2,3-Diaminonaphthalene 2,3-二氨基萘

CAS 771-97-1 MFCD00004116

化学结构图

771-97-1
SMILES: Nc1cc2ccccc2cc1N

化学属性

Mol. FormulaC10H10N2
Mol. Weight158.20
Density1.0968
Melting Point198-200°C
SolubilitySlightly soluble in water
TSCAYes
Refractive index1.6342
Stability对光敏感;对热和空气敏感
Boiling Point273.29 °C at 760 mmHg

别名和识别编码

Chemical Name2,3-Naphthalenediamine
CAS Number771-97-1
EC Number212-241-0
Beilstein Registry Number2206394
MDL NumberMFCD00004116
Synonym 2,3-Diaminonaphthalene {LY} 2,3-Diaminonaphthalene 2,3-diaminonaphthalene 2,3-naphthalenediamine {} {LY} 2,3-Diaminonaphthalene {} {} {LY} 2,3-Diaminonaphthalene {} {} {} {LY} 2,3-Diaminonaphthalene {} {} {} {} {LY} 2,3-Diaminonaphthalene {} {} {} {} {} {LY} 2,3-Diaminonaphthalene {} {} {} {} {} {} {LY} 2,3-Diaminonaphthalene {} {} {} {} {} {} {} {LY} 2,3-Diaminonaphthalene {} {} {} {} {} {} {} {} {LY} 2,3-Diaminonaphthalene {} {} {} {} {} {} {} {} {} {LY} 2,3-Diaminonaphthalene {} {} {} {} {} {} {} {} {} {} {LY} 2,3-Diaminonaphthalene {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 2,3-Diaminonaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,3-Diaminonaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,3-Diaminonaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,3-Diaminonaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,3-Diaminonaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID69872
Reaxys-RN2206394
Chemical Name Translation2,3-二氨基萘
LabNetwork Molecule IDLN01080265
Canonical SMILESNC1=C(N)C=C2C=CC=CC2=C1
InChIInChI=1S/C10H10N2/c11-9-5-7-3-1-2-4-8(7)6-10(9)12/h1-6H,11-12H2
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分类

  • {SNA} Fluorescent Indicators and Probes, Fluorescent Labels, Nitric Oxide Probes, Nitric Oxide and Oxygen Probes, Other Fluorescent Labels, Wavelength Index, 发光化合物及其检测,
  • {SNA} Fluorescent Labels, Other Fluorescent Labels, 生化试剂, 荧光探针，标记，粒子和染色剂
  • {SA} Biochemicals and Reagents, Fluorescent
  • {SNA} Fluorescent Indica

产品应用

  • 用于有机合成，还是测定硒的试剂。

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R45 May cause cancer 可能致癌
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P308+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H350 May cause cancer 可能致癌
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes T Xn
Storage condition RT, protect from light {LY} RT, protect from light Refrigerator {} {LY} RT, protect from light {} {} {LY} RT, protect from light {} {} {} {LY} RT, protect from light {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from
UN Number 2811

其他信息

  • 方法一:由2,3-萘二酚与氨在加压下反应而得。将2,3-萘二酚和氨溶液加入高压釜，在250-260℃保持5-6h。反应后经充分冷却，滤出沉淀，用少量水洗涤，干燥得成品。
  • 图谱信息:2,3-二氨基萘 (771-97-1)核磁图( 13 CNMR) 2,3-二氨基萘 (771-97-1)红外图谱(IR2) 2,3-二氨基萘 (771-97-1)质谱(MS) 2,3-二氨基萘 (771-97-1)核磁图( 1 HNMR) 2,3-二氨基萘
  • 外观性质:叶状结晶。溶于醇、醚、丙酮及稀酸，难溶于水。密度：1.0968 熔点：193-199 °C 折光率：1.6342
  • {Chemic
  • Sigma Aldrich:771-97-1(sigmaaldrich)
  • MOL 文件:771-97-1.mol
  • 溶于醇、醚、丙酮及稀酸，难溶于水。

系列性分类

  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Luminescent Compounds/Detection - Biochemicals and Reagents
  4. Wavelength Index - Luminescent Compounds/Detection
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Fluorescent Probes, Labels, Particles and Stains - Biochemicals and Reagents
  4. Fluorescent Labels - Fluorescent Probes, Labels, Particles and Stains
  5. Other Fluorescent Labels - Fluorescent Labels
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Fluorescent Probes, Labels, Particles and Stains - Biochemicals and Reagents
  4. Fluorescent Indicators and Probes - Fluorescent Probes, Labels, Particles and Stains
  5. Nitric Oxide and Oxygen Probes - Fluorescent Indicators and Probes
  6. Nitric Oxide Probes - Nitric Oxide and Oxygen Probes
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Fluorescent Probes, Labels, Particles and Stains
  4. Fluorescent Indicators and Probes
  5. Nitric Oxide and Oxygen Probes
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Fluorescent Probes, Labels, Particles and Stains
  4. Fluorescent Labels
  5. Fluorescein and Derivatives
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Luminescent Compounds/Detection
  4. Fluorescent Probes, Labels, Particles and Stains
  5. Fluorescent Indicators and Probes
  6. Nitric Oxide and Oxygen Probes
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Luminescent Compounds/Detection
  4. Fluorescent Probes, Labels, Particles and Stains
  5. Fluorescent Labels
  6. Fluorescein and Derivatives

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