Crotyl alcohol 巴豆醇

CAS 6117-91-5 MFCD00002923

化学结构图

6117-91-5
SMILES: CC=CCO

化学属性

Mol. FormulaC4H8O
Mol. Weight72.11
Density0.845 g/mL at 25 °C(lit.)
Refractive index1.4270 to 1.4310
Flash Point-
TSCAYes
Boiling Point
Solubility溶于水、乙醇、乙醚。
pH:A
Melting PointNo Data Available

别名和识别编码

Chemical NameCrotyl Alcohol
Synonym 1-Hydroxy-2-butene 2-Butene-1-ol 2-Butenol 2-Butenyl alcohol 2-buten-1-ol (crotyl alcohol) 2-butenylalcohol 2-丁烯-1-醇 2-丁烯-1-醇, CIS + TRANS (CA 1:19) 2-丁烯-1-醇,(正+反) 2-丁烯醇 3-METHYLALLYL ALCOHOL trans-but-2-en-1-ol CH3CH=CHCH2OH CROTONYL ALCOHOL CROTYL ALCOHOL Crotonyl alcoho1 Crotonyl alcohol Crotyl Alcohol (cis/trans Mixture) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL Number-
CAS Number6117-91-5
EC Number228-086-7
Merck Number2601
Beilstein Registry Number1361395
PubChem Substance ID637922
Reaxys-RN1719374
Chemical Name Translation巴豆醇
Wiswesser Line NotationQ2U2
InChIInChI=1S/C4H8O/c1-2-3-4-5/h2-3,5H,4H2,1H3/b3-2+
Canonical SMILESC/C=C/CO
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分类

  • {SNA} Acyclic, Alkenes, Building Blocks, Chemical Synthesis, Organic Building Blocks
  • {uni_hamburg} no charge; alcohol; 1fragment

产品应用

  • 用于有机合成,制造增塑剂、土壤熏蒸剂、除草剂、医药、涂料等。

相关文献及参考

  • Short: II/25C
  • Merck: 14,2601
  • Merck: 14,2601 Beilstein:1(1)227
  • Short: III/38B

安全信息

RTECSEM9275000
Packing GroupIII
UN Number 1987 UN1987 UN 1987 3/PG 3
Risk Statements
  • R10 Flammable 易燃
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S7 Keep container tightly closed 保存在严格密闭容器中;
GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H302+H312
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P312+P330
  • P301+P317
  • P302+P352
  • P302+P352+P312+P362+P364
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Hazard Codes 3 Xn Xn,F
Hazard Class3
Storage condition +4°C 4 4℃ Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Warnings 危化品目录(2015)
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 1084 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   23,95,1962

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 793 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   23,95,1962

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2000 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   23,95,1962

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 10 ug/plate
REFERENCE :
   TCMUD8 Teratogenesis, Carcinogenesis, and Mutagenesis.  (Alan R. Liss, Inc.,
   41 E. 11th St., New York, NY 10003)  V.1-    1980- Volume(issue)/page/year:
   1,259,1980

Restrict 危险品

其他信息

  • MOL 文件:6117-91-5.mol
  • Acros Organics:巴豆醇(2-丁烯-1-醇) Crotyl alcohol, cis and trans mixture, 90%(6117-91-5)
  • 毒性分级:中毒
  • Alfa Aesar:2-丁烯-1-醇,cis+trans(ca1:19),96% 2-Buten-1-ol, cis + trans (ca 1:19), 96%(6117-91-5)
  • Sigma Aldrich:6117-91-5(sigmaaldrich)
  • 类别:易燃液体
  • 巴豆醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0696 巴豆醇(顺反异构体混和物) Crotyl Alcohol (cis- and trans- mixture) 500ML 3260元 2014/06/02 B0696 巴豆醇(顺反异构体混和物) Crotyl Alcohol (cis- and trans- mixture) 25ML 370元 2010/06/21 405791000 巴豆醇 Crotyl alcohol 90%, cis and trans mixture 100 GR 1333元
  • 储运特性:库房通风低温干燥; 与氧化剂分开存放
  • 方法一:由乙醛缩合而得丁醇醛,再经脱水、加氢而得。
  • 外观性质:无色液体,有特殊气味。
  • TCI Shanghai:巴豆醇(顺反异构体混合物) Crotyl Alcohol (cis- and trans- mixture),>;95.0%(GC)(6117-91-5)
  • 灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
  • 水中溶解度: 166 g/L (20°C)。能与醇和醚混溶,溶于6份水中。
  • 用途一:用于有机合成,制造增塑剂、土壤熏蒸剂、除草剂、医药、涂料等。
  • 上游原料:3-羟基丁醛
  • 可燃性危险特性:遇明火、高温、氧化剂较易燃; 燃烧产生刺激烟雾
  • 急性毒性:口服- 大鼠 LD50: 930 毫克/ 公斤
  • Hazard Note:Harmful/Highly Flammable
  • MSDS 信息:2-丁烯醇(6117-91-5).msds

系列性分类


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