Benzil 苯偶酰

CAS 134-81-6 MFCD00003080

化学结构图

134-81-6
SMILES: O=C(C(=O)c1ccccc1)c1ccccc1

化学属性

Mol. FormulaC14H10O2
Mol. Weight210.23
Melting Point94-95°C
Density1.521
TSCAYes
Boiling Point347.0±11.0 °C at 760 mmHg
Vapor Pressure1 mmHg ( 128.4 °C)
Solubility0.5 G/L (20 ºC)
Stability对光敏感
Flash Point142.6±4.9 °C
Appearance 黄色结晶，熔点95℃，有旋光性，相对密度1.23，沸点346-348℃，溶于乙醇、醚等有机溶剂，不溶于水，还原时生成二苯乙醇酮。

别名和识别编码

Chemical NameBenzil
Synonym Benzil {LY} Benzil {} {LY} Benzil {} {} {LY} Benzil {} {} {} {LY} Benzil {} {} {} {} {LY} Benzil {} {} {} {} {} {LY} Benzil {} {} {} {} {} {} {LY} Benzil {} {} {} {} {} {} {} {LY} Benzil {} {} {} {} {} {} {} {} {LY} Benzil {} {} {} {} {} {} {} {} {} {LY} Benzil {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzil {} {} {} {} {} {} {} {} {} {} {} {LY} Benzil {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzil {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzil {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzil {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzil {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzil {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzil {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzil {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number134-81-6
PubChem Substance ID8651
EC Number205-157-0
Beilstein Registry Number608047
MDL NumberMFCD00003080
Reaxys-RN608047
Merck Number1078
Chemical Name Translation苯偶酰
Wiswesser Line NotationRVVR
LabNetwork Molecule IDLN00196622
InChIInChI=1S/C14H10O2/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10H
Canonical SMILESO=C(C(C1=CC=CC=C1)=O)C2=CC=CC=C2
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分类

  • {SNA} B, Bioactive Small Molecules, Building Blocks, C13 to C14, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks, 细胞生物学
  • {SA} B, Bioactive Small Molecules, Building Blocks,
  • B, Bioactive Small Molecules, Building Blocks, C13 to C14, Carbonyl Compounds, Cell Biology, Chemical Synthesis, Ketones, Organic Building Blocks
  • {SNA
  • {SNA} Building Blocks, C13 to C14, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks

产品应用

  • 用作制药原料、有机合成中间体及紫外线固化剂，也用作杀虫剂。

相关文献及参考

  • Merck: 14,1078 Beilstein: 7,IV,2502
  • Short: II/25D
  • Merck: 14,1078
  • Short: II/27B

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
RTECSDD1925000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S37 Wear suitable gloves 戴适当手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >3 gm/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
REFERENCE :
   IYKEDH Iyakuhin Kenkyu.  Study of Medical Supplies.  (Nippon Koteisho
   Kyokai, 12-15, 2-chome, Shibuya, Shibuya-ku, Tokyo 150, Japan)  V.1- 1970- 
   Volume(issue)/page/year: 15,359,1984

其他信息

  • 用途四:用作制药原料、有机合成中间体及紫外线固化剂，也用作杀虫剂。
  • 毒性分级:中毒
  • TCI Shanghai:苯偶酰 Benzil,>;99.0%(GC)(134-81-6)
  • Hazard Note:Irritant
  • F:10
  • Sigma Aldrich:134-81-6(sigmaaldrich)
  • Acros Organics:联苯酰/苯偶酰 Benzil, 99+%(134-81-6)
  • 灭火剂:干粉,泡沫,沙土,二氧化碳, 雾状水
  • MOL 文件:134-81-6.mol
  • 图谱信息:联苯甲酰(134-81-6)红外图谱(IR2) 联苯甲酰(134-81-6)红外图谱(IR1)
  • 刺激数据:眼睛-兔子 100 毫克/24小时 重度
  • 用途三:有机合成中间体，也用于杀虫剂。该品用作紫外线固化树脂（UV树脂）的光敏剂很有前途。联苯酰对紫外线敏化的波长范围广。苯偶姻在3400A以下，苯偶姻烷基醚在3900A以下。而联苯酰在4800A以下，可在很宽的波长区敏化，因此可用于厚膜树脂的固化，这是以前UA树脂敏化中所不具有的特性。而且固化后没有气味，故适于制作食品包装用的印刷油墨等。
  • 下游产品:(1R,2R)-1,2-二苯基乙二胺 --> (1S,2S)-1,2-二苯基乙二胺 --> 二苯基乙醇酸 --> 2，4，5－三苯基咪唑 --> 二联苯乙二醛肟 --> 苯妥英钠
  • 上游原料:氰化钠 --> 硫酸铜五水合物 --> 醋酸铜 --> 深绿 --> 2-羟基-2-苯基苯乙酮
  • 可燃性危险特性:较易燃; 燃烧分解刺激烟雾
  • 用途一:用作医药中间体、紫外线固化树脂的光敏剂等
  • 海关编码:29143900
  • 类别:易燃固体
  • 用途二:用于光敏剂、有机合成中间体、也可用作粘合剂等。
  • 储运特性:通风低温干燥
  • 检测方法:HPLC
  • Alfa Aesar:苯偶酰,98% Benzil, 98%(134-81-6)
  • 蒸气压:1 mm Hg ( 128.4 °C)
  • 急性毒性:口服-小鼠 LD50: >; 3000 毫克/公斤
  • 能溶于醇、醚、氯仿、乙酸乙酯、苯、甲苯和硝基苯，不溶于水。低毒，半数致死量(大鼠，经口)2710mg/kg。有刺激性。
  • 联苯甲酰价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30018124 联苯甲酰 25g 58元 2011/04/16 B0050 苯偶酰 Benzil 500G 727元 2011/04/16 B0050 苯偶酰 Benzil 25G 153元
  • MSDS 信息:Dibenzoyl(134-81-6).msds
  • 方法一:由苯甲醛与氰化钠缩合得苯偶姻（安息香）后，再经硝酸氧化而得。这一工艺过程因产生亚硝酸气体而造成污染，反应激烈，需仔细操作。生产试剂联苯酰也有采用乙酸铜或硫酸铜的，例如，将4100g结晶硫酸铜、4000g吡啶及1600g水一起搅拌加热，然后加入1696g苯偶姻，加热反应2h，反应物变成深绿色，冷却后倾出硫酸亚酮-吡啶溶液。结晶用水洗涤后与10%盐酸共热。冷却后滤出结晶，可得1450g联苯酰。用空气或硝酸使苯偶姻氧化即得该品。将苯偶姻和硝酸（40%）加入反应锅，经4h慢慢升温至110℃，并保持反应1h。然后冷至40℃以下，甩滤、水洗，得联苯酰粗品。将粗品加水，用30%氢氧化钠调节pH至12，加热至100℃溶解，冷却后过滤，水洗得成品。收率95%以上。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones - Carbonyl Compounds
  6. C13 to C14 - Ketones
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Aromatic Ketones
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones 酮
  6. C11 to C12
  1. Materials Science 材料科学
  2. Photopolymerization Initiators