2-Naphthaldehyde 2-萘甲醛

CAS 66-99-9 MFCD00004094

化学结构图

66-99-9
SMILES: O=CC1C=C2C=CC=CC2=CC=1

化学属性

Mol. FormulaC11H8O
Mol. Weight156
Melting Point58-61
Density1.155
TSCANo
Boiling Point147°C/11mmHg(lit.)
Stability对空气敏感
Flash Point160°C/19mm
Appearance 白色片状结晶。熔点59℃,沸点160℃(1.53kPa)。溶于乙醇、乙醚,能随水蒸气蒸出。
Solubility可溶于乙醇、乙醚、丙酮。

别名和识别编码

Chemical Name2-Naphthaldehyde
Synonym (2)naphthaldehyde -Naphthaldehyde 2-Formylanaphthalene 2-NAPHTHALDEHYDE 98% 2-NAPHTHYLALDEHYDE 2-Naphathalenecarboxaldehyde 2-Naphthakdehyde 2-Naphthaldehyde 2-Naphthaldehyde,98% 2-Naphthalenecarboxaldehyde 2-Naphthylaldehyde 2-naphthaldehyde (beta) 2-naphthalenecarbaldehyde 2-萘甲醛, 98% B-NAPHTHALDEHYDE BETA-NAPHTHALDEHYDE NAPHTHALENE-B-ALDEHYDE NCR 1 Naphthaldehyde,97% Naphthalin-2-aldehyd Naphthalin-2-carbaldehyde beta-Formylnaphthalene beta-Naphthylcarboxaldehyde naphthalene-2-carbaldehyde β-Naphthaldehyde β-Naphthoaldehyde β-Naphthylaldehyde
Beilstein Registry Number507750
PubChem Substance ID87573417
CAS Number66-99-9
EC Number200-640-2
MDL NumberMFCD00004094
Reaxys-RN507750
Chemical Name Translation2-萘甲醛
Wiswesser Line NotationL66J CVH
LabNetwork Molecule IDLN00225341
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分类

  • Aldehydes, Building Blocks, C10-C12, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks
  • {SNA} Aldehydes, Building Blocks, C10-C12, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; large ring; fused rings; 6ring; 10ring; aldehyde; 1fragment

产品应用

  • 用于有机合成。

相关文献及参考

  • Short: II/3
  • Beilstein:7(3)1957
  • Short: III/35D2

安全信息

WGK Germany3
RTECSQJ0190010
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word Warning
GHS Symbol
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P302+P350
  • P302+P352+P312+P362+P364
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302+H312+H332
Storage condition 密封保存。 对空气敏感,密封保存。 Air Sensitive
Hazard Codes Xn
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FRPSAX Farmaco, Edizione Scientifica. (Casella Postale 227, 27100 Pavia,
   Italy)  V.8-43 1953-88 For publisher information, see FRMCE8
   Volume(issue)/page/year: 19,964,1964

其他信息

  • 凝固点:1.0755
  • 用途一:用于有机合成
  • 下游产品:
  • TCI Shanghai:2-萘甲醛 2-Naphthaldehyde,>;98.0%(GC)(66-99-9)
  • 检测方法:GC
  • Alfa Aesar:2-萘甲醛,98% 2-Naphthaldehyde, 98%(66-99-9)
  • 敏感性:Air Sensitive
  • 2-萘甲醛价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010412 2-萘甲醛 5g 210元 2011/08/23 xw01041260 2-萘甲醛 25g 579元 2011/04/16 N0003 2-萘甲醛 2-Naphthaldehyde 25G 1360元
  • 微溶于水,溶于热水。
  • 海关编码:29122900
  • MSDS 信息:2-Naphthaldehyde(66-99-9).msds
  • F:10-23
  • Sigma Aldrich:66-99-9(sigmaaldrich)
  • 存储注意事项:氮气保护
  • Acros Organics:2-萘甲醛 2-Naphthaldehyde, 98%(66-99-9)
  • 方法一:将干燥氯化氢通入无水二氯化锡和无水乙醚的混合物,至饱和后加入2-萘腈的乙醚溶液,再通入氯化氢至饱和,生成黄色的醛亚胺和四氯化锡的络合物。将络合物用水蒸气蒸馏,从馏出液滤出白色固体产物,即为粗品2-萘甲醛,经减压蒸馏,得纯品,收率约70%。
  • MOL 文件:66-99-9.mol
  • 上游原料:乙醚 --> 亚胺 --> 无水氯化亚锡

系列性分类


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