2,3-Diaminonaphthalene 2,3-二氨基萘

CAS 771-97-1 MFCD00004116

化学结构图

771-97-1
SMILES: Nc1cc2ccccc2cc1N

化学属性

Mol. FormulaC10H10N2
Mol. Weight158.20
Density1.0968
Melting Point198-200°C
SolubilitySlightly soluble in water
TSCAYes
Refractive index1.6342
Stability对光敏感;对热和空气敏感
Boiling Point273.29 °C at 760 mmHg

别名和识别编码

Chemical Name2,3-Naphthalenediamine
CAS Number771-97-1
EC Number212-241-0
Beilstein Registry Number2206394
MDL NumberMFCD00004116
Synonym 2,3-Diaminonaphthalene {LY} 2,3-Diaminonaphthalene 2,3-diaminonaphthalene 2,3-naphthalenediamine {} {LY} 2,3-Diaminonaphthalene {} {} {LY} 2,3-Diaminonaphthalene {} {} {} {LY} 2,3-Diaminonaphthalene {} {} {} {} {LY} 2,3-Diaminonaphthalene {} {} {} {} {} {LY} 2,3-Diaminonaphthalene {} {} {} {} {} {} {LY} 2,3-Diaminonaphthalene {} {} {} {} {} {} {} {LY} 2,3-Diaminonaphthalene {} {} {} {} {} {} {} {} {LY} 2,3-Diaminonaphthalene {} {} {} {} {} {} {} {} {} {LY} 2,3-Diaminonaphthalene {} {} {} {} {} {} {} {} {} {} {LY} 2,3-Diaminonaphthalene {} {} {} {} {} {} {} {} {} {} {} {LY} 2,3-Diaminonaphthalene {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,3-Diaminonaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,3-Diaminonaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,3-Diaminonaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,3-Diaminonapht
PubChem Substance ID69872
Reaxys-RN2206394
Chemical Name Translation2,3-二氨基萘
LabNetwork Molecule IDLN01080265
Canonical SMILESNC1=C(N)C=C2C=CC=CC2=C1
InChIInChI=1S/C10H10N2/c11-9-5-7-3-1-2-4-8(7)6-10(9)12/h1-6H,11-12H2
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分类

  • {SNA} Fluorescent Indicators and Probes, Fluorescent Labels, Nitric Oxide Probes, Nitric Oxide and Oxygen Probes, Other Fluorescent Labels, Wavelength Index, 发光化合物及其检测,
  • {SNA} Fluorescent Labels, Other Fluorescent Labels, 生化试剂, 荧光探针,标记,粒子和染色剂
  • {SA} Biochemicals and Reagents, Fluorescent
  • {SNA} Fluorescent Indica

产品应用

  • 用于有机合成,还是测定硒的试剂。

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R45 May cause cancer 可能致癌
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P308+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H350 May cause cancer 可能致癌
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes T Xn
Storage condition RT, protect from light {LY} RT, protect from light Refrigerator {} {LY} RT, protect from light {} {} {LY} RT, protect from light {} {} {} {LY} RT, protect from light {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect fr
UN Number 2811

其他信息

  • 方法一:由2,3-萘二酚与氨在加压下反应而得。将2,3-萘二酚和氨溶液加入高压釜,在250-260℃保持5-6h。反应后经充分冷却,滤出沉淀,用少量水洗涤,干燥得成品。
  • 图谱信息:2,3-二氨基萘 (771-97-1)核磁图( 13 CNMR) 2,3-二氨基萘 (771-97-1)红外图谱(IR2) 2,3-二氨基萘 (771-97-1)质谱(MS) 2,3-二氨基萘 (771-97-1)核磁图( 1 HNMR) 2,3-二氨基萘
  • 外观性质:叶状结晶。溶于醇、醚、丙酮及稀酸,难溶于水。密度:1.0968 熔点:193-199 °C 折光率:1.6342
  • {Chemic
  • Sigma Aldrich:771-97-1(sigmaaldrich)
  • MOL 文件:771-97-1.mol
  • 溶于醇、醚、丙酮及稀酸,难溶于水。

系列性分类


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