(Trimethylsilyl)methanol 三甲基硅基甲醇

CAS 3219-63-4 MFCD00004596

化学结构图

3219-63-4
SMILES: C[Si](C)(C)CO

化学属性

Mol. FormulaC4H12OSi
Mol. Weight104.22 g/mol
Refractive index1.4180 to 1.4200
Boiling Point121°C
Density0.826 g/mL at 25 °C(lit.)
Flash Point56°C(lit.)
TSCAYes
Melting Point<0°C
Danger-Level
pH:
Redox

别名和识别编码

Chemical Name(Trimethylsilyl)Methanol
Synonym (HYDROXYMETHYL)TRIMETHYLSILANE (Hydroxymethyl)trimethylsilane (TRIMETHYLSILYL)METHANOL (Trimethylsilyl)methanol (trimethylsilyl)-methano (trimethylsilyl)methanol (三甲基硅基)甲醇 (羟甲基)三甲基硅烷 1-TRIMETHYLSILYLMETHANOL 1-TRIMETHYLSILYLMETHANOL, 98+% 1-Trimethylsilylmethanol 1-trimethylsilylmethanol 1-三甲基甲硅烷基甲醇 1-三甲基甲硅烷基甲醇, 98+% Hydroxymethyltrimethylsilane Methanol, (trimethylsilyl)- Silane, (hydroxymethyl)trimethyl- TRIMETHYLHYDROXYMETHYLSILANE Trimethylsilylmethanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00004596
CAS Number3219-63-4
PubChem Substance ID76692
EC Number221-746-5
Beilstein Registry Number1731486
Reaxys-RN1731486
Chemical Name Translation三甲基硅基甲醇
Wiswesser Line NotationQ1-SI-1&1&1
LabNetwork Molecule IDLN01746573
InChIInChI=1S/C4H12OSi/c1-6(2,3)4-5/h5H,4H2,1-3H3
Canonical SMILESC[Si](C)(C)CO
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分类

  • {uni_hamburg} no charge; 1fragment
  • {SNA} Alcohols, Building Blocks, C2 to C6, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds

相关文献及参考

  • Short: III/35F Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Silicon-29 Author: Marsmann, H.C.; Uhlig, F.; Gupta, R.R.; Lechner, M.D.; Mikhova, B.M. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35F Year: 2008 Keyword: NMR; Si-29; chemical shifts; coupling constants; nuclear magnetic resonance; silicon-29 ISBN: 978-3-540-45277-5 (print) ISBN: 978-3-540-45278-2 (electronic) Internet Resource: DOI: 10.1007/978-3-540-45278-2 RefComment: X, 463 p. 40 illus., Hardcover RefComment: Written for: Scientists and engineers in the fields of physics, chemistry, and physical chemistry who intend to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic moment, oriented by a magnetic field, and absorb characteristic frequencies in the radiofrequency part of the spectrum. The spectral lines of the nuclei are highly influenced by the chemical environment, i.e. the structure and interaction of the molecules. NMR is now the leading technique and a powerful tool for the investigation of the structure and interaction of molecules. The present Landolt-Börnstein volume III/35 "Nuclear Magnetic Resonance (NMR) Data" is therefore of major interest to all scientists and engineers who intend to use NMR to study the structure and the binding of molecules. Volume III/35 ''NMR-Data'' is divided into several subvolumes and parts. Subvolume III/35A contains the nuclei B-11 and P-31, subvolume III/35B contains the nuclei F-19 and N-15, subvolume III/35C contains the nucleus H-1, subvolume III/35D contains the nucleus C-13, subvolume III/35E contains the nucleus O-17, subvolume III/35F contains the nucleus Si-29, and subvolume III/35G contains the nucleus Se-77. More nuclei will be presented later.
  • Short: III/38A Title: Refractive Indices of Inorganic, Org

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSPC4100000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Packing GroupIII
UN Number 1993 UN 1987 3/PG 3 UN1993
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R10 Flammable 易燃
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Hazard Codes Xi
Hazard Class3
Storage condition 2-8°C
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1080 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   DANKAS Doklady Akademii Nauk SSSR.  Proceedings of the Academy of Sciences
   of the USSR.  For English translation, see DBIOAM and DKBSAS.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-    1933-
   Volume(issue)/page/year: 229,1011,1976

Restrict

其他信息

  • 三甲基硅基甲醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1250 三甲基硅基甲醇 Trimethylsilylmethanol 5ML 813元 2014/06/02 T1250 三甲基硅基甲醇 Trimethylsilylmethanol 25ML 2780元 2014/06/02 T1250 三甲基硅基甲醇 Trimethylsilylmethanol 1ML 310元
  • MOL 文件:3219-63-4.mol
  • Sigma Aldrich:3219-63-4(sigmaaldrich)
  • TCI Shanghai:三甲基硅基甲醇 Trimethylsilylmethanol,>;97.0%(GC)(3219-63-4)
  • 图谱信息:三甲基硅基甲醇(3219-63-4)质谱(MS) 三甲基硅基甲醇(3219-63-4)核磁图( 1 HNMR) 三甲基硅基甲醇(3219-63-4)红外图谱(IR1) 三甲基硅基甲醇(3219-63-4)核磁图( 13 CNMR)
  • Alfa Aesar:1-三甲基甲硅烷基甲醇,98+% 1-Trimethylsilylmethanol, 98+%(3219-63-4)
  • TSCA:Yes

系列性分类


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