Dibenzyl Phosphite 亚磷酸二苄酯

CAS 17176-77-1 MFCD00004774

化学结构图

17176-77-1
SMILES: O=P(OCC1C=CC=CC=1)OCC1C=CC=CC=1

化学属性

Mol. FormulaC14H15O3P
Mol. Weight262
Density1.187
Boiling Point110-120
Refractive indexn20/D 1.555(lit.)
Flash Point>110°(230°F)
TSCANo
Melting Point-5

别名和识别编码

Chemical NameDibenzyl Phosphite
Synonym Phosphorous acid dibenzyl esterDibenzylphosphonate Phosphonic acid, dibenzyl ester Dibenzyl phosphite Dibenzylphosphite Dibenzyl hydrogen phosphite 亚磷酸二苄酯 Phosphonic acid, bis(phenylmethyl) ester Benzyl phosphite (C7H7O)2(HO)P phosphonic acid dibenzyl ester Phosphorous acid dibenzyl ester Phosphorigsäuredibenzylester Phosphorous acid, bis(phenylmethyl) ester 二苄基亚磷酸酯 Dibenzyl phosphonate Benzyl phosphonate ((C7H7O)2HPO) Phosphorigsäure-dibenzylester
Beilstein Registry Number1982794
PubChem Substance ID24893776
CAS Number17176-77-1
EC Number241-226-1
MDL NumberMFCD00004774
Reaxys-RN1982794
Merck Number3014
Chemical Name Translation亚磷酸二苄酯
LabNetwork Molecule IDLN01269975
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分类

  • Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Phosphates/Phosphites, Phosphorus Compounds
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Phosphates/Phosphites, Phosphorus Compounds

相关文献及参考

  • A selective method for the phosphorylation of phenols involves reaction in the presence of N-ethyldiisopropylamine and DMAP to give the dibenzyl phenyl phosphate: Tetrahedron Lett., 37, 771 (1996).
  • Short: III/35A
  • Short: III/38A

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves
Signal word
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P332+P313
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S24 Avoid contact with skin 避免皮肤接触；
  • S37 Wear suitable gloves 戴适当手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Storage condition Moisture Sensitive
GHS Symbol
Hazard Codes Xi
Packing GroupIII

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Organic Phosphates/Phosphites - Phosphorus Compounds

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