4-(Chloromethyl)-3,5-dimethylisoxazole 4-氯甲基-3,5-二甲基异噁唑
CAS 19788-37-5 MFCD00003154
化学结构图
SMILES: CC1ON=C(C)C=1CCl
化学属性
| Mol. Formula | C6H8ClNO |
|---|---|
| Mol. Weight | 146 |
| Refractive index | 1.4850 to 1.4890 |
| Boiling Point | 87-88 |
| Density | 1.173 |
| Flash Point | 96°C(lit.) |
| TSCA | Yes |
别名和识别编码
| Chemical Name | 4-(Chloromethyl)-3,5-dimethylisoxazole |
|---|---|
| CAS Number | 19788-37-5 |
| Alfabeta Name | CHLOROMETHYLDIMETHYLISOXAZOLE 435()---, |
| MDL Number | MFCD00003154 |
| PubChem Substance ID | 87560777 |
| EC Number | 243-312-4 |
| Beilstein Registry Number | 110780 |
| Reaxys-RN | 110780 |
| Synonym | 4-(Chloromethyl)-3,5-dimethylisoxazole; 4-(Chloromethyl)-3,5-dimethyl-1,2-oxazole 4-氯甲基-3,5-二甲基异噁唑 |
| Chemical Name Translation | 4-氯甲基-3,5-二甲基异噁唑 |
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分类
- Building Blocks, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Isoxazoles
- {SNA} Building Blocks, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Isoxazoles
产品应用
- 有机合成中间体。
相关文献及参考
- Beilstein:27(4)988
- For similar annulations using higher homologues: Org. Synth. Coll., 6, 781 (1988).
- Review of the synthetic reactions of isoxazoles: Heterocycles, 12, 1343 (1979).
- Annulation reagent: Pure Appl. Chem., 9, 131 (1964); J. Am. Chem. Soc., 89, 5459 (1967). Reviews: Synthesis, 777 (1976); Tetrahedron, 32, 3 (1976).
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H332 Harmful if inhaled 吸入有害
- H302 Harmful if swallowed 吞食有害
- H312 Harmful in contact with skin 皮肤接触有害
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H319 Causes serious eye irritation 严重刺激眼睛
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352+P332+P313+P362+P364
- P305+P351+P338
- P305+P351+P338+P337+P313
- P332+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S37 Wear suitable gloves 戴适当手套；
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