds: Subvolume A: Diamagnetic susceptibility and magnetic anisotropy of inorganic and organometallic compounds; Subvolume B: Diamagnetic susceptibility of organic compounds, oils, paraffins and polyethylenes; Subvolume C: Diamagnetic susceptibility and magnetic anisotropy of organic compounds. The data presented in this volume are based on the literature survey of the chemical abstracts up to 2005. The calculated values of diamagnetic susceptibility of organic compounds in the present subvolume II/27B are presented along with their experimental values. They have been calculated with the use of structural parameters in structural formula by using different theoretical methods available in the literature.
  • Short: III/35B Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Fluorine-19 and Nitrogen-15 Author: Balasubramanian, M.; Gupta, R.R.; Jain, M.; Perumal, S. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35B Year: 1998 ISBN: 3-540-63275-1 ISBN: 978-3-540-63275-7 Internet Resource: DOI:10.1007/b55685 RefComment: VII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts an

安全信息

RTECSSM8300000
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H302 Harmful if swallowed 吞食有害
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
WGK Germany3
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Hazard Codes 4.1
UN Number 3234 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 75 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD691-490

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 800 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NYKZAU Nippon Yakurigaku Zasshi.  Japanese Journal of Pharmacology. (Nippon
   Yakuri Gakkai, c/o Kyoto Daigaku Igakubu Yakurigaku Kyoshitsu, Konoe-cho,
   Yoshida, Sakyo-ku, Kyoto 606, Japan) V.40-    1944- Volume(issue)/page/year:
   60,209,1964

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • Acros Organics:4-Phenylazophenol, 97%(1689-82-3)
  • Sigma Aldrich:1689-82-3(sigmaaldrich)
  • 方法一:由苯胺经重氮化、偶合而得。将盐酸和碎冰投入反应锅，搅拌下加入苯胺，于5℃以下缓缓加入亚硝酸钠溶液。用淀粉碘化钾试纸测试，呈深蓝色则到达反应终点。在偶合锅中配制苯酚钠盐溶液，加入碎冰，搅拌下缓缓加入上述重氮化液，控制在15℃以下反应。加料完毕，继续搅拌20min。然后用稀盐酸调节pH为3-4，搅拌30min后离心过滤，滤饼用水洗至中性，干燥，得羟基偶氮苯。
  • 上游原料:稀盐酸 --> 淀粉-碘化钾试纸 --> 偶氮苯
  • 用途一:用作有机合成中间体和指示剂。
  • Alfa Aesar:4-苯偶氮基苯酚,98% 4-Phenylazophenol, 98%(1689-82-3)
  • 4-N-苯基苯酰胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30099780 4-羟基偶氮苯;对羟基偶氮苯;对苯偶氮酚;4-苯基偶氮苯酚 25g 226元 2011/04/16 P0149 4-(苯偶氮)苯酚 4-(Phenylazo)phenol 25G 437元 2010/06/21 417360250 4-N-苯基苯酰胺 4-Phenylazophenol 97% 25 GR 424元
  • MOL 文件:1689-82-3.mol
  • TCI Shanghai:4-苯偶氮基苯酚 4-(Phenylazo)phenol,>;95.0%(T)(1689-82-3)
  • 色指数:11800

系列性分类

  1. Life Science 生命科学
  2. Hematology and Histology 血液学和组织学
  3. Stains and Dyes - Hematology and Histology
  4. Stains & Dyes, A to Z - Stains and Dyes
  5. P - Stains & Dyes, A to Z
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Titration - Analytical Reagents
  4. Indicators - Titration
  5. Adsorption Indicators - Indicators
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Aromatic alcohols 芳香醇
  1. Analytical & Chromatography 分析化学与色谱
  2. Titration
  3. Indicators

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