Bisphenol F, 98%, reference material 4,4-二羟基二苯甲烷

CAS 620-92-8 MFCD00002385

化学结构图

620-92-8
SMILES: Oc1ccc(Cc2ccc(O)cc2)cc1

化学属性

Mol. FormulaC13H12O2
Mol. Weight200.24
Melting Point162-164°C
TSCAYes
Appearance 白色叶状结晶。熔点160℃,紫外线可引起变色。
Boiling Point297.96 °C at 760 mmHg

别名和识别编码

Chemical NameBisphenol F, 98%, reference material
CAS Number620-92-8
Synonym 4,4'-Dihydroxydiphenylmethane {LY} 4,4'-Dihydroxydiphenylmethane {} {LY} 4,4'-Dihydroxydiphenylmethane {} {} {LY} 4,4'-Dihydroxydiphenylmethane {} {} {} {LY} 4,4'-Dihydroxydiphenylmethane {} {} {} {} {LY} 4,4'-Dihydroxydiphenylmethane {} {} {} {} {} {LY} 4,4'-Dihydroxydiphenylmethane {} {} {} {} {} {} {LY} 4,4'-Dihydroxydiphenylmethane {} {} {} {} {} {} {} {LY} 4,4'-Dihydroxydiphenylmethane {} {} {} {} {} {} {} {} {LY} 4,4'-Dihydroxydiphenylmethane {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dihydroxydiphenylmethane {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dihydroxydiphenylmethane {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dihydroxydiphenylmethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dihydroxydiphenylmethane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dihydroxydiphenylmethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dihydroxydiphenylmethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Dihydroxydiphen
Beilstein Registry Number2049425
PubChem Substance ID12111
EC Number210-658-2
MDL NumberMFCD00002385
Reaxys-RN2049425
Chemical Name Translation4,4-二羟基二苯甲烷
Wiswesser Line NotationQR D1R DQ
LabNetwork Molecule IDLN00224367
InChIInChI=1S/C13H12O2/c14-12-5-1-10(2-6-12)9-11-3-7-13(15)8-4-11/h1-8,14-15H,9H2
Canonical SMILESOC1=CC=C(CC2=CC=C(O)C=C2)C=C1
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分类

  • Building Blocks, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Polyols
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Polyols

产品应用

  • Bisphenol F is a bisphenol derivative with antioxidant activities. Bisphenol F has been reported to exhibit estrogen agonistic properties.

相关文献及参考

  • Higashihara, N. et al.: Arch. Toxicol., 81, 825 (2007); Kanai, H. et al.: Int. J. Cancer, 93, 20 (2001); Pospisil, J. et al.: Kinet. Mech. Polyreacti.Int. Symp. Macromol. Chem. Prepr.,5, 383 (1969);
  • Beil. 6 ,IV,6664
  • FT-IR 1 (1), 1118:D / FT-IR 2 (2), 1906:B / FT-NMR 1 (2), 322:B / IR-Spectra (3), 671:F / IR-Spectra (2), 599:E / NMR-Reference 2 (1), 916:A / RegBook 1 (1), 1309:L / Sax 6 , 490 / Structure Index 1 , 200:C:4

安全信息

Precautionary statements
  • P305+P351+P338
  • P337+P317
  • P264+P265
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P317
WGK Germany2
GHS Symbol
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H303 May be harmfully swallowed 吞食可能有害
Hazard Codes Xi
RTECSSL9625000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4950 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   23,95,1962

Storage condition 2-8°C {LY} 2-8°C Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°

其他信息

  • 下游产品:草酸亚铁二水合物
  • 方法一:由苯酚与甲醛在酸性介质中反应而得。以强无机酸(如硫酸、盐酸)为催化剂的生产工艺有许多缺点,如设备易腐蚀,杂质多(如副反应生成氯甲基醚和氯甲基酚),分离困难。美国孟山都公司采用磷酸作催化剂,产品颜色好,产量高。最大优点是苯酚在磷酸中的溶解度低,有利于产品分离和催化剂的循环使用。甲醛的转化率为90%,4,4'-、2,4-2,2'-异构物之比为55:37:8。有机相经中和、过滤、蒸馏,得到产品双酚F 。
  • 图谱信息:4,4'-二羟基二苯甲烷(620-92-8)红外图谱(IR1) 4,4'-二羟基二苯甲烷(620-92-8)红外图谱(IR2) 4,4'-二羟基二苯甲烷(620-92-8)核磁图( 1 HNMR) 4,4'-二羟基二苯甲烷(620-92-8)核磁图( 13 CNMR) 4,4'-二羟基二苯甲烷(620-92-8)质谱(MS)
  • 储运特性:库房通风低温干燥
  • 毒性分级:中毒
  • 4,4'-二羟基二苯甲烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0819 4,4'-二羟基二苯基甲烷 4,4'-Dihydroxydiphenylmethane 5G 803元 2014/06/02 B0819 4,4'-二羟基二苯基甲烷 4,4'-Dihydroxydiphenylmethane 25G 2330元 2010/05/25 A11417 4,4'-二羟基二苯基甲烷, 97% 4,4'-Dihydroxydiphenylmethane, 98% 5g 1134元
  • 急性毒性:口服-大鼠 LD50: 4950 毫克/公斤
  • MOL 文件:620-92-8.mol
  • 灭火剂:干粉,泡沫,砂土,二氧化碳, 雾状水
  • 可燃性危险特性:可燃; 受热分解刺激烟雾
  • 用途一:适用加工软片、电子分色软片、激光照排软片、明室拷贝软片
  • 4,4'-二羟基二苯甲烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 B0819 4,4'-二羟基二苯基甲烷 4,4'-Dihydroxydiphenylmethane 5G 663元 2011/04/16 B0819 4,4'-二羟基二苯基甲烷 4,4'-Dihydroxydiphenylmethane 25G 1910元 2010/05/25 A11417 4,4'-二羟基二苯基甲烷, 97% 4,4'-Dihydroxydiphenylmethane, 98% 5g 1134元
  • Alfa Aesar:4,4'-二羟基二苯基甲烷,97% 4,4'-Dihydroxydiphenylmethane, 98%(620-92-8)
  • 用途二:(1)环氧树脂 以双酚F为原料的环氧树脂与以双酚A为原料的环氧树脂相比,有粘度低、作业性优良等特点,可应用于无溶剂型至超高固体份涂料,也可应用于衬里材料、地板材料、注型材料、浸渍材料、层压材料等领域。(2)聚碳酸酯树脂 由双酚F与光气制成的聚碳酸酯树脂易溶于二氯甲烷等低沸点有机溶剂,软化点低,加工成型性好,即使在受到非常大的破坏时也用伸缩性,适于制造成型材料或薄膜等。(3)聚酯树脂 双酚F与环氧烷加成制得的联苯型二醇,与二元酸等反应所制得的树脂,粘度低,机械性能和化学性能均优异,特别适宜于制造耐腐蚀材料。双酚F还可用于生产油溶性酚醛树脂、阻燃剂、抗氧剂和表面活性剂等。
  • TCI Shanghai:4,4'-二羟基二苯基甲烷 4,4'-Dihydroxydiphenylmethane,>;99.0%(GC)(620-92-8)
  • 上游原料:甲酚 --> 甲基醚
  • Sigma Aldrich:620-92-8(sigmaaldrich)
  • 类别:有毒物品

系列性分类


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