2,2-Bis(bromomethyl)-1,3-propanediol 2,2-二(溴甲基)-1,3-丙二醇

CAS 3296-90-0 MFCD00004688

化学结构图

3296-90-0
SMILES: OCC(CO)(CBr)CBr

化学属性

Mol. FormulaC5H10Br2O2
Mol. Weight261.94
Density1.422
Vapor Pressure10 mmHg ( 178 °C)
Melting Point112-114 °C
Boiling Point235 °C at 760 mmHg

别名和识别编码

Chemical Name2,2-Bis(bromomethyl)-1,3-propanediol
CAS Number3296-90-0
Synonym Dibromoneopentyl Glycol {LY} Dibromoneopentyl Glycol {} {LY} Dibromoneopentyl Glycol {} {} {LY} Dibromoneopentyl Glycol {} {} {} {LY} Dibromoneopentyl Glycol {} {} {} {} {LY} Dibromoneopentyl Glycol {} {} {} {} {} {LY} Dibromoneopentyl Glycol {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dibromoneopentyl Glycol {} {} {} {} {} {} {} {LY} Dibromoneopentyl Glycol {} {} {} {} {} {} {} {} {LY} Dibromoneopentyl Glycol {} {} {} {} {} {} {} {} {} {LY} Dibromoneopentyl Glycol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dibromoneopentyl Glycol {} {} {} {} {} {} {} {} {} {} {} {LY} Dibromoneopentyl Glycol {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dibromoneopentyl Glycol {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dibromoneopentyl Glycol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dibromoneopentyl Glycol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dibromoneopentyl Glycol {} {} {} {} {} {} {} {} {} {} {} {}
EC Number221-967-7
Beilstein Registry Number1(4)2554
MDL NumberMFCD00004688
PubChem Substance ID18692
Reaxys-RN1304582
Chemical Name Translation2,2-二(溴甲基)-1,3-丙二醇
Wiswesser Line NotationQ1X1Q1E1E
LabNetwork Molecule IDLN00225088
InChIInChI=1S/C5H10Br2O2/c6-1-5(2-7,3-8)4-9/h8-9H,1-4H2
Canonical SMILESBrCC(CBr)(CO)CO
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分类

  • Mutagenesis Research Chemicals
  • Aliphatics
  • {SNA} Alcohols, Monomers, Polymer Science, 材料科学
  • {SNA} Alcohols, Materials Science, Monomers, Polymer Science

产品应用

  • ########

相关文献及参考

  • Heddle, J., et al.: Mutat. Res., 123, 61

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
Precautionary statements
  • P302+P352+P332+P313+P362+P364
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P332+P313
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P405 Store locked up. 上锁保管。
  • P308+P313
  • P305+P351+P338+P337+P313
  • P301+P312+P330
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H351 Suspected of causing cancer 怀疑致癌
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
RTECSTY3195500
Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Codes Xn T T,Xn
UN Number 2811
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 102 gm/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-452,1996

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 72800 mg/kg/Y-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Skin and Appendages - tumors
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-452,1996

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0524337

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1880 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0524337

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 800 mg/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   10(Suppl 10),1,1987

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1 mg/plate
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   19(Suppl 21),2,1992

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 124 gm/kg
SEX/DURATION            : male 15 week(s) pre-mating
                          female 15 week(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Maternal Effects - parturition
   Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured
   before birth)
   Reproductive - Effects on Newborn - other postnatal measures or effects
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1981-  Volume(issue)/page/year:
   13,245,1989

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 62 gm/kg
SEX/DURATION            : female 15 week(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Fertility - female fertility index (e.g. # females pregnant
   per # sperm positive females; # females pregnant per # females mated)
   Reproductive - Effects on Newborn - other postnatal measures or effects
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1981-  Volume(issue)/page/year:
   13,245,1989

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 62 gm/kg
SEX/DURATION            : male 15 week(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - testes, epididymis, sperm duct
   Reproductive - Paternal Effects - prostate, seminal vesicle, Cowper's gland,
   accessory glands
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1981-  Volume(issue)/page/year:
   13,245,1989

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • 下游产品:折尼铂
  • 用途一:一种反应性阻燃剂,使用后能达到更加严密的阻燃效果
  • TCI Shanghai:2,2-二(溴甲基)-1,3-丙二醇 2,2-Bis(bromomethyl)-1,3-propanediol,>;98.0%(GC)(3296-90-0)
  • 二溴新戊二醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D1808 2,2-双(溴甲基)-1,3-丙二醇 2,2-Bis(bromomethyl)-1,3-propanediol 500G 268元 2014/06/02 D1808 2,2-双(溴甲基)-1,3-丙二醇 2,2-Bis(bromomethyl)-1,3-propanediol 25G 98元
  • MOL 文件:3296-90-0.mol
  • 图谱信息:二溴新戊二醇(3296-90-0)核磁图( 1 HNMR) 二溴新戊二醇(3296-90-0)质谱(MS) 二溴新戊二醇(3296-90-0)核磁图( 13 CNMR) 二溴新戊二醇(3296-90-0)红外图谱(IR2) 二溴新戊二醇(3296-90-0)红外图谱(IR1)
  • Sigma Aldrich:3296-90-0(sigmaaldrich)
  • MSDS 信息:2,2-Bis(bromomethyl)-1,3-propanediol(3296-90-0).msds
  • 上游原料:季戊四醇
  • 蒸气压:10 mm Hg ( 178 °C)

系列性分类


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