Dichlorprop 2,4-滴丙酸

CAS 120-36-5 MFCD00002645

化学结构图

120-36-5
SMILES: CC(Oc1ccc(Cl)cc1Cl)C(=O)O

化学属性

Mol. FormulaC9H8Cl2O3
Mol. Weight235
Melting Point117.5-118.1°C
TSCAYes
Density1.421
Solubility微溶于水,溶于多数有机溶剂。

别名和识别编码

Chemical NameDichlorprop
Alfabeta NameDICHLOROPHENOXYPROPANOICACID 224()--,
MDL NumberMFCD00002645
Synonym agrotect Chloroxone Seritox 50 propanoic acid, 2-(2,4-dichlorophenoxy)- dormone Celatox-DP (±)-2-(2,4-Dichlorophenoxy)propionic acid (±)-2-(2,4-Dichlo RD 406 Cornox rd Canapur U46 2-(2,4-DP) Propionic acid, 2-(2,4-dichlorophen Celatox DP dichlorprop DCP Cornox RK {Ch amoxone AF 302 AKOS BBB/209 Amidox α-(2,4-Dichlorophenoxy)propionic acid 2-(2,4-dichloro-phenoxy)-propionic acid Kwas 2,4-dwuchlorofenoksypropionowy 2-(2,4-dichlorophenoxy)propanoic acid Herbizid DP Dichloroprop 2,4二氯苯氧乙酸 2-(2,4-二氯苯氧基)丙酸,2, 2-(2,4-Dichlorophenoxy)propionic acid; 2,4-DP alpha-(2,4-Dichlorophenoxy) propionic acid 2,4-Dichlorophenoxy-α-propionic acid Polymone 2-(2,4-Dichlorphenoxy)-propionsäure Polytox 2,4-二氯苯氧丙酸 Dicotox Propanoic acid, 2-(2,4-dichlorophenoxy)- (±)-2,4-DP 2-(2,4-二氯苯基)丙酸 Dichlorprop {h 2-(2,4-Dichlo 2-(2,4-Dichlor-phenoxy)-propionsäure Diprop Acide 2-(2,4-dichloro-phenoxy) propionique Canapu Hormatox U46 DP-Fluid 甲氯滴 2-(2,4-DICHLOROPHENOXY)PROPIONIC ACID 2-(2,4-DIC BH 2,4-D crotilin 2,4-滴丙酸 2-(2,4-Dichlorophenoxy) propionic acid Kildip Acido 2-(2,4-dicloro-fenossi)-propionico (±)-Dichlorprop 2-(2,4-二氯苯氧基)丙酸
CAS Number120-36-5
PubChem Substance ID24868574
Beilstein Registry Number2213812
EC Number204-390-5
Merck Number14,3078
Chemical Name Translation2,4-滴丙酸
Wiswesser Line NotationQVY1&OR BG DG
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分类

  • {SNA} All alphabetically sorted, Alphabe
  • {SNA} All alphabetically
  • {SA} Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Chromatography, D, DIA - DIC, Environmental Standards, Herbicides, Method Specific, Oeko-Tex Standard 100, Pesticides, Pesticides & Metabolites, Phenoxy structure, Plant growth regulators
  • {SNA} Alphabetical Index of Analytical Standards, Method and Regulation Specific, All alphabetically sorted, Analytical Standards, Analytical/Chromatography, Chromatography, D, DIA - DIC, Environmental Standards,

产品应用

  • 为输异型芽后除草剂。对防除谷物地的蓼属杂草有效

相关文献及参考

  • Short: EINECS
  • Short: IV/8A
  • Merck: 14,3078

安全信息

Warnings IRRITANT 危化品目录(2015) 危险化学品
RTECSUF1050000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
WGK Germany2
Signal word Danger
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R38 Irritating to skin 刺激皮肤
Hazard Codes Xn Xn,Xi
Storage condition APPROX 4°C 储存温度2-8℃
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 309 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   RPZHAW Roczniki Panstwowego Zakladu Higieny.  (Ars Polona, POB 1001, 00-068
   Warsaw 1, Poland) V.1-    1950-  Volume(issue)/page/year: 31,373,1980

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 620 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - muscle contraction or spasticity
   Behavioral - coma
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 50(9),22,1985

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1400 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   28ZEAL "Pesticide Index," Frear, E.H., ed., State College, PA, College
   Science Pub., 1969  Volume(issue)/page/year: 5,76,1976

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 344 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology,
   Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128)  V.1-
   1990-  Volume(issue)/page/year: 1,177,1992

TYPE OF TEST            : LD5

TYPE OF TEST            : LC

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 700 mg/L
REFERENCE :
   ZAPOAK Zeitschrift fuer Allgemeine Mikrobiologie.  (Akademie-Verlag GmbH,
   Postfach 1233, Berlin DDR-1086 Ger. Dem. Rep.)  V.1-    1960-
   Volume(issue)/page/year: 9,483,1969

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 3 gm/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
REFERENCE :
   ARZNAD Arzneimittel-Forschung. Drug Research.  (Editio Cantor Verlag,
   Postfach 1255, W-7960 Aulendorf, Fed. Rep. Ger.)  V.1-    1951-
   Volume(issue)/page/year: 33,1479,1983

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 5 gm/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reprod

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 20 mg/kg
SEX/DURATION            : female 4-18 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
REFERENCE :
   TJADAB Teratology, The International Journal of Abnormal Development. (Alan
   R. Liss, Inc., 41 E. 11th St., New York, NY 10003)  V.1-    1968-
   Volume(issue)/page/year: 33,11A,1986

TYPE OF TE

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 4 gm/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   ARZNAD Arzneimittel-Forschung. Drug Research.  (Editio Cantor Verlag,
   Postfach 1255, W-7960 Aulendorf, Fed. Rep. Ger.)  V.1-    1951-
   Volume(issue)/page/year: 33,1479,1983

其他信息

  • 可燃性危险特性:受热分解有毒氯化物气体
  • 灭火剂:砂土、干粉、泡沫
  • 用途一:为输异型芽后除草剂。对防除谷物地的蓼属杂草有效。
  • 外观性质:纯品为无色无味结晶。
  • TCI Shanghai:2-(2,4-二氯苯氧基)丙酸 2-(2,4-Dichlorophenoxy)propionic Acid,>;98.0%(T)(120-36-5)
  • 类别:农药
  • 毒性分级:高毒
  • Sigma Aldrich:120-36-5(sigmaaldrich)
  • 上游原料:2,4-二氯酚 --> 2-氯丙酸
  • MSDS 信息:2-(2,4-二氯苯氧基)丙酸(120-36-5).msds
  • 图谱信息:2,4-滴丙酸(120-36-5)质谱(MS) 2,4-滴丙酸(120-36-5)红外图谱(IR2) 2,4-滴丙酸(120-36-5)红外图谱(IR1) 2,4-滴丙酸(120-36-5)核磁图( 13 CNMR)
  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 急性毒性:口服-大鼠 LD50: 344 毫克/公斤; 口服-小鼠 LD50: 309 毫克/公斤
  • 在20℃水中溶解度为350ppm,易溶于多数有机溶剂
  • 2,4-滴丙酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 D1942 2-(2,4-二氯苯氧基)丙酸 2-(2,4-Dichlorophenoxy)propionic Acid 25G 400元 2010/05/25 B24344 2-(2,4-二氯苯氧基)丙酸, 98% 2-(2,4-Dichlorophenoxy)propionic acid, 98% 500g 862元 2010/05/25 B24344 2-(2,4-二氯苯氧基)丙酸, 98% 2-(2,4-Dichlorophenoxy)propionic acid, 98% 100g 274元
  • 方法一:由2,4-二氯苯酚钠盐与α-氯代丙酸经缩合而得。该品为两个旋光异构体的混合物,但只有右旋异构体才有生物活性。
  • 下游产品:(R)-2-(2,4-二氯苯氧基)丙酸
  • MOL 文件:120-36-5.mol
  • Alfa Aesar:2-(2,4-二氯苯氧基)丙酸,98% 2-(2,4-Dichlorophenoxy)propionic acid, 98%(120-36-5)

系列性分类


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