Sodium persulfate 过硫酸钠

CAS 7775-27-1 MFCD00003501

化学结构图

7775-27-1
SMILES: O=S(=O)([O-])OOS(=O)(=O)[O-].[Na+].[Na+]

化学属性

Mol. FormulaNa2O8S2
Mol. Weight238.1
Density2.4
TSCAYes
Melting Point>300°C
Solubility550 G/L (20 ºC)
Stability易吸潮
Boiling Point-
Flash Point-

别名和识别编码

Chemical NameSodium persulfate
Synonym Sodium Persulfate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
MDL Number-
PubChem Substance ID62655
CAS Number7775-27-1
EC Number231-892-1
Merck Number14,8656
Beilstein Registry Number2384789
Chemical Name Translation过硫酸钠
Wiswesser Line NotationNA2 S2-O8
LabNetwork Molecule IDLN00194436
InChIInChI=1S/2Na.H2O8S2/c;;1-9(2,3)7-8-10(4,5)6/h;;(H,1,2,3)(H,4,5,6)/q2*+1;/p-2
Canonical SMILESO=S(OOS(=O)(O[Na])=O)(O[Na])=O
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分类

  • {uni_hamburg} no charge; peroxide; 3fragments; ionic
  • {
  • {SNA} BioUltra, 分子生物学, 分子生物学试剂
  • {SNA} Chemical Synthesis, Essential Chemicals, Oxidizing Agents, Research Essentials, Salts,
  • {SNA} BioUltra, Molecular Biology, Molecular Biology Reagents
  • Chemical Synthesis, Essential Chemicals, Free Radical Initiators, Inorganic Peroxides, Inorganic Salts, Solutions and Reagents, Materials Science, Oxidation, Polymer Science, Polymerization Initiators, Reagent Grade, Research Essentials, Sulfur-Based, Synthetic Reagents
  • {SNA} Chemical Synthesis, Oxidizing Agents, Sulfur-Based,

产品应用

  • 氧化剂。电池去极剂。聚合反应促进剂。用作漂白剂、氧化剂、乳液聚合促进剂。

相关文献及参考

  • Short: EINECS
  • Short: IV/1b
  • Merck: 14,8656

安全信息

GHS Symbol
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
  • P221 Take any precaution to avoid mixing with combustibles/… 采取一切防范措施,避免与可燃物混合/...
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P285 In case of inadequate ventilation wear respiratory protection. 在通风不足的情况下,戴呼吸防护。
  • P301+P312
  • P301+P317
  • P302+P352
  • P304+P340
  • P304+P341
  • P305+P351+P338
  • P308+P316
  • P309+P311
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P333+P313
  • P333+P317
  • P337+P313
  • P337+P317
  • P342+P311
  • P342+P316
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403 Store in a well-ventilated place. 储存在通风良好的地方。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H272 May intensify fire; oxidizer 可能加剧火势;氧化剂。
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes 5.1 O;Xn
WGK Germany1
RTECSSE0525000
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Signal word Danger
Safety Statements
  • S17 Keep away from combustible material 远离可燃物料;
  • S22 Do not breathe dust 不要吸入粉尘;
  • S24 Avoid contact with skin 避免皮肤接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37 Wear suitable gloves 戴适当手套;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
UN Number 1505
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R42/43
  • R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
Packing GroupIII
Storage condition -20°C 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Hazard Class5.1
Warnings 危化品目录(2015)
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 226 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   COREAF Comptes Rendus Hebdomadaires des Seances, Academie des Sciences.
   (Paris, France)  V.1-261, 1835-1965.  For publisher information, see CRASEV.
    Volume(issue)/page/year: 257,791,1963

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 178 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85KYAH "Merck Index; an Encyclopedia of Chemicals, Drugs, and Biologicals",
   11th ed., Rahway, NJ 07065, Merck & Co., Inc. 1989 Volume(issue)/page/year:
   11,1366,1989

Restrict 危险品

其他信息

  • 类别:氧化剂
  • MOL 文件:7775-27-1.mol
  • 爆炸物危险特性:与还原剂、硫、磷等混合可爆; 受热、撞击、明火可爆
  • 制备方法:(1)硫酸铵水溶液电解氧化生成过硫酸铵,再与氢氧化钠进行复分解反应,将副产的氨逐出后,再减压浓缩、结晶、干燥,可得过硫酸钠。(NH4)2S2O8+2NaOH→Na2S2O8+2NH3+2H2O。 (2)电解冷硫酸可制得过二硫酸,再与碱作用,可制得过硫酸钠。 (I) 2HSO4--2e→H2S2O8 (II)H2S2O8+2NaOH→Na2S2O8+2H2O。
  • 强氧化剂:过硫酸钠具有强氧化性,可用作氧化剂,可将Cr3+、Mn2+等氧化成相应的高氧化态化合物,当有Ag+存在时,可促进上述氧化反应;利用其氧化性可用作漂白剂、金属表面处理剂、化学试剂;医药原料;电池、乳液聚合反应的促进剂和引发剂。
  • 用途二:用作氧化剂、漂白剂和电池去极剂
  • 下游产品:2-溴甲基苯甲酸 --> 马来酸-烯丙醇共聚物
  • 急性毒性:腹腔- 小鼠 LD50: 226 毫克/ 公斤
  • 用途三:用于照相业的废液处理,用作印刷电路板表面金属的软蚀剂及纺织用脱浆剂、硫化染料发色剂等
  • 用途四:氧化剂。电池去极剂。聚合反应促进剂。用作漂白剂、氧化剂、乳液聚合促进剂。
  • Sigma Aldrich:7775-27-1(sigmaaldrich)
  • 职业标准:TWA 2 毫克/ 立方米
  • MSDS 信息:过硫酸钠(7775-27-1).msds
  • Alfa Aesar:Sodium peroxydisulfate, 98%(7775-27-1)
  • 过硫酸钠价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80118418 过硫酸钠;高硫酸钠;过二硫酸钠;二硫八氧酸钠;过硫酸碱 500g 20元 2010/06/21 202025000 过硫酸钠 Sodium persulfate 98+% 500 GR 350元 2010/06/21 202020250 过硫酸钠 Sodium persulfate 98+% 25 GR 169元
  • Acros Organics:过硫酸钠 Sodium persulfate, 98+%(7775-27-1)
  • 图谱信息:过硫酸钠(7775-27-1)红外图谱(IR1)
  • 可燃性危险特性:受热分解有毒氮氧化物气体
  • 毒性分级:高毒
  • 灭火剂:雾状水、砂土、泡沫
  • 理化性质:过硫酸钠又称过二硫酸钠。白色晶体或结晶性粉末。无嗅。无味。分子式Na2S2O8,相对分子质量238.13。常温下逐渐分解,加热或在乙醇中可迅速分解,分解后放出氧气并生成焦硫酸钠。湿气及铂黑、银、铅、铁、铜、镁、镍、锰等金属离子或它们的合金均可促进分解,高温(200℃左右)急剧分解,放出过氧化氢。易溶于水(20℃时70.4)。有强氧化性。对皮肤有强烈刺激性,长时间接触皮肤,可引起过敏症,操作时应注意。大鼠经口LD50 895mg/kg。密封保存。实验室通过加热过硫酸铵与苛性钠或碳酸钠溶液,除去氨和二氧化碳而得过硫酸钠。 以上信息由Chemicalbook的彤彤编辑整理。
  • 用途一:用于医药、漂白、电池,并用作化学试剂
  • 能逐渐分解,潮湿和高温能使分解加速。能被乙醇和银离子分解。20℃时水中溶解度为549g/L。有氧化性。有刺激性。
  • 外观性质:白色晶状粉末,无臭。
  • 上游原料:氢氧化钠 --> 过氧化硫酸铵
  • 储运特性:库房通风低温干燥; 轻装轻卸; 与有机物、还原剂、硫、磷易燃物, 食品原料分开存放

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