CAS 90-30-2 MFCD00003878-1-Naphthalenamine, N-phenyl- N-苯基-1-萘胺 -LabNovo

1-Naphthalenamine, N-phenyl- N-苯基-1-萘胺

CAS 90-30-2 MFCD00003878

化学结构图

SMILES: c1ccc(Nc2cccc3ccccc23)cc1

化学属性

Mol. Formula	C16H13N
Mol. Weight	219.28
Density	1.1
Boiling Point	226°C at 760 mmHg
Melting Point	60-62°C
TSCA	Yes
Solubility	不溶
Stability	对光敏感
Flash Point	>110°C

别名和识别编码

Chemical Name	1-Naphthalenamine, N-phenyl-
CAS Number	90-30-2
EC Number	201-983-0
Beilstein Registry Number	12,1224
MDL Number	MFCD00003878
Synonym	N-Phenylnaphthalen-1-amine {LY} N-Phenylnaphthalen-1-amine {} {LY} N-Phenylnaphthalen-1-amine {} {} {LY} N-Phenylnaphthalen-1-amine {} {} {} {LY} N-Phenylnaphthalen-1-amine {} {} {} {} {LY} N-Phenylnaphthalen-1-amine {} {} {} {} {} {LY} N-Phenylnaphthalen-1-amine {} {} {} {} {} {} { {} {} {} {} {} {} {LY} N-Phenylnaphthalen-1-amine {} {} {} {} {} {} {} {LY} N-Phenylnaphthalen-1-amine {} {} {} {} {} {} {} {} {LY} N-Phenylnaphthalen-1-amine {} {} {} {} {} {} {} {} {} {LY} N-Phenylnaphthalen-1-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-Phenylnaphthalen-1-amine {} {} {} {} {} {} {} {} {} {} {} {LY} N-Phenylnaphthalen-1-amine {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-Phenylnaphthalen-1-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-Phenylnaphthalen-1-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-Phenylnaphthalen-1-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-Phenyl
Reaxys-RN	2211174
PubChem Substance ID	7013
Chemical Name Translation	N-苯基-1-萘胺
Wiswesser Line Notation	L66J BMR
LabNetwork Molecule ID	LN00196883
InChI	InChI=1S/C16H13N/c1-2-9-14(10-3-1)17-16-12-6-8-13-7-4-5-11-15(13)16/h1-12,17H
Canonical SMILES	C12=CC=CC=C1C(NC3=CC=CC=C3)=CC=C2

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安全信息

Signal word

GHS Symbol

WGK Germany2

Safety Statements

S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
S29 Do not empty into drains 不要排入下水道；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
S36 Wear suitable protective clothing 穿戴适当的防护服；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R22 Harmful if swallowed 吞咽有害

Precautionary statements

P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P302+P352+P333+P313+P362+P364
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P273 Avoid release to the environment. 避免释放到环境中。
P501 Dispose of contents/container to..… 处理内容物/容器.....
P405 Store locked up. 上锁保管。
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P301+P312+P330
P308+P311
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。

RTECSQM4500000

Hazard statements

H302 Harmful if swallowed 吞食有害
H315 Causes skin irritation 会刺激皮肤
H335 May cause respiratory irritation 可能导致呼吸道刺激
H319 Causes serious eye irritation 严重刺激眼睛

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

Packing GroupIII

UN Number UN3077 3077

Hazard Codes Xn;N Xn,N

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

Hazard Class9

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 17280 mg/kg/9W-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Kidney, Ureter, Bladder - Kidney tumors
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   44,3098,1984

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 5400 mg/kg/9W-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Kidney, Ureter, Bladder - Kidney tumors
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   44,3098,1984

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 8 gm/kg
TOXIC EFFECTS :
   Liver - other changes
   Kidney, Ureter, Bladder - other changes
   Skin and Appendages - dermatitis, other (after systemic exposure)
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0535072

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1231 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMRL** Aerospace Medical Research Laboratory Report.  (Aerospace Technical
   Div., Air Force Systems Command, Wright-Patterson Air Force Base, OH 45433)
   Volume(issue)/page/year: TR-74-78,1974

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1625 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMRL** Aerospace Medical Research Laboratory Report.  (Aerospace Technical
   Div., Air Force Systems Command, Wright-Patterson Air Force Base, OH 45433)
   Volume(issue)/page/year: TR-74-78,1974

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Human Lung
DOSE/DURATION           : 50 mg/L
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD-A041-973

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Human Cells - not otherwise specified
DOSE/DURATION           : 27500 ug/L
REFERENCE :
   ITCSAF In Vitro.  (Rockville, MD)  V.1-20, 1965-85.  For publisher
   information, see ICDBEO.  Volume(issue)/page/year: 17,719,1981

TYPE OF TEST            : Dominant lethal test
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 830 mg/kg/5D (Intermittent)
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD-A041-973

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 10 ug/plate
REFERENCE :
   SYSWAE Shiyan Shengwu Xuebao.  Journal of Experimental Biology.  (China
   International Book Trading Corp., POB 2820, Beijing, Peop. Rep. China) V.1- 
     1953-    Suspended 1966-77.  Volume(issue)/page/year: 12,41,1979

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 500 nL/plate
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD-A041-973

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 60 mg/L
REFERENCE

其他信息

图谱信息:1-萘氨基苯(90-30-2)红外图谱(IR3) 1-萘氨基苯(90-30-2)核磁图( 13 CNMR) 1-萘氨基苯(90-30-2)红外图谱(IR1) 1-萘氨基苯(90-30-2)核磁图( 1 HNMR) 1-萘氨基苯(90-30-2)红外图谱(IR2) 1-萘氨基苯(90-30-2)质谱(MS)
外观性质:白色至淡黄色晶体, 遇日光逐渐变紫色。
下游产品:碱性蓝 26
TCI Shanghai:N-苯基-1-萘胺 N-Phenyl-1-naphthylamine,>;97.0%(N)(90-30-2)
用途二:该品系芳香族仲胺类防老剂。用于天然橡胶、二烯类合成橡胶、氯丁橡胶。是再生胶通用型防老剂，也用于氯丁胶乳。对热、氧、屈挠、天候老化、疲劳有良好的防护作用。在氯丁橡胶中兼有抗臭氧老化的性能，对有害金属也有一定的抑制作用。该品常与其他防老剂如AP，DNP，尤其是4010和4010N并用。在干胶中易分散，亦易分解于水中。在橡胶中的溶解度高达5%，用量为3-4份时不喷霜。由于其具有污染性、迁移性及在日光下颜色变深的特性，因此不适用于白色及浅色制品，主要用于制造轮胎、胶管、胶带、胶辊、胶鞋、海底电缆绝缘层等。在塑料工业中，该品可作聚乙烯的热稳定剂。工业品因含有1-萘胺和苯胺，故有毒性。
海关编码:29214980
上游原料:氨基苯 --> 对氨基苯磺酸 --> 1-萘胺
1-萘氨基苯价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 P0197 N-苯基-1-萘胺 N-Phenyl-1-naphthylamine 500G 764元 2014/06/02 P0197 N-苯基-1-萘胺 N-Phenyl-1-naphthylamine 25G 135元 2010/06/21 147162500 1-萘氨基苯 N-Phenyl-1-naphthylamine 98% 250 GR 834元
用途一:适用于天然橡胶和氯丁橡胶，可与其他防老剂混合使用
方法一:由1-萘胺与苯胺在对氨基苯磺酸催化下，于250℃进行缩合而得。将苯胺、对氨基苯磺酸、熔化好的1-萘胺投入缩合锅，在250℃进行缩合，反应结束后进行分馏。在低真空下蒸出苯胺入混合馏分（套用），根据馏分的实测凝固点决定馏分的分割点。蒸出防老剂甲和高沸物。熔融的防老剂甲经冷却切片、包装即为成品。原料消耗（kg/t)1-萘胺（99%） 710苯胺（99.2） 425
遇日光逐渐变为紫色。溶于乙醇、乙酸、乙醚、氯仿和苯，微溶于水。低毒，半数致死量(大鼠，经口)1625mg/kg。有刺激性。
Alfa Aesar:N-苯基-1-萘胺,97% N-Phenyl-1-naphthylamine, 97%(90-30-2)
MOL 文件:90-30-2.mol
Acros Organics:N-苯基-1-萘胺 N-Phenyl-1-naphthylamine, 98%(90-30-2)
Sigma Aldrich:90-30-2(sigmaaldrich)
用途三:制造染料和其他有机化合物。橡胶抗氧剂。防老剂。对空气、热和屈挠老化都有防护作用，但制品遇光变色。适用于天然橡胶和氯丁橡胶。
MSDS 信息:N-苯基-α萘胺(90-30-2).msds

1-Naphthalenamine, N-phenyl- N-苯基-1-萘胺

CAS 90-30-2 MFCD00003878

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