N-(Triphenylphosphoranylidene)Aniline 四苯基氨化膦
CAS 2325-27-1 MFCD00003044
化学结构图
SMILES: c1ccc(N=P(c2ccccc2)(c2ccccc2)c2ccccc2)cc1
化学属性
| Mol. Formula | C24H20NP |
|---|---|
| Mol. Weight | 353.40 |
| Melting Point | 130 °C |
| TSCA | No |
别名和识别编码
| Chemical Name | N-(Triphenylphosphoranylidene)Aniline |
|---|---|
| Synonym | N,1,1,1-tetraphenyl-lambda5-phosphanimine {LY} N,1,1,1-tetraphenyl-lambda5-phosphanimine {} {LY} N,1,1,1-tetraphenyl-lambda5-phosphanimine {} {} {LY} N,1,1,1-tetraphenyl-lambda5-phosphanimine {} {} {} {LY} N,1,1,1-tetraphenyl-lambda5-phosphanimine {} {} {} {} {} {} {} {} {LY} N,1,1,1-tetraphenyl-lambda5-phosphanimine {} {} {} {} {} {LY} N,1,1,1-tetraphenyl-lambda5-phosphanimine {} {} {} {} {} {} {LY} N,1,1,1-tetraphenyl-lambda5-phosphanimine {} {} {} {} {} {} {} {LY} N,1,1,1-tetraphenyl-lambda5-phosphanimine {} {} {} {} {} {} {} {} {LY} N,1,1,1-tetraphenyl-lambda5-phosphanimine {} {} {} {} {} {} {} {} {} {LY} N,1,1,1-tetraphenyl-lambda5-phosphanimine {} {} {} {} {} {} {} {} {} {} {LY} N,1,1,1-tetraphenyl-lambda5-phosphanimine {} {} {} {} {} {} {} {} {} {} {} {LY} N,1,1,1-tetraphenyl-lambda5-phosphanimine {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,1,1,1-tetraphenyl-lambda5-phosphanimine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,1,1,1-tetraphenyl-lambda5-phospha |
| MDL Number | MFCD00003044 |
| PubChem Substance ID | 75352 |
| CAS Number | 2325-27-1 |
| EC Number | 219-039-1 |
| Beilstein Registry Number | 753032 |
| Chemical Name Translation | 四苯基氨化膦 |
| InChIKey | PTLOPIHJOPWUNN-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN02145103 |
| InChI | InChI=1S/C24H20NP/c1-5-13-21(14-6-1)25-26(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24/h1-20H |
| Canonical SMILES | C1=CC=C(C=C1)N=P(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4 |
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分类
- {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Others, Phosphorus Compounds
- {SA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Others, Phosphorus Compounds
- {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Other Phosphorus Compounds, Phosphorus Compounds
相关文献及参考
- Beil. 16 ,I,423
- FT-IR 2 (2), 3343:C / FT-NMR 1 (2), 1681:C / RegBook 1 (2), 2281:M / Structure Index 1 , 357:D:5
- Has been used as a protected form of aniline for the preparation of monoalkylanilines by alkylation and hydrolysis: Synthesis, 295 (1980).
- A Wittig-like reaction with N,N'-diaryl thioureas gives N,N',N"-triarylguanidines: Synth. Commun., 13, 67 (1983).
- For a review of the chemistry of iminophosphoranes, see: Synthesis, 469 (1973).
- Has been used as a protected form of aniline for the preparation of monoalkylanilines by alkylation and hydrolysis: Synthesis, 295 (1980).
- A Wittig-like reaction with N,N'-diaryl thioureas gives N,N',N"-triarylguanidines: Synth. Commun., 13, 67 (1983).
- For a review of the chemistry of iminophosphoranes, see: Synthesis, 469 (1973).
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352
- P304+P340
- P305+P351+P338
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P332+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
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