Tetraphenylgermane 四苯基锗
CAS 1048-05-1 MFCD00002997
化学结构图
SMILES: c1ccc([Ge](c2ccccc2)(c2ccccc2)c2ccccc2)cc1
化学属性
| Mol. Formula | C24H20Ge |
|---|---|
| Mol. Weight | 381.06 |
| TSCA | Yes |
| Melting Point | 230-235 °C |
| Refractive index | 1.5800 |
| Boiling Point | >400 °C at 760 mmHg |
别名和识别编码
| Chemical Name | Tetraphenylgermane |
|---|---|
| Synonym | Tetraphenylgermane {LY} Tetraphenylgermane tetraphenylgermane {} {LY} Tetraphenylgermane {} {} {LY} Tetraphenylgermane {} {} {} {LY} Tetraphenylgermane {} {} {} {} {LY} Tetraphenylgermane {} {} {} {} {} {LY} Tetraphenylgermane {} {} {} {} {} {} {LY} Tetraphenylgermane {} {} {} {} {} {} {} {LY} Tetraphenylgermane {} {} {} {} {} {} {} {} {LY} Tetraphenylgermane {} {} {} {} {} {} {} {} {} {LY} Tetraphenylgermane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetraphenylgermane {} {} {} {} {} {} {} {} {} {} {} {LY} Tetraphenylgermane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetraphenylgermane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetraphenylgermane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetraphenylgermane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetraphenylgermane {} {} {} {} {} {} {} {} {} {} {} |
| MDL Number | MFCD00002997 |
| CAS Number | 1048-05-1 |
| EC Number | 213-880-8 |
| Reaxys-RN | 3209581 |
| PubChem Substance ID | 66103 |
| Chemical Name Translation | 四苯基锗 |
| InChIKey | ILEXMONMGUVLRM-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN01246913 |
| InChI | InChI=1S/C24H20Ge/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24/h1-20H |
| Canonical SMILES | C1([Ge](C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4)=CC=CC=C1 |
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分类
- {uni_hamburg} no charge; metal-organic; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Germanium
相关文献及参考
- Short: II/25D Title: Structure Data of Free Polyatomic Molecules: Molecules Containing Five or More Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25D Year: 2003 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-42860-7 ISBN: 978-3-540-42860-2 Internet Resource: DOI:10.1007/b75952 RefComment: VIII, 569 pages. Hardcover RefComment: Written for scientists and researchers in the fields of chemistry and physics Abstract: This fourth subvolume presents data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc) of free polyatomic molecules including free radicals and molecular ions. The survey on structure data consists of four subvolumes, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this fourth subvolume, the structure of molecules containing five to sixty carbon atoms is listed.
- Short: II/3 Title: Luminescence of Organic Substances Author: Schmillen, A.; Legler, R. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/3 Year: 1967 ISBN: 3-540-03895-7 ISBN: 978-3-540-03895-5 Internet Resource: DOI:10.1007/b86158 RefComment: 270 figs., VIII, 416 pages. Hardcover Abstract: For more than 1000 luminescent organic substances the most important data are represented as wave numbers of absorption and emission bands, decay times and quantum efficiencies. Additional tabl
安全信息
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P264+P265
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P312
- P301+P317
- P302+P350
- P302+P352
- P302+P352+P332+P313+P362+P364
- P304+P312
- P304+P340
- P305+P351+P338
- P305+P351+P338+P337+P313
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P317
- P319
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
- P330 Rinse mouth. 漱口
- P332+P313
- P332+P317
- P337+P313
- P337+P317
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P362+P364
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H302 Harmful if swallowed 吞食有害
- H312 Harmful in contact with skin 皮肤接触有害
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H332 Harmful if inhaled 吸入有害
- H335 May cause respiratory irritation 可能导致呼吸道刺激
其他信息
- 四苯基锗价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1159 四苯基锗 Tetraphenylgermane 1G 364元 2010/05/25 35842 四苯基锗, 98% Tetraphenylgermanium, 98% 2g 371元 2010/05/25 35842 四苯基锗, 98% Tetraphenylgermanium, 98% 10g 1596元
- Alfa Aesar:四苯基锗,98% Tetraphenylgermanium, 98%(1048-05-1)
- TCI Shanghai:四苯基锗 Tetraphenylgermane,>;95.0%(GC)(1048-05-1)
- TSCA:Yes
- 图谱信息:四苯基锗(1048-05-1)质谱(MS)
- MOL 文件:1048-05-1.mol
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