1-Naphthyl Acetonitrile 1-萘乙腈

CAS 132-75-2 MFCD00004041

化学结构图

132-75-2
SMILES: N#CCc1cccc2ccccc12

化学属性

Mol. FormulaC12H9N
Mol. Weight167
Refractive index1.6192
Boiling Point191-194
Melting Point33-35
Flash Point>110°(230°F)
TSCAYes
Appearance 白色结晶。熔点32-33℃，沸点162-164℃，191-194℃（2.4kPa），折光率（nD20）1.6192。不溶于水。

别名和识别编码

Chemical Name1-Naphthyl Acetonitrile
Synonym 1-Naphthaleneacetonitrile Acetonitrile, (1-naphthyl)- 1-Naphtylacetonitrile α-naphthyl acetonitrile 1-NAPHTHYLMETHYLCYANIDE α-(1-naphthyl)acetonitrile naphthalen-1-yl-acetonitrile 1-naphthylacetonitrile A-NAPHTHALENEACETONITRILE (SEE 5049) 1-萘基乙睛 1-Naphthylacetonitrile97% 1-Cyanomethylnaphthalene ALPHA-NAPHTHYLACETONITRILE (1-Naphthyl)-acetonitril Α-萘乙腈 1-NAPHTHYLACETONITRILE alpha-(1-naphthyl)acetonitrile α-Naphthylacetonitrile 1-萘乙腈 a-naphthylacetonitrile alpha-Naphthyl acetonitrile α-萘乙腈 Naphthalene-1-acetonitrile 45) 1-NAPHTHYL ACETONITILE naphthalenyl-acetonitrile (1-naphthyl)-acetonitril 1-Naphthylene Acetonitrile 1-NAPHTHALENEACETONITRILE 2-(1-Naphthyl)acetonitrile
MDL NumberMFCD00004041
CAS Number132-75-2
PubChem Substance ID8596
EC Number205-078-1
Beilstein Registry Number9(3)3209
Alfabeta NameNAPHTHYLACETONITRILE 1-
Reaxys-RN1101012
Chemical Name Translation1-萘乙腈
InChIKeyOQRMWUNUKVUHQO-UHFFFAOYSA-N
Wiswesser Line NotationL66J B1CN
InChIInChI=1S/C12H9N/c13-9-8-11-6-3-5-10-4-1-2-7-12(10)11/h1-7H,8H2
LabNetwork Molecule IDLN00184317
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; large ring; fused rings; 6ring; 10ring; 1fragment
  • {SNA} Building Blocks, C10 to C27, Chemical Synthesis, Cyanides/Nitriles, Nitrogen Compounds, Organic Building Blocks

相关文献及参考

  • Short: IV/16 Title: Surface tension of pure liquids and binary mixtures Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: IV/16 Year: 1997 Keyword: organic compounds; surface tension; liquids; mixtures ISBN: 3-540-63276-X ISBN: 978-3-540-63276-4 Internet Resource: DOI:10.1007/b60566 RefComment: VII, 439 pages.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H301+H311+H331
  • H332 Harmful if inhaled 吸入有害
  • H315 Causes skin irritation 会刺激皮肤
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSAM1240000
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P403+P233
  • P301+P310+P330
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P332+P313
  • P302+P352+P312+P361+P364
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P405 Store locked up. 上锁保管。
  • P305+P351+P338+P337+
Signal word
Packing GroupIII
UN Number 3439
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Hazard Codes Xn
Warnings IRRITANT
Hazard Class6.1 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 180 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#03835

其他信息

  • 用途一:用于有机合成
  • 图谱信息:1-萘乙腈(132-75-2)红外图谱(IR2) 1-萘乙腈(132-75-2)质谱(MS) 1-萘乙腈(132-75-2)核磁图( 1 HNMR) 1-萘乙腈(132-75-2)红外图谱(IR1)
  • TCI Shanghai:1-萘乙腈 1-Naphthylacetonitrile,>;98.0%(GC)(132-75-2)
  • 1-萘乙腈价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 N0366 1-萘乙腈 1-Naphthylacetonitrile 500G 3170元 2014/06/02 N0366 1-萘乙腈 1-Naphthylacetonitrile 25G 374元 2010/06/21 128230250 1-萘乙腈 1-Naphthylacetonitrile 97% 25 GR 951元
  • 1-萘乙腈价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 N0366 1-萘乙腈 1-Naphthylacetonitrile 500G 2610元 2011/04/16 N0366 1-萘乙腈 1-Naphthylacetonitrile 25G 309元 2010/06/21 128230250 1-萘乙腈 1-Naphthylacetonitrile 97% 25 GR 951元
  • 用途二:有机合成中间体。
  • Sigma Aldrich:132-75-2(sigmaaldrich)
  • MOL 文件:132-75-2.mol
  • Acros Organics:1-萘乙腈 1-Naphthylacetonitrile, 97%(132-75-2)
  • 上游原料:氰化钠
  • Alfa Aesar:1-萘基乙睛,97% 1-Naphthylacetonitrile, 97%(132-75-2)
  • 方法一:将695g 1-（氯甲基）萘、1500ml甲醇和475ml水、350g氰化钠的混合物沸腾回流，搅拌反应2h。蒸出1300ml甲醇，冷却，用水洗涤反应物至中性，得670-680g 1-萘乙腈。
  • MSDS 信息:1-Naphthyl acetonitrile(132-75-2).msds

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Cyanides/Nitriles - Nitrogen Compounds
  6. C10 to C27 - Cyanides/Nitriles

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