N-Phenylanthranilic acid N-苯基邻氨基苯甲酸

CAS 91-40-7 MFCD00002421

化学结构图

91-40-7
SMILES: O=C(O)c1ccccc1Nc1ccccc1

化学属性

Mol. FormulaC13H11NO2
Mol. Weight213.23
Melting Point182-185 °C
TSCAYes
Solubility不溶
Appearance 白色片状结晶。熔点183-184℃（分解）。溶于热乙醇，微溶于热水、热苯及乙醚。
Boiling Point353.22 °C at 760 mmHg

别名和识别编码

Chemical NameN-Phenylanthranilic acid
CAS Number91-40-7
Alfabeta NameANILINOBENZOICACID 2-
MDL NumberMFCD00002421
Synonym Fenamic acid {LY} Fenamic acid {} {LY} Fenamic acid {} {} {LY} Fenamic acid {} {} {} {LY} Fenamic acid {} {} {} {} {LY} Fenamic acid {} {} {} {} {} {LY} Fenamic acid {} {} {} {} {} {} {LY} Fenamic acid {} {} {} {} {} {} {} {LY} Fenamic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fenamic acid {} {} {} {} {} {} {} {} {} {LY} Fenamic acid {} {} {} {} {} {} {} {} {} {} {LY} Fenamic acid {} {} {} {} {} {} {} {} {} {} {} {LY} Fenamic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fenamic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fenamic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fenamic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fenamic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fenamic acid {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID4386
EC Number202-066-8
Beilstein Registry Number1456607
Merck Number7273
Chemical Name TranslationN-苯基邻氨基苯甲酸
Reaxys-RN1456607
Wiswesser Line NotationQVR BMR
LabNetwork Molecule IDLN00132408
InChIInChI=1S/C13H11NO2/c15-13(16)11-8-4-5-9-12(11)14-10-6-2-1-3-7-10/h1-9,14H,(H,15,16)
Canonical SMILESO=C(O)C1=CC=CC=C1NC2=CC=CC=C2
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分类

  • {SNA} Aromatic Amino Acids, Bioactive Small Molecules, Cell Biology, Chemical Biology, Chemical Synthesis, P, Peptide Chemistry, Unnatural Amino Acid Derivatives
  • {SNA} Aromatic Amino Acids, Chemical Biology, Chemical Synthesis, PA-PH, Peptide Chemistry, Unnatural Amino Acid Derivatives, 生物活性小分子, 细胞生物学
  • {SNA} Aromatic Amino Acids, Chemical Biology, Chemical Synthesis, Peptide Chemistry, Unnatural Amino Acids & Derivatives
  • {SA} Analytical Reagents, Analytical Reagents for General Use, Analytical/Chromatography, Bioactive Small Molecules, Cell Biology,

产品应用

  • 氧化还原指示剂，用于检测钒.

相关文献及参考

  • Merck: 14,7273
  • Short: II/3
  • Short: EINECS
  • Merck: 14,7273 Beilstein:14,327

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
RTECSCB3730000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Signal word Warning
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S37 Wear suitable gloves 戴适当手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 160 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   YKKZAJ Yakugaku Zasshi.  Journal of Pharmacy.  (Nippon Yakugakkai, 2-12-15
   Shibuya, Shibuya-ku, Tokyo 150, Japan)  No.1-    1881-
   Volume(issue)/page/year: 89,1392,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 235 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   RPTOAN Russian Pharmacology and Toxicology (English Translation).
   Translation of FATOAO.  (Euromed Pub., 33, Woodlands Rd., Surbiton, Surrey,
   UK)  V.30-    1967-  Volume(issue)/page/year: 37,105,1974

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 方法一:将2g邻氨基苯甲酸、3.2g溴苯、2g碳酸钾、0.1g铅粉和12mg硝基苯混合，加热回流3h。用水蒸气蒸除硝基和未反应的溴苯，冷却后过滤，用盐酸使滤液呈酸性，得N-苯基邻氨基苯甲酸粗品。粗品经苯重结晶，是3g成品。
  • 下游产品:氯氮平 --> 吖啶酮 --> 10-氮(杂)蒽
  • 用途二:用作分析试剂及氧化还原指示剂
  • 用途一:用作医药中间体
  • 图谱信息:N-苯基邻氨基苯甲酸(91-40-7)红外图谱(IR3) N-苯基邻氨基苯甲酸(91-40-7)红外图谱(IR2) N-苯基邻氨基苯甲酸(91-40-7)核磁图( 1 HNMR) N-苯基邻氨基苯甲酸(91-40-7)红外图谱(IR1) N-苯基邻氨基苯甲酸(91-40-7)核磁图( 13 CNMR) N-苯基邻氨基苯甲酸(91-40-7)质谱(MS)
  • Acros Organics:N-苯基蒽酸/N-苯基邻氨基苯甲酸 N-Phenylanthranilic acid, 98%(91-40-7)
  • 上游原料:溴苯 --> 邻氨基苯甲酸 --> 铅粉(灰色) --> 苯甲酸(粗品)
  • Alfa Aesar:N-苯基邻氨基苯甲酸,99% N-Phenylanthranilic acid, 99%(91-40-7)
  • MOL 文件:91-40-7.mol
  • 检测方法:T
  • MSDS 信息:Diphenylamine-2-carboxylic acid(91-40-7).msds
  • 海关编码:29224995
  • N-苯基邻氨基苯甲酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30143060 N-苯基代邻氨基苯甲酸 25g 26元 2011/04/16 D0873 N-苯基邻氨基苯甲酸 N-Phenylanthranilic Acid 25G 517元 2010/06/21 163000100 N-苯基邻氨基苯甲酸 N-Phenylanthranilic acid 98% 10 GR 222元
  • 用途四:氧化还原指示剂，用于检测钒.
  • 用途三:用作检验钢中的钒，测定重铬酸钾和钒酸盐的试剂。
  • TCI Shanghai:N-苯基邻氨基苯甲酸 N-Phenylanthranilic Acid,>;98.0%(LC)(T)(91-40-7)

系列性分类

  1. Life Science 生命科学
  2. Cell Biology 细胞生物学
  3. Bioactive Small Molecules - Cell Biology
  4. P - Bioactive Small Molecules
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Analytical Reagents for General Use - Analytical Reagents
  4. Puriss p.a. - Analytical Reagents for General Use
  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Unnatural Amino Acid Derivatives 人工合成氨基酸
  5. Aromatic Amino Acids - Unnatural Amino Acid Derivatives
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Analytical Reagents for General Use - Analytical Reagents
  4. Puriss p.a. - Analytical Reagents for General Use
  5. O-P, Puriss p.a. - Puriss p.a.
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Aromatic acids

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