N,N′-Diphenylthiourea N,N-二苯基硫脲

CAS 102-08-9 MFCD00004921

化学结构图

102-08-9
SMILES: S=C(Nc1ccccc1)NC1CCCCC1

化学属性

Mol. FormulaC13H12N2S
Mol. Weight228.31
Melting Point152-155°C
Density1.32
TSCAYes
Solubility<0.01 G/100 ML AT 19 ºC
Appearance 白色有光泽的片状结晶。熔点154-155℃，相对密度1.32，溶于四氢呋喃、环己酮、丙酮、醇、乙醚，微溶于聚氯乙烯用的各种增塑剂，不溶于水和二硫化碳。易燃，味苦，磨擦时发光。
Boiling Point348.7±25.0 °C at 760 mmHg
Flash Point164.7±23.2 °C

别名和识别编码

Chemical NameN,N′-Diphenylthiourea
CAS Number102-08-9
Alfabeta NameDIPHENYLTHIOUREA 132---,
MDL NumberMFCD00004921
Synonym N,N′-Diphenylthiourea {LY} N,N′-Diphenylthiourea {} {LY} N,N′-Diphenylthiourea {} {} {LY} N,N′-Diphenylthiourea {} {} {} {LY} N,N′-Diphenylthiourea {} {} {} {} {LY} N,N′-Diphenylthiourea {} {} {} {} {} {LY} N,N′-Diphenylthiourea {} {} {} {} {} {} {LY} N,N′-Diphenylthiourea {} {} {} {} {} {} {} {LY} N,N′-Diphenylthiourea {} {} {} {} {} {} {} {} {LY} N,N′-Diphenylthiourea {} {} {} {} {} {} {} {} {} {LY} N,N′-Diphenylthiourea {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} N,N′-Diphenylthiourea {} {} {} {} {} {} {} {} {} {} {} {LY} N,N′-Diphenylthiourea {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N′-Diphenylthiourea {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N′-Diphenylthiourea {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N′-Diphenylthiourea {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N′-Diphenylthiourea {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID87576188
EC Number203-004-2
Beilstein Registry Number644277
Merck Number3333
Reaxys-RN644277
Chemical Name TranslationN,N-二苯基硫脲
LabNetwork Molecule IDLN00159958
InChIInChI=1S/C13H12N2S/c16-13(14-11-7-3-1-4-8-11)15-12-9-5-2-6-10-12/h1-10H,(H2,14,15,16)
Canonical SMILESS=C(NC1=CC=CC=C1)NC2=CC=CC=C2
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Bioactive Small Molecules, Building Blocks, Cell Biology, Chemical Synthesis, DIG-DY, Organic Building Blocks, Sulfur Compounds, Thioureas
  • {SNA} Building Blocks, Chemical Synthesis, DIG-DY, Organic Building Blocks, Sulfur Co

产品应用

  • 测定锇、钌的化学试剂。

相关文献及参考

  • Short: II/27B
  • Merck:14,3333
  • Short: III/5a
  • Merck:14,3333 Beilstein:12,394
  • {uni_ham

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard statements
  • H300 Fatal if swallowed 吞食致命
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
RTECSFE1225000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P310+P330
  • P302+P352+P333+P313+P362+P364
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Packing GroupII
UN Number 2811
Risk Statements
  • R25 Toxic if swallowed 吞咽有毒
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
Hazard Codes 6.1 T
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class6.1

其他信息

  • Acros Organics:Thiocarbanilide, 98%(102-08-9)
  • 用途一:用作天然胶乳和氯丁胶乳快速硫化促进剂
  • 溶于四氢呋喃、环己酮、丙酮、醇、乙醚，微溶于聚氯乙烯用的各种增塑剂，不溶于水和二硫化碳。易燃，味苦，磨擦时发光。
  • 用途二:用作测定锇和钌的试剂、硫浆促进剂，也用于染料工业
  • 海关编码:29309070
  • 图谱信息:N,N'-二苯基硫脲(102-08-9)核磁图( 1 HNMR) N,N'-二苯基硫脲(102-08-9)红外图谱(IR2) N,N'-二苯基硫脲(102-08-9)红外图谱(IR1) N,N'-二苯基硫脲(102-08-9)核磁图( 13 CNMR) N,N'-二苯基硫脲(102-08-9)质谱(MS)
  • MOL 文件:102-08-9.mol
  • 下游产品:2-巯基苯并噻唑 --> 二苯胍 --> 硫代异氰酸苯酯
  • 用途三:本品为硫化速度较快的促进剂，主要用于天然胶乳和氯丁胶乳制品，亦可用于制造硫化胶囊、水胎、补胎胶、电线电缆、工业制品、胶鞋等。本品也可作为乳液法聚氯乙烯的热稳定剂，特别适用于软质制品，一般用量为0.2-0.5%，不会使塑料制品着色，但不能防止制品受光变色。不能与铅、镉稳定剂并用，否则会导致制品变色。二苯硫脲也是医药、染料的中间体，用于生产靛蓝、甲基靛蓝、硫化染料及浮选剂、防酸剂等。本品是测定锇、钌的化学试剂。本品毒性低，小鼠腹腔注射LD50为400毫克/公斤，大鼠口服LD50为2000毫克/公斤，无致癌性。
  • MSDS 信息:1,3-Diphenyl-2-thiourea(102-08-9).msds
  • N,N'-二苯基硫脲价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30077524 对称二苯硫脲 25g 47元 2011/04/16 T0197 1,3-二苯基-2-硫脲 1,3-Diphenyl-2-thiourea 25G 156元 2011/04/16 T0197 1,3-二苯基-2-硫脲 1,3-Diphenyl-2-thiourea 500G 437元
  • TCI Shanghai:1,3-二苯基-2-硫脲 1,3-Diphenyl-2-thiourea,>;98.0%(T)(102-08-9)
  • Alfa Aesar:N,N'-二苯基硫脲,98% N,N'-Diphenylthiourea, 98%(102-08-9)
  • 用途四:测定锇、钌的化学试剂。
  • Sigma Aldrich:102-08-9(sigmaaldrich)
  • 方法一:由苯胺与二硫化碳缩合而得。公斤/吨苯胺 900二硫化碳 420

系列性分类

  1. Life Science 生命科学
  2. Cell Biology 细胞生物学
  3. Bioactive Small Molecules - Cell Biology
  4. DIG-DY - Bioactive Small Molecules
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Thioureas - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Thiols/Mercaptans

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