Trichloro(Cyclopentadienyl)Titanium(IV) 环戊二烯基三氯化钛(IV)

CAS 1270-98-0 MFCD00003724

化学结构图

1270-98-0
SMILES: Cl[Ti](Cl)Cl.[CH]1[CH][CH][CH][CH]1

化学属性

Mol. FormulaC5H5Cl3Ti
Mol. Weight219.32
Melting Point210 °C (dec.)(lit.)
TSCANo
Appearance yellow xtl.
Stabilitymoisture sensitive

别名和识别编码

Chemical NameTrichloro(Cyclopentadienyl)Titanium(IV)
Synonym Cyclopentadienyltitanium(IV) trichloride {LY} Cyclopentadienyltitanium(IV) trichloride {} {LY} Cyclopentadienyltitanium(IV) trichloride {} {} {LY} Cyclopentadienyltitanium(IV) trichloride {} {} {} {LY} Cyclopentadienyltitanium(IV) trichloride {} {} {} {} {LY} Cyclopentadienyltitanium(IV) trichloride {} {} {} {} {} {LY} Cyclopentadienyltitanium(IV) trichloride {} {} {} {} {} {} {LY} Cyclopentadienyltitanium(IV) trichloride {} {} {} {} {} {} {} {LY} Cyclopentadienyltitanium(IV) trichloride {} {} {} {} {} {} {} {} {LY} Cyclopentadienyltitanium(IV) trichloride {} {} {} {} {} {} {} {} {} {LY} Cyclopentadienyltitanium(IV) trichloride {} {} {} {} {} {} {} {} {} {} {LY} Cyclopentadienyltitanium(IV) trichloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopentadienyltitanium(IV) trichloride {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopentadienyltitanium(IV) trichloride {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopentadienyltitanium(IV)
MDL NumberMFCD00003724
CAS Number1270-98-0
PubChem Substance ID24854059
Beilstein Registry Number16(4)1770
Chemical Name Translation环戊二烯基三氯化钛(IV)
InChIKeyQOXHZZQZTIGPEV-UHFFFAOYSA-K
LabNetwork Molecule IDLN01744661
Canonical SMILES[][Ti](Cl)(Cl)Cl.c1cccc1
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Titanium
  • {uni_hamburg} no charge; metal-organic; other heterocycle; carbocycle; alicycle; fused rings; 3ring; 4ring; 5ring; 6ring; 1fragment; zwitterion
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Titanium Catalysts

相关文献及参考

  • Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P304+P340
  • P304+P340+P310
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P305+P351+P338
  • P301+P330+P331
  • P303+P361+P353+P310+P363
  • P405 Store locked up. 上锁保管。
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
RTECSXR1927300
Signal word Danger
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
Packing GroupIII
UN Number UN 3261 8/PG 2 UN3096 3261 UN3261
Risk Statements
  • R34 Causes burns 会导致灼伤
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Moisture Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect fro
Hazard Codes C
Hazard Class8 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Parenteral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 130 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EJMCA5 European Journal of Medicinal Chemistry--Chimie Therapeutique.
   (Editions Scientifiques Elsevier, 29 rue Buffon, F-75005, Paris, France)
   V.9-    1974-  Volume(issue)/page/year: 19,347,1984

其他信息

  • 三氯一茂钛价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C1994 环戊二烯基三氯化钛(IV) Cyclopentadienyltitanium(IV) Trichloride 5G 1460元 2014/06/02 C1994 环戊二烯基三氯化钛(IV) Cyclopentadienyltitanium(IV) Trichloride 1G 514元 2010/06/21 215770025 三氯一茂钛 Cyclopentadienyltitanium trichloride 99% 2.5 GR 1023元
  • TCI Shanghai:环戊二烯基三氯化钛(IV) Cyclopentadienyltitanium(IV) Trichloride,>;98.0%(T)(1270-98-0)
  • Alfa Aesar:Cyclopentadienyltitanium trichloride(1270-98-0)
  • 三氯一茂钛价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 C1994 环戊二烯基三氯化钛(IV) Cyclopentadienyltitanium(IV) Trichloride 5G 1470元 2011/04/16 C1994 环戊二烯基三氯化钛(IV) Cyclopentadienyltitanium(IV) Trichloride 1G 526元 2010/06/21 215770025 三氯一茂钛 Cyclopentadienyltitanium trichloride 99% 2.5 GR 1023元
  • MOL 文件:1270-98-0.mol
  • Sigma Aldrich:1270-98-0(sigmaaldrich)
  • Acros Organics:环戊二烯基三氯化钛 Cyclopentadienyltitanium trichloride, 99%(1270-98-0)
  • TSCA:No
  • F:10-21
  • 敏感性:Moisture Sensitive
  • 图谱信息:三氯一茂钛(1270-98-0)红外图谱(IR2) 三氯一茂钛(1270-98-0)红外图谱(IR1) 三氯一茂钛(1270-98-0)质谱(MS) 三氯一茂钛(1270-98-0)核磁图( 1 HNMR) 三氯一茂钛(1270-98-0)核磁图( 13 CNMR)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Titanium - Catalysis and Inorganic Chemistry
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Titanium - Catalysis and Inorganic Chemistry
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Reagents for Polymerization - Polymer Science
  4. Catalysts for Polymerization - 烯烃聚合催化
  5. Olefin Polymerization - Catalysts for Polymerization
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Catalysts for Organic Synthesis 有机合成催化剂
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metallocenes
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Tin
  1. Metallocenes, Derivatives & Cp Precursors
  2. Titanium

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