Decahydronaphthalene 十氢萘

CAS 91-17-8 MFCD00004130

化学结构图

91-17-8
SMILES: c1ccc2ccccc2c1

化学属性

Mol. FormulaC10H18
Mol. Weight138.25
Refractive index1.4730 to 1.4780
Boiling Point-
Density0.896
Melting Point-125
Flash Point-
TSCAYes
Autoignition Point482 °F
Vapor Density4.76 (vs air)
Vapor Pressure42 mmHg ( 92 °C)
Solubility6 mg/L at 20 °C
Stability对光、空气和热敏感
pH:A

别名和识别编码

Chemical NameDecahydronaphthalene
Synonym Decahydronaphthalene {LY} Decahydronaphthalene {} {LY} Decahydronaphthalene {} {} {LY} Decahydronaphthalene {} {} {} {LY} Decahydronaphthalene {} {} {} {} {LY} Decahydronaphthalene {} {} {} {} {} {LY} Decahydronaphthalene {} {} {} {} {} {} {LY} Decahydronaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Decahydronaphthalene {} {} {} {} {} {} {} {} {LY} Decahydronaphthalene {} {} {} {} {} {} {} {} {} {LY} Decahydronaphthalene {} {} {} {} {} {} {} {} {} {} {LY} Decahydronaphthalene {} {} {} {} {} {} {} {} {} {} {} {LY} Decahydronaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {LY} Decahydronaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Decahydronaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Decahydronaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Decahydronaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Decahydronaphthalene {} {} {} {} {} {} {} {} {} {} {}
CAS Number91-17-8
PubChem Substance ID7044
EC Number202-046-9
Beilstein Registry Number878165
MDL Number-
Merck Number2846
Chemical Name Translation十氢萘
Reaxys-RN878165
Wiswesser Line NotationL66TJ
LabNetwork Molecule IDLN00199657
InChIInChI=1S/C10H18/c1-2-6-10-8-4-3-7-9(10)5-1/h9-10H,1-8H2
Canonical SMILESC12CCCCC1CCCC2
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分类

  • {SNA} Anhydrous Solvents, Solvent Bottles, Solvent Packaging Options, Solvent by Application, Solvents, Sure/Seal Bottles
  • ACS and Reagent Grade Solvents, Amber Glass Bottles, Carbon Steel Cans with NPT Threads, Reagent, Reagent Grade Solvents, Semi-Bulk Solvents, Solvent Bottles, Solvent Packaging Options, Solvent by Application, Solvents

产品应用

  • 有机物结晶用溶剂,用作油脂、树脂、橡胶等的溶剂和除漆剂,润滑剂 。在微量分析中测定矿物的折射指数。测定硼。色谱分析对比物质。

相关文献及参考

  • Merck 14 ,2846
  • Beil. 5 ,III,245
  • Aldrich MSDS 1 , 548:D / Corp MSDS 1 (1), 1011:A / FT-IR 1 (1), 38:B / FT-NMR 1 (1), 54:B / IR-Spectra (3), 29:B / IR-Spectra (2), 28:F / RegBook 1 (1), 35:O / Sax 6 , 857 / Structure Index 1 , 5:D:2 / Vapor Phase 3 , 56:A

安全信息

GHS Symbol
WGK Germany1
Hazard Codes 3 C,N
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H331 Toxic if inhaled 吸入中毒
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSQJ3150000
Precautionary statements
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P330+P331+P310
  • P303+P361+P353
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P370+P378
  • P403+P233
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Packing GroupIII
UN Number 1147 UN 1147 3/PG 3
Risk Statements
  • R20 Harmful by inhalation 吸入有害
  • R34 Causes burns 会导致灼伤
  • R51/53
Safety Statements
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐:立即求医并出示该容器或标签;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
Hazard Class3
Storage condition RT, stored under argon {LY} RT, stored under argon {} {LY} RT, stored under argon {} {} {LY} RT, stored under argon {} {} {} {LY} RT, stored under argon {} {} {} {} {LY} RT, stored under argon {} {} {} {} {} {LY} RT, stored under argon {} {} {} {} {} {} {LY} RT, stored under argon {} {} {} {} {} {} {} {LY} RT, stored under argon {} {} {} {} {} {} {} {} {LY} RT, stored under argon {} {} {} {} {} {} {} {} {} {LY} RT, stored under argon {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under argon {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under argon {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under argon {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under argon {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under argon {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under argon {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored
Warnings 危化品目录(2015)
TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 50 ppm/24H/90D-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Endocrine - tumors
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1981-  Volume(issue)/page/year:
   5,785,1985

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5 ppm/24H/90D-C
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Endocrine - tumors
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1981-  Volume(issue)/page/year:
   5,785,1985

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4170 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher information, see AEHLAU.
   Volume(issue)/page/year: 4,119,1951

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 5900 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher information, see AEHLAU.
   Volume(issue)/page/year: 4,119,1951

TYPE OF T

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 319 ppm/8H
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - chronic pulmonary edema
   Liver - other changes
   Kidney, Ureter, Bladder - other changes
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD-A086-341

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 993 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Info

Restrict 危险品

其他信息

  • 上游原料:干燥剂 --> 塔板
  • 毒性分级:中毒
  • 职业标准:TLV-TWA 100 毫克/ 立方米; STEL 200 毫克/ 立方米
  • 灭火剂:泡沫、干粉、二氧化碳、砂土
  • Alfa Aesar:十氢化萘,cis+trans,98% Decahydronaphthalene, cis + trans, 98%(91-17-8)
  • MSDS 信息:十氢萘(91-17-8).msds
  • 微有类似甲醇气味,纯品无萘的气味。能随水蒸气挥发。溶于乙醇、乙醚、甲醇、氯仿和苯,可与丙醇和异丙醇以及大多数酮、酯类混溶,不溶于水。
  • 爆炸物危险特性:与空气混合可爆
  • 类别:易燃液体
  • 蒸气密度:4.76 (vs air)
  • 用途二:可用作涂料的溶剂,用于提取脂肪和蜡,代替松节油用于鞋油、地板蜡的制造,可与苯和乙醇配成混合物,作为内燃机的燃料。
  • 方法一:工业上由萘在镍催化剂存在下进行催化加氢得到两种异构体的等量混合物。如果需要较纯的异构体,可将工业级十氢萘用浓硫酸洗至酸层无色。然后碱洗、水洗,分去水层,用干燥剂干燥。减压精馏,在130块理论塔板的塔中,回流比接近145:1,可得纯度达99.93%(重量)的顺式异构体;在200块理论塔板的塔中,回流比为160:1,可得纯度达99.97%的反式异构体。
  • 敏感性:Hygroscopic
  • 海关编码:29021990
  • 用途三:有机物结晶用溶剂,用作油脂、树脂、橡胶等的溶剂和除漆剂,润滑剂 。在微量分析中测定矿物的折射指数。测定硼。色谱分析对比物质。
  • 图谱信息:萘烷(91-17-8)质谱(MS) 萘烷(91-17-8)红外图谱(IR1)
  • Acros Organics:萘烷/十氢萘 Decahydronaphthalene, mixture of cis and trans, 98%(91-17-8)
  • 可燃性危险特性:遇明火、高温、强氧化剂可燃;燃烧排放刺激烟雾
  • 萘烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 81005683 十氢萘;萘烷 kg 120元 2011/08/23 81005680 十氢萘;萘烷 500ml 70元 2011/04/16 D0008 十氢化萘(顺反异构体混和物) Decahydronaphthalene (cis- and trans- mixture) 25ML 131元
  • 急性毒性:口服- 大鼠 LD50: 4170 毫克/ 公斤
  • Sigma Aldrich:91-17-8(sigmaaldrich)
  • 用途一:用作折光率测定的液体,也用作溶剂
  • 下游产品:7-甲基异喹啉 --> 异佛尔酮二异氰酸酯 --> 盐酸氯氨酮
  • 刺激数据:皮肤- 兔子 10 毫克/ 24小时 轻度; 眼- 兔子 500 毫克/ 24小时 轻度
  • 蒸气压:42 mm Hg ( 92 °C)
  • 外观性质:无色液体,有芳香气味。
  • MOL 文件:91-17-8.mol
  • 储运特性:包装完整、轻装轻卸; 库房通风、远离明火、高温、与氧化剂分开存放
  • TCI Shanghai:十氢化萘(顺反异构体混合物)[原油和石油产品中硫成分的测试方法] Decahydronaphthalene (cis- and trans- mixture) [Testing Methods for Sulfur in Crude Oil and Petroleum Products],>;99.0%(GC)(91-17-8)

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