Triphenyltin Hydride 三苯基氢化锡

CAS 892-20-6 MFCD00003004

化学结构图

892-20-6
SMILES: C1CCC([SnH](C2CCCCC2)C2CCCCC2)CC1

化学属性

Mol. FormulaC18H16Sn
Mol. Weight351.03
Refractive indexn20/D 1.632(lit.)
Boiling Point163-165 °C at 0.3 mmHg
Density1.374 g/mL at 25 °C(lit.)
Melting Point28 °C
Flash Point>110°(230°F)
TSCANo

别名和识别编码

Chemical NameTriphenyltin Hydride
Synonym Triphenyltin hydride {LY} Triphenyltin hydride {} {LY} Triphenyltin hydride {} {} {LY} Triphenyltin hydride {} {} {} {LY} Triphenyltin hydride {} {} {} {} {LY} Triphenyltin hydride {} {} {} {} {} {LY} Triphenyltin hydride {} {} {} {} {} {} {LY} Triphenyltin hydride {} {} {} {} {} {} {} {LY} Triphenyltin hydride {} {} {} {} {} {} {} {} {LY} Triphenyltin hydride {} {} {} {} {} {} {} {} {} {LY} Triphenyltin hydride {} {} {} {} {} {} {} {} {} {} {LY} Triphenyltin hydride {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenyltin hydride {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenyltin hydride {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenyltin hydride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenyltin hydride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenyltin hydride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00003004
CAS Number892-20-6
PubChem Substance ID24854702
EC Number212-967-8
Beilstein Registry Number3544353
Chemical Name Translation三苯基氢化锡
LabNetwork Molecule IDLN02145090
Canonical SMILESC1([SnH](C2=CC=CC=C2)C3=CC=CC=C3)=CC=CC=C1
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分类

  • {SNA} Chemical Synthesis, Organometallic Reagents, Organotin, Organotins, Reduction, Synthetic Reagents, Tin Hydrides
  • {uni_hamburg} no charge; metal-organic; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

相关文献及参考

  • For general reactions of organotin hydrides, see Tri-n-butyl­tin hydride, A13298.
  • 2-(Bromomethyl)penicillin V methyl ester undergoes ring-expansion via the methylene radical, to give the corresponding cepham: Tetrahedron, 44, 5953 (1988):
  • Short: III/35C4
  • Hydrostannylation of terminal alkynes is conveniently carried out in the presence of triethylboron. Reaction is faster than with tributyl tin hydride and gives higher yields. Stereoselectivity varies from 69-100% (E): Tetrahedron, 45, 923 (1989):
  • Short: EINECS
  • Reagent for free-radical desulfurization of the thionocarbonates of 1,2-diols to the corresponding methylenedioxy compounds: J. Org. Chem., 62, 1690 (1997).
  • Reagent for free-radical desulfurization of the thionocarbonates of 1,2-diols to the correspond

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H331 Toxic if inhaled 吸入中毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301 Toxic if swallowed 吞食有毒
  • H301+H311+H331
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Precautionary statements
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P301+P310
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P301+P310+P330
  • P304+P340+P312
  • P302+P352+P312
Signal word Danger
RTECSWH8882000
Packing GroupIII
UN Number UN 3077 9/PG 3 UN3146
Risk Statements
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
  • R50/53
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S27/28
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen Air & Moisture Sensitive {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Hazard Codes T,N
Hazard Class6.1
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 81 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,591,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 7900 ug/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,591,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 491 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,591,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 8500 ug/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,591,1969

其他信息

  • MOL 文件:892-20-6.mol
  • Acros Organics:三苯基氢化锡 Triphenyltin hydride, 95%(892-20-6)
  • Alfa Aesar:三苯基氢化锡,97% Triphenyltin hydride, 97%(892-20-6)
  • 三苯基锡化氢价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 223780250 三苯基锡化氢 Triphenyltin hydride 95% 25 GR 2423元 2010/05/25 L00163 三苯基氢化锡, 97% Triphenyltin hydride, 97% 5g 605元 2010/05/25 L00163 三苯基氢化锡, 97% Triphenyltin hydride, 97% 25g 1890元
  • TSCA:No
  • Sigma Aldrich:892-20-6(sigmaaldrich)
  • 敏感性:Moisture Sensitive

系列性分类


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