Diphenylmercury 二苯基汞

CAS 587-85-9 MFCD00002998

化学结构图

587-85-9
SMILES: c1ccc([Hg]c2ccccc2)cc1

化学属性

Mol. FormulaC12H10Hg
Mol. Weight354.81
Density2.318
Melting Point124-125°
TSCAYes
Boiling Point>306° dec.
Flash Point>306°C
Solubility不溶于水，微溶于乙醇、热醇，溶于氯仿、苯、二硫化碳。

别名和识别编码

Chemical NameDiphenylmercury
Synonym Benzene, mercuriodi- DIPHENYLMERCURY DIPHENYLMERCURY PESTANAL, 250 MG Difenylrtut Diphenyl mercury (aryl compound) Diphenylmercure Diphenylmercury {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00002998
CAS Number587-85-9
PubChem Substance ID24853735
Beilstein Registry Number0637234
EC Number209-606-1
Chemical Name Translation二苯基汞
Wiswesser Line NotationR-HG-R
LabNetwork Molecule IDLN04547237
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分类

  • {uni_hamburg} no charge; metal-organic; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Mercury

相关文献及参考

  • Short: II/25D Title: Structure Data of Free Polyatomic Molecules: Molecules Containing Five or More Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25D Year: 2003 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-42860-7 ISBN: 978-3-540-42860-2 Internet Resource: DOI:10.1007/b75952 RefComment: VIII, 569 pages. Hardcover RefComment: Written for scientists and researchers in the fields of chemistry and physics Abstract: This fourth subvolume presents data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc) of free polyatomic molecules including free radicals and molecular ions. The survey on structure data consists of four subvolumes, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this fourth subvolume, the structure of molecules containing five to sixty carbon atoms is listed.
  • Short: III/35D5 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Carbon-13, Part 5: Organometallic Compounds Author: Mikhova, Bozhana Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35D5 Year: 2008 Keyword: Carbon-13; chemical shift; magnetic properties of nuclei; nuclear magnetic resonance data ISBN: 978-3-540-74188-6 (print) ISBN: 978-3-540-74189-3 (electronic) Internet Resource: DOI:10.1007/978-3-540-74189-3 RefComment: VIII, 241 p., Hardcover RefComment: Written

安全信息

WGK Germany3
RTECSOW3150000
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P301+P310
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
Hazard statements
  • H330 Fatal if inhaled 吸入致命
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H310 Fatal in contact with skin 皮肤接触致命
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H300 Fatal if swallowed 吞食致命
  • H300+H310+H330
GHS Symbol
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Signal word Danger
Safety Statements
  • S13 Keep away from food, drink and animal foodstuffs 远离食品、饮料和动物饲料保存；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Packing GroupII
UN Number UN 2026 6.1/PG 3 UN2026
Risk Statements
  • R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有剧毒
  • R50/53
  • R33 Danger of cumulative effects 有累积作用的危险
Hazard Codes T+,N
Hazard Class6.1
Storage condition Poison room
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 50 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NCNSA6 National Academy of Sciences, National Research Council,
   Chemical-Biological Coordination Center, Review.  (Washington, DC)
   Volume(issue)/page/year: 5,30,1953

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NCNSA6 National Academy of Sciences, National Research Council,
   Chemical-Biological Coordination Center, Review.  (Washington, DC)
   Volume(issue)/page/year: 5,30,1953

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 250 mg/kg
TOXIC EFFECTS :
   Behavioral - altered sleep time (including change in righting reflex)
   Behavioral - ataxia
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 4,231,1952

其他信息

  • Sigma Aldrich:587-85-9(sigmaaldrich)
  • MSDS 信息:二苯基汞(587-85-9).msds
  • 类别:农药
  • 职业标准:TLV-TWA 0.05 毫克 (汞)/ 立方米
  • MOL 文件:587-85-9.mol
  • 毒性分级:高毒
  • 可燃性危险特性:明火可燃; 高热分解有毒含汞化物烟雾
  • 急性毒性:口服- 大鼠 LDL0: 500 毫克/ 公斤; 腹腔-小鼠 LDL0: 250 毫克/公斤
  • Alfa Aesar:二苯基汞 Diphenylmercury(587-85-9)
  • 图谱信息:二苯基汞(587-85-9)质谱(MS) 二苯基汞(587-85-9)核磁图( 13 CNMR) 二苯基汞(587-85-9)Raman光谱 二苯基汞(587-85-9)核磁图( 1 HNMR) 二苯基汞(587-85-9)红外图谱(IR2) 二苯基汞(587-85-9)红外图谱(IR1)
  • 储运特性:库房通风低温干燥; 与氧化剂、食品添加剂、酸类分开存放
  • Acros Organics:二苯基汞 Diphenylmercury, 99%(587-85-9)
  • 灭火剂:泡沫、雾状水、砂土
  • 外观性质:白色结晶。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Mercury - Catalysis and Inorganic Chemistry
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organomercury - Organometallic Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Amines - Chemical Class
  5. Aromatics - Amines
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. D - Alphabetic
  5. DIO - DIZ - D

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