Cis-1,2-Bis(Diphenylphosphino)Ethylene 顺-1,2-双(二苯基膦)乙烯

CAS 983-80-2 MFCD00003046

化学结构图

983-80-2
SMILES: C(=C\P(c1ccccc1)c1ccccc1)\P(c1ccccc1)c1ccccc1

化学属性

Mol. Formula(C6H5)2PCH=CHP(C6H5)2
Mol. Weight396.40
Melting Point122-124 °C(lit.)
TSCANo
Appearance white xtl.
Boiling Point546.8 °C at 760 mmHg

别名和识别编码

Chemical NameCis-1,2-Bis(Diphenylphosphino)Ethylene
MDL NumberMFCD00003046
CAS Number983-80-2
Synonym (Z)-1,2-Bis(diphenylphosphino)ethene {LY} (Z)-1,2-Bis(diphenylphosphino)ethene {} {LY} (Z)-1,2-Bis(diphenylphosphino)ethene {} {} {LY} (Z)-1,2-Bis(diphenylphosphino)ethene {} {} {} {LY} (Z)-1,2-Bis(diphenylphosphino)ethene {} {} {} {} {LY} (Z)-1,2-Bis(diphenylphosphino)ethene {} {} {} {} {} { {} {} {} {} {} {LY} (Z)-1,2-Bis(diphenylphosphino)ethene {} {} {} {} {} {} {LY} (Z)-1,2-Bis(diphenylphosphino)ethene {} {} {} {} {} {} {} {LY} (Z)-1,2-Bis(diphenylphosphino)ethene {} {} {} {} {} {} {} {} {LY} (Z)-1,2-Bis(diphenylphosphino)ethene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Z)-1,2-Bis(diphenylphosphino)ethene {} {} {} {} {} {} {} {} {} {} {LY} (Z)-1,2-Bis(diphenylphosphino)ethene {} {} {} {} {} {} {} {} {} {} {} {LY} (Z)-1,2-Bis(diphenylphosphino)ethene {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Z)-1,2-Bis(diphenylphosphino)ethene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Z)-1,2-Bis(diphenylphosphino)ethene {} {} {} {} {} {} {} {} {} {} {} {
PubChem Substance ID2733415
EC Number213-569-7
Beilstein Registry Number757792
Chemical Name Translation顺-1,2-双(二苯基膦)乙烯
InChIKeyNCKJIJSEWKIXAT-DQRAZIAOSA-N
LabNetwork Molecule IDLN01066874
InChIInChI=1S/C26H22P2/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26/h1-22H/b22-21-
Canonical SMILESP(C1=CC=CC=C1)(C2=CC=CC=C2)/C=C\P(C3=CC=CC=C3)C4=CC=CC=C4
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Polydentate Phosphine Ligands

相关文献及参考

  • Chelating ligand.

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Air Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from lig
Hazard Codes Xi

其他信息

  • MOL 文件:983-80-2.mol
  • 敏感性:Air Sensitive
  • Sigma Aldrich:983-80-2(sigmaaldrich)
  • Alfa Aesar:顺-1,2-双(二苯基膦)乙烯,97% cis-1,2-Bis(diphenylphosphino)ethylene, 97%(983-80-2)
  • 顺-1,2-双(二苯基膦)乙烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 320890050 顺-1,2-双(二苯基膦)乙烯 cis-1,2-Bis(diphenylphosphino)ethylene 98% 5 GR 3294元 2010/06/21 320890010 顺-1,2-双(二苯基膦)乙烯 cis-1,2-Bis(diphenylphosphino)ethylene 98% 1 GR 771元 2010/05/25 A16859 顺-1,2-双(二苯基膦)乙烯, 97% cis-1,2-Bis(diphenylphosphino)ethylene, 97% 5g 2268元
  • Acros Organics:cis-1,2-Bis(diphenylphosphino)ethylene, 98%(983-80-2)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Polydentate Phosphine Ligands 多齿膦配体
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Polydentate Phosphine Ligands 多齿膦配体
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds
  4. Phosphorus Precursors
  1. Functional Group 官能团索引
  2. phosphine
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus

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