2-Hydroxyethyl methacrylate 甲基丙烯酸羟乙酯

CAS 868-77-9 MFCD00002863

化学结构图

868-77-9
SMILES: C=C(C)C(=O)OCCO

化学属性

Mol. FormulaC6H10O3
Mol. Weight130.14
Refractive index1.4490 to 1.4540
Boiling Point67 °C at 3.5 mmHg
Density1.073
Flash Point107°C(lit.)
TSCAYes
Melting Point-12 °C
Vapor Density5 (vs air)
Vapor Pressure0.01 mmHg ( 25 °C)
Solubility可溶
Stability对光线敏感

别名和识别编码

Chemical Name2-Hydroxyethyl methacrylate
CAS Number868-77-9
Synonym 2-Hydroxyethyl methacrylate {LY} 2-Hydroxyethyl methacrylate {} {LY} 2-Hydroxyethyl methacrylate {} {} {LY} 2-Hydroxyethyl methacrylate {} {} {} {LY} 2-Hydroxyethyl methacrylate {} {} {} {} {LY} 2-Hydroxyethyl methacrylate {} {} {} {} {} {LY} 2-Hydroxyethyl methacrylate {} {} {} {} {} {} {LY} 2-Hydroxyethyl methacrylate {} {} {} {} {} {} {} {LY} 2-Hydroxyethyl methacrylate {} {} {} {} {} {} {} {} {LY} 2-Hydroxyethyl methacrylate {} {} {} {} {} {} {} {} {} {LY} 2-Hydroxyethyl methacrylate {} {} {} {} {} {} {} {} {} {} {LY} 2-Hydroxyethyl methacrylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Hydroxyethyl methacrylate {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Hydroxyethyl methacrylate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Hydroxyethyl methacrylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Hydroxyethyl methacrylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Hydroxy
PubChem Substance ID13360
Beilstein Registry Number1071583
MDL NumberMFCD00002863
EC Number212-782-2
Reaxys-RN1071583
Chemical Name Translation甲基丙烯酸羟乙酯
Wiswesser Line NotationQ2OVY1&U1
LabNetwork Molecule IDLN00163931
InChIInChI=1S/C6H10O3/c1-5(2)6(8)9-4-3-7/h7H,1,3-4H2,2H3
Canonical SMILESCC(C(OCCO)=O)=C
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分类

  • {SNA} 3D Printing Materials for Research and Deve
  • Acrylic Monomers, Building Blocks, C6 to C7, Carbonyl Compounds, Chemical Synthesis,
  • {SNA} Acrylic Monomers, Building Blocks, C6 to C7, Carbonyl Compounds, Chemical Synthesis, Esters, Materials Science, Methacrylate, Monomers, Organic Building Blocks, Polymer Science
  • {SNA} 3D Printing Materials for Research and Development, Acrylic Monomers, Building Blocks, C6 to C7, Carbonyl Compounds, Chemical Synthesis, Esters, Methacrylate, Monomers, Monomers and Polymerization Tools for 3D Printing,

产品应用

  • 甲基丙烯酸羟乙酯是一种官能单体,供制备热固性丙烯酸涂料丁苯橡胶乳液改性剂。丙烯酸改性聚氨酯涂料,水溶性电镀涂料粘合剂,纤维整理剂,纸品涂料,感光涂料及聚氯乙烯树脂改性剂等物质用的各种树脂,用途广泛。

相关文献及参考

  • Delbressine, L., et al.: Xenobiotica, 11, 241 (1981),
  • Gerberick, G., et al.: Toxicol. Sci., 97, 417 (2007),
  • Beil. 2 ,IV,1530
  • Aldrich MSDS 1 , 1059:B / Corp MSDS 1 (1), 1922:D / FT-IR 1 (1), 665:B / FT-IR 2 (1), 1090:B / FT-NMR 1 (1), 1045:A / IR-Spectra (3), 390:A / IR-Spectra (2), 345:F / NMR-Reference 2 (1), 560:C / RegBook 1 (1), 753:M / Sax 6 , 1344 / Sigma FT-IR 1 (2), 625:D / Structure Index 1 , 116:A:9 / Vapor Phase 3 , 720:D

安全信息

GHS Symbol
WGK Germany1
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H319 Causes serious eye irritation 严重刺激眼睛
Hazard Codes Xi
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352+P333+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P333+P313
  • P337+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
RTECSOZ4725000
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light Air Sensitive {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 99200 nL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPMSAE Journal of Pharmaceutical Sciences.  (American Pharmaceutical Assoc.,
   2215 Constitution Ave., NW, Washington, DC 20037)  V.50-    1961-
   Volume(issue)/page/year: 63,376,1974

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 497 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPMSAE Journal of Pharmaceutical Sciences.  (American Pharmaceutical Assoc.,
   2215 Constitution Ave., NW, Washington, DC 20037)  V.50-    1961-
   Volume(issue)/page/year: 62,778,1973

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMPMAR Archives des Maladies Professionnelles de Medecine du Travail et de
   Securite Sociale.  (SPPIF, B.P.22, F-41353 Vineuil, France)  V.7-    1946-
   Volume(issue)/page/year: 36,58,1975

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 4680 mg/kg
TOXIC EFFECTS :
   Behavioral - coma
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 1130

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 3062 mg/kg
SEX/DURATION            : male 35 week(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Fertility - pre-implantation mortality (e.g. reduction in
   number of implants per female; total number of implants per corpora lutea)
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Effects on Embryo or Fetus - fetal death
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 52(11),81,1987

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 3062 mg/kg
SEX/DURATION            : female 35 week(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
   Reproductive - Effects on Embryo or Fetus - fetal death
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 52(11),81,1987

其他信息

  • TCI Shanghai:甲基丙烯酸-2-羟基乙酯(含稳定剂甲氧基氢醌) 2-Hydroxyethyl Methacrylate (stabilized with MEHQ),>;95.0%(GC)(868-77-9)
  • 海关编码:29161490
  • 方法一:1.由环氧乙烷与甲基丙烯酸反应而得。在甲基丙烯酸中加入硫氰酸铁、四甲基氯化铵等及少许对苯二酚,搅拌加热至90℃,在氮气保护下,通入环氧乙烷气体反应约2h。将反应产物冷至60℃,加少量对苯二酚后减压蒸馏,收集86-89℃(0.67kPa)馏分即得成品,收率80%以上。2.甲基丙烯酸钾盐与氯乙醇在阻聚剂存在下反应生成粗甲基丙烯酸-2-羟基乙酯,经盐析、精制得成品。
  • 用途二:主要用于树脂及涂料的改性。与其他丙烯酸类单体共聚,可制得侧链含有活性羟基的丙烯酸树脂,可进行酯化反应和交联反应,合成不溶性树脂和提高粘接性,可用作纤维处理剂等。与三聚氰胺-甲醛(或脲醛)树脂、环氧树脂等共同反应,用于制造双组分涂料。加入高级轿车油漆中,可长期保持镜面光泽。还可用作合成纺织物的胶粘剂和医用高分子单体等。
  • 甲基丙烯酸羟乙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30039880 4-氯-3,5-二硝基苯甲酸;3,5-二硝基-4-氯苯甲酸 10g 114元 2011/08/23 30039881 4-氯-3,5-二硝基苯甲酸;3,5-二硝基-4-氯苯甲酸 25g 300.3元 2011/08/23 TM008501 甲基丙烯酸-2-羟乙酯 500g 360元
  • 图谱信息:甲基丙烯酸羟乙酯(868-77-9)红外图谱(IR1) 甲基丙烯酸羟乙酯(868-77-9)Raman光谱 甲基丙烯酸羟乙酯(868-77-9)质谱(MS) 甲基丙烯酸羟乙酯(868-77-9)红外图谱(IR2)
  • F:8
  • 蒸气密度:5 (vs air)
  • 易燃,溶于水,溶于通常的有机溶液剂,极易聚合
  • 外观性质:无色透明液体。
  • 蒸气压:0.01 mm Hg ( 25 °C)
  • 用途三:甲基丙烯酸羟乙酯是一种官能单体,供制备热固性丙烯酸涂料丁苯橡胶乳液改性剂。丙烯酸改性聚氨酯涂料,水溶性电镀涂料粘合剂,纤维整理剂,纸品涂料,感光涂料及聚氯乙烯树脂改性剂等物质用的各种树脂,用途广泛。
  • Sigma Aldrich:868-77-9(sigmaaldrich)
  • Alfa Aesar:2-羟基乙基甲基丙烯酸盐,97%,stab.withca500ppm4-methoxyphenol 2-Hydroxyethyl methacrylate, 97%, stab. with ca 500ppm 4-methoxyphenol(868-77-9)
  • 上游原料:曙光红(四溴荧光素) --> 1,4-苯二酚 --> 2-氯乙醇 --> 2-甲基丙烯酸 --> 阻聚剂 --> 四甲基氯化铵
  • MSDS 信息:甲基丙烯酸2-羟乙酯(868-77-9).msds
  • 检测方法:GC,NMR
  • Acros Organics:甲基丙烯酸2-羟乙酯 2-Hydroxyethyl methacrylate, stabilized, 96%(868-77-9)
  • MOL 文件:868-77-9.mol
  • 用途一:用于合成医用高分子材料、热固性涂料及粘合剂等
  • 敏感性:Air Sensitive

系列性分类


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