N-Carbobenzyloxy-L-aspartic acid N-苄氧羰基-L-天冬氨酸

CAS 1152-61-0 MFCD00002719

化学结构图

1152-61-0
SMILES: O=C(O)C[C@H](NC(=O)OCc1ccccc1)C(=O)O

化学属性

Mol. FormulaC12H13NO6
Mol. Weight267.23
Density1.404
Melting Point117-119°C
TSCAYes
Refractive index9.5 ° (C=7, AcOH)
Boiling Point410.42 °C at 760 mmHg

别名和识别编码

Chemical NameN-Carbobenzyloxy-L-Aspartic Acid
MDL NumberMFCD00002719
CAS Number1152-61-0
EC Number214-568-4
Beilstein Registry Number2336722
Synonym Z-Asp-OH {LY} Z-Asp-OH {} {LY} Z-Asp-OH {} {} {LY} Z-Asp-OH {} {} {} {LY} Z-Asp-OH {} {} {} {} {LY} Z-Asp-OH {} {} {} {} {} {LY} Z-Asp-OH {} {} {} {} {} {} {LY} Z-Asp-OH {} {} {} {} {} {} {} {LY} Z-Asp-OH {} {} {} {} {} {} {} {} {LY} Z-Asp-OH {} {} {} {} {} {} {} {} {} {LY} Z-Asp-OH {} {} {} {} {} {} {} {} {} {} {LY} Z-Asp-OH {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Z-Asp-OH {} {} {} {} {} {} {} {} {} {} {} {} {LY} Z-Asp-OH {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Z-Asp-OH {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Z-Asp-OH {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Z-Asp-OH {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Z-Asp-OH {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Z-Asp-OH {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID2723942
Chemical Name TranslationN-苄氧羰基-L-天冬氨酸
Reaxys-RN2336722
LabNetwork Molecule IDLN00190291
InChIInChI=1S/C12H13NO6/c14-10(15)6-9(11(16)17)13-12(18)19-7-8-4-2-1-3-5-8/h1-5,9H,6-7H2,(H,13,18)(H,14,15)(H,16,17)/t9-/m0/s1
Canonical SMILESO=C(O)C[C@@H](C(O)=O)NC(OCC1=CC=CC=C1)=O
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分类

  • {SNA} Amino Acid Derivatives, Aspartic Acid, Chemical Biology, Chemical Synthesis, Peptide Chemistry
  • {SNA} Amino Acids & Derivatives, Aspartic Acid, Chemical Biology, Chemical Synthesis, Peptide Chemistry

产品应用

  • 用于生化试剂，多肽合成。

相关文献及参考

  • Beilstein: 6,IV,2395

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
Storage condition 2-8°C {LY} 2-8°C Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°

其他信息

  • 图谱信息:N-CBZ-L-天冬氨酸(1152-61-0)核磁图( 13 CNMR) N-CBZ-L-天冬氨酸(1152-61-0)质谱(MS) N-CBZ-L-天冬氨酸(1152-61-0)Raman光谱 N-CBZ-L-天冬氨酸(1152-61-0)核磁图( 1 HNMR) N-CBZ-L-天冬氨酸(1152-61-0)红外图谱(IR2) N-CBZ-L-天冬氨酸(1152-61-0)红外图谱(IR1)
  • Sigma Aldrich:1152-61-0(sigmaaldrich)
  • 用途一:用于生化试剂，多肽合成。
  • Acros Organics:N-苄氧羰基-L-天冬氨酸 N-Carbobenzyloxy-L-aspartic acid, 98%(1152-61-0)
  • 比旋光度:10.5 ° (c=1,AcOH)
  • 检测方法:T,NMR
  • MOL 文件:1152-61-0.mol
  • TCI Shanghai:N-苄氧羰基-L-天冬氨酸 N-Carbobenzoxy-L-aspartic Acid,>;99.0%(T)(1152-61-0)
  • MSDS 信息:N-(Benzyloxycarbonyl)-L-aspartic acid(1152-61-0).msds
  • Alfa Aesar:N-苄氧羰基-L-天冬氨酸,98+% N-Benzyloxycarbonyl-L-aspartic acid, 98+%(1152-61-0)
  • N-CBZ-L-天冬氨酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C0629 N-苄氧羰基-L-天冬氨酸 N-Carbobenzoxy-L-aspartic Acid 5G 260元 2014/06/02 C0629 N-苄氧羰基-L-天冬氨酸 N-Carbobenzoxy-L-aspartic Acid 25G 759元 2010/06/21 172051000 N-CBZ-L-天冬氨酸 N-Carbobenzyloxy-L-aspartic acid 98% 100 GR 2707元
  • 溶于大多数常规有机溶剂。
  • 外观性质:白色粉末状晶体，溶于大多数常规有机溶剂。熔点:116 °C [α]20D 9.5 °(c=2, AcOH)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Amino Acid Derivatives 氨基酸及其衍生物
  5. Aspartic Acid - Amino Acid Derivatives
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Amino Acids 氨基酸
  4. Modified Amino Acids - Amino Acids
  5. Cbz-amino Acids
  1. Life Science 生命科学
  2. Biochemistry / Glyco-Chemistry
  3. Protected & Labeled Amino Acids

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