Triphenylphosphine sulfide 三苯基膦硫

CAS 3878-45-3 MFCD00004917

化学结构图

3878-45-3
SMILES: S=P(c1ccccc1)(c1ccccc1)c1ccccc1

化学属性

Mol. FormulaC18H15PS
Mol. Weight294.35
Melting Point161-163 °C
TSCANo
Density1.20
Boiling Point428.7±28.0 °C at 760 mmHg

别名和识别编码

Chemical NameTriphenylphosphine Sulfide
Beilstein Registry Number16(3)866
PubChem Substance ID19758
CAS Number3878-45-3
EC Number223-407-7
MDL NumberMFCD00004917
Reaxys-RN645872
Synonym Triphenylphosphine sulfide {LY} Triphenylphosphine sulfide {} {LY} Triphenylphosphine sulfide {} {} {LY} Triphenylphosphine sulfide {} {} {} {LY} Triphenylphosphine sulfide {} {} {} {} {LY} Triphenylphosphine sulfide {} {} {} {} {} {LY} Triphenylphosphine sulfide {} {} {} {} {} {} {LY} Triphenylphosphine sulfide {} {} {} {} {} {} {} {LY} Triphenylphosphine sulfide {} {} {} {} {} {} {} {} {LY} Triphenylphosphine sulfide {} {} {} {} {} {} {} {} {} {LY} Triphenylphosphine sulfide {} {} {} {} {} {} {} {} {} {} {LY} Triphenylphosphine sulfide {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylphosphine sulfide {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylphosphine sulfide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylphosphine sulfide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylphosphine sulfide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation三苯基膦硫
InChIKeyVYNGFCUGSYEOOZ-UHFFFAOYSA-N
Wiswesser Line NotationSPR&R&R
LabNetwork Molecule IDLN00195913
InChIInChI=1S/C18H15PS/c20-19(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
Canonical SMILESS=P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Phosphorus Compounds, Synthetic Reagents
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Phosphorus Compounds, Synthetic Reagents

相关文献及参考

  • Short: III/35D2
  • In the presence of TFA, converts epoxides to episulfides (thiiranes) of the same stereochemistry: J. Am. Chem. Soc., 94, 2880 (1972).
  • The Pd-catalyzed bisalkoxycarbonylation of olefins gives improved yields in the presence of triphenylphosphine sulfide as a ligand. The phosphine oxide and selenide were significantly less effective, and no product was obtained with triphenylphosphine itself: Tetrahedron Lett, 39, 7529 (1998):

安全信息

Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P301+P317
  • P302+P352
  • P302+P352+P312+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P317
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
WGK Germany3
GHS Symbol
Signal word Warning
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H302+H312
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xn
RTECSSZ2820000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
UN Number UN3464
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Packing GroupIII
Hazard Class6.1 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 180 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#05727

Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr

其他信息

  • Acros Organics:三苯基瞵硫 Triphenylphosphine sulfide, 99+%(3878-45-3)
  • Sigma Aldrich:3878-45-3(sigmaaldrich)
  • MOL 文件:3878-45-3.mol
  • TCI Shanghai:三苯基膦硫 Triphenylphosphine Sulfide,>;99.0%(GC)(3878-45-3)
  • Alfa Aesar:三苯基硫化膦,98% Triphenylphosphine sulfide, 98%(3878-45-3)
  • 三苯基瞵硫价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1066 三苯基膦硫 Triphenylphosphine Sulfide 500G 2470元 2014/06/02 T1066 三苯基膦硫 Triphenylphosphine Sulfide 25G 305元 2010/06/21 159030100 三苯基瞵硫 Triphenylphosphine sulfide 99+% 10 GR 555元

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Thiol Esters - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Synthetic Reagents - Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Phosphorus Halides
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds
  4. Elemental Phosphorus

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