Phenylalanine, 3-​hydroxy- DL-间酪氨酸

CAS 775-06-4 MFCD00002597

化学结构图

775-06-4
SMILES: N[C@@H](Cc1cccc(O)c1)C(=O)O

化学属性

Mol. FormulaC9H11NO3
Mol. Weight181.19
Melting Point280-285°C
Density1.333
Appearance crystalline
Boiling Point314.29 °C at 760 mmHg

别名和识别编码

Chemical NamePhenylalanine, 3-​hydroxy-
CAS Number775-06-4
Synonym DL-m-Tyrosine {LY} DL-m-Tyrosine {} {LY} DL-m-Tyrosine {} {} {LY} DL-m-Tyrosine {} {} {} {LY} DL-m-Tyrosine {} {} {} {} {LY} DL-m-Tyrosine {} {} {} {} {} {LY} DL-m-Tyrosine {} {} {} {} {} {} {LY} DL-m-Tyrosine {} {} {} {} {} {} {} {LY} DL-m-Tyrosine {} {} {} {} {} {} {} {} {LY} DL-m-Tyrosine {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} DL-m-Tyrosine {} {} {} {} {} {} {} {} {} {} {LY} DL-m-Tyrosine {} {} {} {} {} {} {} {} {} {} {} {LY} DL-m-Tyrosine {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} DL-m-Tyrosine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} DL-m-Tyrosine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} DL-m-Tyrosine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} DL-m-Tyrosine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} DL-m-Tyrosine {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID87576631
EC Number212-270-9
Beilstein Registry Number14,605
MDL NumberMFCD00002597
Reaxys-RN2416853
Merck Number9839
Chemical Name TranslationDL-间酪氨酸
Wiswesser Line NotationQVYZ1R CQ
LabNetwork Molecule IDLN00194612
Canonical SMILESNC(CC1=CC=CC(O)=C1)C(O)=O
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分类

  • Amino Acids & Derivatives
  • {SNA} Amino Acids, Biochemicals and Reagents
  • Aromatics
  • {SNA} Amino Acids, 生化试剂
  • {SA} Chemical Biology, Chemical Synthesis, Peptide Chemistry, Tyrosine Derivatives, Unnatural Amino Acid Derivatives

产品应用

  • A precursor in the formation of catecholamines.

相关文献及参考

  • Carlsson, L.: Eur. J. Pharmacol., 2, 187 (1967); Rubenson, J.: Pharm. Pharmacol., 23, 228, 412 (1971); Sandler, et al.: Nature, 229, 414 (1971); Ungerstedt, et al.: Eur. J. Pharmacol., 21, 230 (1973)
  • Beilstein:14,605

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
RTECSYP2278000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 320 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#02549

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 1400 mg/kg
SEX/DURATION            : female 1-7 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - other developmental
   abnormalities
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   38,251,1976

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • 图谱信息:DL-间酪氨酸(775-06-4)质谱(MS) DL-间酪氨酸(775-06-4)红外图谱(IR1) DL-间酪氨酸(775-06-4)红外图谱(IR2) DL-间酪氨酸(775-06-4)核磁图( 13 CNMR)
  • MOL 文件:775-06-4.mol
  • DL-间酪氨酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0787 DL-间酪氨酸 DL-m-Tyrosine 5G 1760元 2014/06/02 T0787 DL-间酪氨酸 DL-m-Tyrosine 1G 516元 2010/06/21 140630010 DL-间酪氨酸 DL-m-Tyrosine 98.5% 1 GR 482元
  • TCI Shanghai:DL-间酪氨酸 DL-m-Tyrosine,>;95.0%(T)(775-06-4)
  • 上游原料:乙醇 --> 乙醚 --> 溴 --> 氨 --> 三溴化磷 --> 3-(3-羟基苯基)丙酸
  • color:white to off-white
  • MSDS 信息:DL-m-Tyrosine(775-06-4).msds
  • Sigma Aldrich:775-06-4(sigmaaldrich)
  • Acros Organics:DL-m-酪氨酸 DL-m-Tyrosine, 98.50%(775-06-4)

系列性分类

  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Amino Acids 氨基酸
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Food & Beverage Standards - Chromatography
  5. Food Residue Analysis - Food & Beverage Standards
  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Unnatural Amino Acid Derivatives 人工合成氨基酸
  5. Tyrosine Derivatives - Unnatural Amino Acid Derivatives
  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Unnatural Amino Acid Derivatives 人工合成氨基酸
  5. Tyrosine Derivatives - Unnatural Amino Acid Derivatives
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Amino Acids
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Albumins and Transport Proteins
  4. Albumin

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