• 原料直供
• 试剂商城
• 直接询价

分类

• {Chemicalbook} 电镀化学品: 烯丙基硫脲
• {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfur Compounds, Thioureas
• {uni_hamburg} no charge; 1fragment

产品应用

• 无氰镀铜添加剂；防腐剂；有机合成原料。

相关文献及参考

• [2]. Yu, Y., J.A. Ramsay, and B.A. Ramsay, Use of allylthiourea to produce soluble methane monooxygenase in the presence of copper. Appl Microbiol Biotechnol, 2009. 82(2): p. 333-9.
• Merck:14,9362
• Merck:14,9362 Beilstein:4(4)1072
• Short: II/27B
• Short: III/5a
• [1]. Ginestet, P., et al., Estimation of nitrifying bacterial activities by measuring oxygen uptake in the presence of the metabolic inhibitors allylthiourea and azide. Appl Environ Microbiol, 1998. 64(6): p. 2266-8.
• [1]. Ginestet, P., et al., Estimation of nitrifying bacterial activities by measuring oxygen uptake in the presence of the metabolic inhibitors allylthiourea and azide. Appl Environ Microbiol, 1998. 64(6): p. 2266-8.
• [2]. Yu, Y., J.A. Ramsay, and B.A. Ramsay, Use of allylthiourea to produce soluble methane monooxygenase in the presence of copper. Appl Microbiol Biotechnol, 2009. 82(2): p. 333-9.
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安全信息

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION

{

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 50 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HBAMAK "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." (Leipzig,
   Ger. Dem. Rep.)  Volume(issue)/page/year: 4,1289,1935

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 110 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HBAMAK "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." (Leipzig,
   Ger. Dem. Rep.)  Volume(issue)/page/year: 4,1289,1935

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1858 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   YKKZAJ Yakugaku Zasshi.  Journal of Pharmacy.  (Nippon Yakugakkai, 2-12-15
   Shibuya, Shibuya-ku, Tokyo 150, Japan)  No.1-    1881-
   Volume(issue)/page/year: 94,1419,1974

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 90,260,1947

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 150 ug/plate
REFERENCE :
   ABCHA6 Agricultural and Biological Chemistry.  (Maruzen Co. Ltd., POB 5050,
   Tokyo International, Tokyo 100-31, Japan)  V.25-    1961-
   Volume(issue)/page/year: 44,3017,1980

其他信息

• 烯丙基硫脲价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30004926 烯丙基硫脲;硫代芥子胺 100g 41元 2011/04/16 A0220 1-烯丙基-2-硫脲 1-Allyl-2-thiourea 25G 382元 2011/04/16 A0220 1-烯丙基-2-硫脲 1-Allyl-2-thiourea 500G 2920元
• 用途二:本品是用作无氰镀铜添加剂，增加镀品光亮和耐腐蚀性。亦可作防腐剂。
• 用途三:无氰镀铜添加剂、防腐剂、有机合成原料。
• 方法一:由氯丙烯与硫氰化钠加热熔解，冷却后加入少量碘化钾，再加入氯丙烯及乙醇，回流16 h，冷却分出油层，用水洗3～4 次，得异硫氰酸烯丙酯，用无水氯化钙干燥，蒸馏，收集沸点在140～155 ℃馏分。然后将其加入氨水中，在搅拌下加热至80 ℃左右，发生强烈反应，冷却析出结晶，过滤，干燥而得粗品，再经乙醇重结晶而得成品。
• 用途一:用作无氰镀铜添加剂、防腐剂，也用于有机合成
• 可燃性危险特性:可燃;燃烧产生有毒氮氧化物和硫氧化物烟雾
• Sigma Aldrich:109-57-9(sigmaaldrich)
• 类别:有毒物品
• Alfa Aesar:烯丙基硫脲，98% N-Allylthiourea, 98%(109-57-9)
• MSDS 信息:Allylthiourea(109-57-9).msds
• 海关编码:29309070
• 图谱信息:烯丙基硫脲(109-57-9)核磁图( 13 CNMR) 烯丙基硫脲(109-57-9)红外图谱(IR2) 烯丙基硫脲(109-57-9)红外图谱(IR1) 烯丙基硫脲(109-57-9)质谱(MS) 烯丙基硫脲(109-57-9)核磁图( 1 HNMR)
• 储运特性:库房通风低温干燥; 与食品原料分开存放
• Acros Organics:烯丙基硫脲 Allylthiourea, 98%(109-57-9)
• 用途四:无氰镀铜添加剂；防腐剂；有机合成原料。
• 微有蒜臭味。能溶于30份水，溶于乙醇。溶解度: 67 g/l 水(20°C) ， 1370 g/l 甲醇；不溶于苯，溶于乙醚，硼酸、苯甲酸和聚氨酯溶液；微溶于70%乙醇
• 上游原料:无水氯化钙 --> 碘化钾 --> 丙烯酰氯 --> 硫氰酸钠 --> 异硫氰酸烯丙酯
• 方法二:由氯丙烯与硫氰化钠反应，先将硫氰化钠加热溶解，冷却后加入少量碘化钾，再加入氯丙烯及乙醇，回流16h，冷却分出油层用水洗3-4次得异硫氰酸烯丙酯，用无水氯化钙干燥，蒸馏，收集沸点为140-155℃馏分而得“酯”。然后将其加入氨水中在搅拌下加热至80℃左右，发生猛烈反应，冷却析出结晶，过滤，干燥而得粗品，再经乙醇重结晶而得成品。
• 急性毒性:口服-大鼠 LD50: 100 毫克/公斤; 腹腔-大鼠LD50: 500 毫克/公斤
• 毒性分级:高毒
• MOL 文件:109-57-9.mol
• 灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水
• TCI Shanghai:烯丙基硫脲 1-Allyl-2-thiourea,>;98.0%(T)(109-57-9)