4,4′-Sulfonyldiphenol 4,4′-磺酰基二苯酚

CAS 80-09-1 MFCD00002350

化学结构图

80-09-1
SMILES: OC1C=CC(=CC=1)S(=O)(=O)C1C=CC(O)=CC=1

化学属性

Mol. FormulaC12H10O4S
Mol. Weight250.27
Melting Point247°C
Density1.432
TSCAYes
Appearance 白色针状结晶。熔点240-241℃。易溶于脂肪烃，溶于醇和醚，微溶于芳烃，难溶于水。该品分子中含两个羟基和一个吸电子很强的砜基，故酸性比其他酚类强。
Solubility1.1 g/L (20 °C)
Boiling Point505.3°C at 760 mmHg
Flash Point259.4°C

别名和识别编码

Chemical Name4,4′-Sulfonyldiphenol
Synonym 4,4'-Sulfonyldiphenol {LY} 4,4'-Sulfonyldiphenol {} {LY} 4,4'-Sulfonyldiphenol {} {} {LY} 4,4'-Sulfonyldiphenol {} {} {} {LY} 4,4'-Sulfonyldiphenol {} {} {} {} {LY} 4,4'-Sulfonyldiphenol {} {} {} {} {} { {} {} {} {} {} {LY} 4,4'-Sulfonyldiphenol {} {} {} {} {} {} {LY} 4,4'-Sulfonyldiphenol {} {} {} {} {} {} {} {LY} 4,4'-Sulfonyldiphenol {} {} {} {} {} {} {} {} {LY} 4,4'-Sulfonyldiphenol {} {} {} {} {} {} {} {} {} {LY} 4,4'-Sulfonyldiphenol {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Sulfonyldiphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Sulfonyldiphenol {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Sulfonyldiphenol {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Sulfonyldiphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Sulfonyldiphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00002350
CAS Number80-09-1
Beilstein Registry Number2052954
PubChem Substance ID87563524
EC Number201-250-5
Chemical Name Translation4,4′-磺酰基二苯酚
Reaxys-RN2052954
Wiswesser Line NotationQR DSWR DQ
LabNetwork Molecule IDLN00223652
Canonical SMILESO=S(C1=CC=C(O)C=C1)(C2=CC=C(O)C=C2)=O
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分类

  • {SNA} Bisphenol and Sulfonyldiphenol Monomers, Monomers, Polymer Science, 材料科学
  • {SNA} Bisphenol and Sulfonyldiphenol Monomers, Materials Science, Monomers, Polymer Science

相关文献及参考

  • Beilstein:6,861

安全信息

Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P332+P313
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P337+P313
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P302+P352
  • P405 Store locked up. 上锁保管。
WGK Germany1
GHS Symbol
Signal word
Hazard statements
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H303 May be harmfully swallowed 吞食可能有害
Hazard Codes Xi
RTECSSM8925000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R36 Irritating to eyes 刺激眼睛
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : >1 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0534330

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4556 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   BIOFX* BIOFAX Industrial Bio-Test Laboratories, Inc., Data Sheets.  (1810
   Frontage Rd., Northbrook, IL 60062)  Volume(issue)/page/year: 601-05501,1974

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >10250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   BIOFX* BIOFAX Industrial Bio-Test Laboratories, Inc., Data Sheets.  (1810
   Frontage Rd., Northbrook, IL 60062)  Volume(issue)/page/year: 601-05501,1974

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0534330

{hazard_

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXP

Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {}

其他信息

  • 双酚 S价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010021 双酚 S 5g 100元 2011/08/23 30064326 4，4’-二羟基二苯砜 100g 50元 2011/04/16 B0495 双(4-羟苯基)砜 Bis(4-hydroxyphenyl) Sulfone 500G 613元
  • 用途二:4,4'-二羟基二苯砜主要用作固色剂。此外，可用作镀液添加剂、皮革鞣剂、分散染料高温染色的分散剂、酚醛树脂硬化促进剂，树脂阻燃剂等。也是农药、染料、助剂的中间体。作为双酚A的代用品，可作为聚碳酸酯、环氧树脂、聚酯、酚醛树脂的原料，以及聚砜、聚醚砜的原料。该品也用于制造彩色摄影材料、照相反差增强剂、热敏记录材料（显色剂）、日用表面活性剂和高效除臭剂等。以双酚S为原料可制取固色剂A（国外商品名为Cibatex PA）。
  • Acros Organics:磺酰二苯酚（双酚S） 4,4'-Sulfonyldiphenol, 99.70%(80-09-1)
  • 海关编码:29309070
  • 用途三:主要用作固色剂。此外，可用作镀液添加剂、皮革鞣剂、分散染料高温染色的分散剂、酚醛树脂硬化促进剂，树脂阻燃剂等。也是农药、染料、助剂的中间体。作为双酚A的代用品，可作为聚碳酸酯、环氧树脂、聚酯、酚醛树脂的原料，以及聚砜、聚醚砜的原料。该品也用于制造彩色摄影材料、照相反差增强剂、热敏记录材料（显色剂）、日用表面活性剂和高效除臭剂等。
  • MSDS 信息:4,4'-Dihydroxydiphenylsulfone(80-09-1).msds
  • Sigma Aldrich:80-09-1(sigmaaldrich)
  • 图谱信息:双酚 S(80-09-1)核磁图( 13 CNMR) 双酚 S(80-09-1)红外图谱(IR1) 双酚 S(80-09-1)核磁图( 1 HNMR) 双酚 S(80-09-1)红外图谱(IR2) 双酚 S(80-09-1)质谱(MS)
  • 易溶于醇、乙晴、二甲亚砜、碱溶液、热水，微溶于冷水。
  • TCI Shanghai:双-(4-羟苯基)砜 Bis(4-hydroxyphenyl) Sulfone,>;98.0%(LC)(T)(80-09-1)
  • MOL 文件:80-09-1.mol
  • Alfa Aesar:双(4-羟基苯基)砜,99% Bis(4-hydroxyphenyl) sulfone, 99%(80-09-1)
  • 用途一:主要用作合成聚砜树脂的单体，也可直接应用于涂料、皮革改性剂、染料中间体、金属电镀亮光剂等
  • 方法一:由苯酚与硫酸反应而得。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfones - Sulfur Compounds
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Monomers - Polymer Science
  4. Bisphenol and Sulfonyldiphenol Monomers - Monomers
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfoxides - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Monomers
  4. Biodegradable Polymer Monomers
  1. Materials Science 材料科学
  2. Pressure & Heat Sensitive Recording Materials

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