Pentafluorothiophenol 五氟苯硫酚

CAS 771-62-0 MFCD00004828

化学结构图

771-62-0
SMILES: Fc1c(F)c(F)c(S)c(F)c1F

化学属性

Mol. FormulaC6HF5S
Mol. Weight200.13
Density1.501
Refractive indexn20/D 1.4645(lit.)
Flash Point51°C(lit.)
TSCANo
Boiling Point143°C(lit.)
Melting Point-24
Stability对空气敏感
Appearance colorless liq.

别名和识别编码

Chemical NamePentafluorothiophenol
MDL NumberMFCD00004828
CAS Number771-62-0
Synonym Pentafluorothiophenol {LY} Pentafluorothiophenol {} {LY} Pentafluorothiophenol {} {} {LY} Pentafluorothiophenol {} {} {} {LY} Pentafluorothiophenol {} {} {} {} {LY} Pentafluorothiophenol {} {} {} {} {} {LY} Pentafluorothiophenol {} {} {} {} {} {} {LY} Pentafluorothiophenol {} {} {} {} {} {} {} {LY} Pentafluorothiophenol {} {} {} {} {} {} {} {} {LY} Pentafluorothiophenol {} {} {} {} {} {} {} {} {} {LY} Pentafluorothiophenol {} {} {} {} {} {} {} {} {} {} {LY} Pentafluorothiophenol {} {} {} {} {} {} {} {} {} {} {} {LY} Pentafluorothiophenol {} {} {} {} {} {} {} {} {} {} {} {} {LY} Pentafluorothiophenol {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Pentafluorothiophenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Pentafluorothiophenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Pentafluorothiophenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Pentafluorothio
EC Number212-236-3
Beilstein Registry Number1876292
PubChem Substance ID13042
Chemical Name Translation五氟苯硫酚
Reaxys-RN1876292
Wiswesser Line NotationSHR BF CF DF EF FF
InChIKeyUVAMFBJPMUMURT-UHFFFAOYSA-N
LabNetwork Molecule IDLN01746185
Canonical SMILESFC1=C(F)C(F)=C(F)C(S)=C1F
InChIInChI=1S/C6HF5S/c7-1-2(8)4(10)6(12)5(11)3(1)9/h12H
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfur Compounds, Thiols/Mercaptans

相关文献及参考

安全信息

RTECSDC1940000
Packing GroupII
UN Number 2920
Risk Statements
  • R10 Flammable 易燃
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
  • R34 Causes burns 会导致灼伤
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen Air Sensitive Flammables area {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {}
GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H302+H312
  • H312 Harmful in contact with skin 皮肤接触有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H331 Toxic if inhaled 吸入中毒
  • H332 Harmful if inhaled 吸入有害
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P352
  • P302+P361+P354
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P312
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P316
  • P317
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Hazard Codes 8 C C,T
Hazard Class8/3
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 56 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#03384

其他信息

  • 图谱信息:五氟硫酚(771-62-0)质谱(MS) 五氟硫酚(771-62-0)核磁图( 13 CNMR)
  • Sigma Aldrich:771-62-0(sigmaaldrich)
  • MOL 文件:771-62-0.mol
  • F:10-13-23
  • 五氟硫酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0861 五氟苯硫酚 Pentafluorobenzenethiol 25G 1840元 2014/06/02 P0861 五氟苯硫酚 Pentafluorobenzenethiol 5G 560元 2010/06/21 129920250 五氟硫酚 Pentafluorothiophenol 97% 25 ML 3776元
  • Acros Organics:五氟硫代苯酚 Pentafluorothiophenol, 97%(771-62-0)
  • Alfa Aesar:五氟噻吩,97% Pentafluorothiophenol, 97%(771-62-0)
  • TCI Shanghai:五氟苯硫酚 Pentafluorobenzenethiol,>;95.0%(GC)(771-62-0)
  • 敏感性:Stench
  • Hazard Note:Toxic/Stench

系列性分类


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