Naphthionic acid 4-萘胺-1-磺酸

CAS 84-86-6 MFCD00004027

化学结构图

84-86-6
SMILES: Nc1ccc(S(=O)(=O)O)c2ccccc12

化学属性

Mol. FormulaC10H9NO3S
Mol. Weight223.25
Melting Point300 °C
TSCAYes
Density1.67
Solubility微溶于水，溶于乙醇、乙醚。
Boiling Point220 °C at 760 mmHg

别名和识别编码

Chemical Name4-Amino-1-naphthalenesulfonic Acid
Synonym 4-Aminonaphthalene-1-sulfonic acid {LY} 4-Aminonaphthalene-1-sulfonic acid 4-amino-1-naphthalenesulfonic acid 4-aminonaphthalene-1-sulfonic acid 4-aminonaphthalenesulfonic acid naphthionic acid naphthionic acid, cobalt salt naphthionic acid, copper (2+) salt (2:1) naphthionic acid, magnesium (2:1) salt naphthionic acid, monosodium salt {} {LY} 4-Aminonaphthalene-1-sulfonic acid {} {} {LY} 4-Aminonaphthalene-1-sulfonic acid {} {} {} {LY} 4-Aminonaphthalene-1-sulfonic acid {} {} {} {} {LY} 4-Aminonaphthalene-1-sulfonic acid {} {} {} {} {} {LY} 4-Aminonaphthalene-1-sulfonic acid {} {} {} {} {} {} {LY} 4-Aminonaphthalene-1-sulfonic acid {} {} {} {} {} {} {} {LY} 4-Aminonaphthalene-1-sulfonic acid {} {} {} {} {} {} {} {} {LY} 4-Aminonaphthalene-1-sulfonic acid {} {} {} {} {} {} {} {} {} {LY} 4-Aminonaphthalene-1-sulfonic acid {} {} {} {} {} {} {} {} {} {} {LY} 4-Aminonaphthalene-1-sulfo
MDL NumberMFCD00004027
CAS Number84-86-6
PubChem Substance ID6790
EC Number201-567-9
Beilstein Registry Number14(3)2241
Reaxys-RN1971299
Merck Number6403
Chemical Name Translation4-萘胺-1-磺酸
Wiswesser Line NotationL66J BZ ESWQ
LabNetwork Molecule IDLN00238187
Canonical SMILESO=S(C1=C2C=CC=CC2=C(N)C=C1)(O)=O
InChIInChI=1S/C10H9NO3S/c11-9-5-6-10(15(12,13)14)8-4-2-1-3-7(8)9/h1-6H,11H2,(H,12,13,14)
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; large ring; fused rings; 6ring; 10ring; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfonic/Sulfinic Acids, Sulfur Compounds
  • {SA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfonic/Sulfinic Acids, Sulfur Compounds

相关文献及参考

  • Merck 14 ,6403
  • Beil. 14 ,IV,2793
  • Corp MSDS 1 (1), 198:B / FT-IR 2 (2), 3249:C / FT-IR 1 (2), 507:C / RegBook 1 (2), 2213:H / Sax 6 , 234 / Structure Index 1 , 347:A:6
  • Short: III/5a Title: Structure Data of Organic Crystals: C ... C 13 Author: Schudt, E.; Weitz, G. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/5a Year: 1971 ISBN: 3-540-05177-5 ISBN: 978-3-540-05177-0 Internet Resource: DOI:10.1007/b19970 RefComment: XXI, 736 pages, and VII, 890 pages. Hardcover Abstract: Volume III/5 offers a compitation as complete as possible of the space groups and lattice con-stants of all crystals which have been studied by means of X-rays, neutron and electron diffraction.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Codes C
RTECSQK1270000
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P302+P361+P354
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P316
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S25 Avoid contact with eyes 避免眼睛接触；
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
UN Number UN 2585 8/PG 3 UN2585 2585
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R22 Harmful if swallowed 吞咽有害
Packing GroupIII
Hazard Class8 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 300 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >7500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0533716

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 对氨基萘磺酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0344 4-氨基-1-萘磺酸 4-Amino-1-naphthalenesulfonic Acid 25G 629元 2011/04/16 A0344 4-氨基-1-萘磺酸 4-Amino-1-naphthalenesulfonic Acid 500G 4830元 2010/05/25 B21829 4-氨基萘-1-磺酸, 98% 4-Aminonaphthalene-1-sulfonic acid, 98% 25g 316元
  • 储运特性:库房通风低温干燥
  • 用途一:用作偶氮染料中间体，也用于食用色素
  • 下游产品:直接红 28 --> 酸性红 27 --> 食品黄 3 --> 酸性红 18 --> 1-萘酚-4-磺酸 --> 2,3-二氯-1,4-萘醌 --> 4-羟基-3-(4-磺酸-1-萘偶氮)-1-萘磺酸二钠盐 --> 直接黄106
  • Alfa Aesar:4-氨基萘-1-磺酸,98% 4-Aminonaphthalene-1-sulfonic acid, 98%(84-86-6)
  • 图谱信息:对氨基萘磺酸(84-86-6)红外图谱(IR2) 对氨基萘磺酸(84-86-6)质谱(MS) 对氨基萘磺酸(84-86-6)红外图谱(IR1) 对氨基萘磺酸(84-86-6)核磁图( 13 CNMR)
  • 毒性分级:高毒
  • MOL 文件:84-86-6.mol
  • 外观性质:无色至灰白色粉末, 在空气中变为玫瑰色。
  • 急性毒性:腹腔-小鼠 LD50: 300 毫克/公斤
  • 用途二:染料中间体。用于制造酸性红A、B，酸性大红3R，直接大红4B，直接大枣红GB，直接枣红B等，并用于生产1-萘酚-4-磺酸等中间体。
  • 上游原料:苯酚 --> 硫化钠 --> 三氯苯
  • 灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水
  • 方法一:萘胺磺化得4-氨基-1-萘磺酸，经中和而得钠盐。磺化反应在溶剂三氯苯中进行，反应温度185-190℃，控制真空度2.67-5.33kPa，保温反应3.5h，取样检查终点。合格后降温到150℃，加碱水中和，控制pH=8-9。在70-80℃，将中和液加石炭酸和硫化碱，升温至90-95℃后静置，分层。上层料液经浓缩、冷却、结晶、离心甩干即为钠盐成品。收率83%。下层三氯苯经水洗回收套用。
  • TCI Shanghai:4-氨基-1-萘磺酸 4-Amino-1-naphthalenesulfonic Acid,>;96.0%(T)(84-86-6)
  • Sigma Aldrich:84-86-6(sigmaaldrich)
  • 海关编码:29214500
  • MSDS 信息:对氨基萘磺酸(84-86-6).msds
  • 可燃性危险特性:可燃;燃烧产生有毒氮氧化物和硫氧化物烟雾
  • 类别:有毒物品

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfonic/Sulfinic Acids 磺酸/亚磺酸
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfonic/Sulfinic Acids 磺酸/亚磺酸

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