9(10H)-Acridone 9(10H)-吖啶酮

CAS 578-95-0 MFCD00005019

化学结构图

578-95-0
SMILES: O=c1c2ccccc2[nH]c2ccccc12

化学属性

Mol. FormulaC13H9NO
Mol. Weight195.22
Melting Point>300°C
TSCAYes
Density1.23
Appearance 黄色针状或片状结晶。熔点361-362℃。能溶于热乙酸、热醇、氢氧化钾和醇溶液，不溶于水、醚、苯和氯仿。在醇溶液中显蓝色荧光。
Boiling Point355°C at 760 mmHg

别名和识别编码

Chemical Name9(10H)-Acridone
CAS Number578-95-0
Alfabeta NameACRIDONE H910()-
MDL NumberMFCD00005019
Synonym Acridone {LY} Acridone {} {LY} Acridone {} {} {LY} Acridone {} {} {} {LY} Acridone {} {} {} {} {LY} Acridone {} {} {} {} {} {LY} Acridone {} {} {} {} {} {} {LY} Acridone {} {} {} {} {} {} {} {LY} Acridone {} {} {} {} {} {} {} {} {LY} Acridone {} {} {} {} {} {} {} {} {} {LY} Acridone {} {} {} {} {} {} {} {} {} {} {LY} Acridone {} {} {} {} {} {} {} {} {} {} {} {LY} Acridone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Acridone {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Acridone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Acridone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Acridone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Acridone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Acridone {} {} {} {} {} {}
PubChem Substance ID2015
Beilstein Registry Number7104
EC Number209-434-7
Reaxys-RN7104
Chemical Name Translation9(10H)-吖啶酮
Wiswesser Line NotationT C666 BM IVJ
LabNetwork Molecule IDLN00173490
InChIInChI=1S/C13H9NO/c15-13-9-5-1-3-7-11(9)14-12-8-4-2-6-10(12)13/h1-8H,(H,14,15)
Canonical SMILESC1=C2C(=CC=C1)C(C3=C(N2)C=CC=C3)=O
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分类

  • {SNA} A-AM, Bioactive Small Molecules, Building Blocks, C13 to C14, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks, 细胞生物学
  • A-AM, Bioactive Small Molecules, Building Blocks, C13 to C14, Carbonyl Compounds, Cell Biology, Chemical Synthesis, Ketones, Organic Building Blo
  • {SA} A-AM, Bioactive Small Molecules, Building Blocks, C13 to C14, Carbonyl Compounds, Cell Biology, Chemical Synthesis, Ketones, Organic Build

产品应用

  • 有机合成。

相关文献及参考

  • Beilstein:21(3/4)4171

安全信息

Warnings IRRITANT
WGK Germany3
RTECSAR6976000
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Hazard Codes Xn
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
GHS Symbol 
TYPE OF TEST            : DNA adduct
TEST SYSTEM             : Mammal - species unspecified Lymphocyte
DOSE/DURATION           : 10 pph
REFERENCE :
   BIPMAA Biopolymers.  (John Wiley & Sons, Inc., 605 Third Ave., New York, NY
   10158)  V.1-    1963-  Volume(issue)/page/year: 11,2537,1972

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • 下游产品:10-氮(杂)蒽 --> 分散艳蓝 S-FR
  • 储运特性:库房通风低温干燥
  • 方法一:由邻氯苯甲酸和苯胺反应生成二苯胺-2-羧酸(即邻苯氨基苯甲酸或N-苯基氨茴酸)，再在浓硫酸中脱水环合而得。在装有蒸馏装置和搅拌器的250ml三颈烧瓶中，加入10g(0.064mol)邻氯苯甲酸，10g碳酸钾，40ml(0.42mol)苯胺和0.1g新制备的铜粉。将混合物搅拌、加热，慢慢将反应产生的水蒸出来。约需3h。然后用水蒸气蒸馏法蒸出未反应的苯胺。将剩余物加活性炭脱色过滤。滤液中加入浓盐酸使结晶析出，冷却，滤出结晶，用少量冷水洗涤抽干。粗品用乙酸和乙醇重结晶，熔点为183-184℃。把5g邻苯氨基苯甲酸与35ml浓硫酸混合，在水浴上加热3h。冷却后，在强烈搅拌下加入40ml冰水.滤出沉淀。将它加到300ml2.5%的碳酸钠溶液中，加热，过滤，用水洗涤后干燥，即得吖啶酮。
  • 可燃性危险特性:可燃; 加热分解释放有毒氮氧化物烟雾
  • MOL 文件:578-95-0.mol
  • Sigma Aldrich:578-95-0(sigmaaldrich)
  • TCI Shanghai:9(10H)-吖啶酮 9(10H)-Acridone,>;98.0%(LC)(N)(578-95-0)
  • Acros Organics:吖啶酮 9(10H)-Acridone, 99%(578-95-0)
  • 能溶于热乙酸、热醇、氢氧化钾和醇溶液，不溶于水；醚；苯和氯仿。在醇溶液中显蓝色荧光。
  • 上游原料:铜 --> 2-氯苯甲酸 --> N-苯基邻氨基苯甲酸 --> 邻苯
  • 用途一:有机合成。
  • 灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水
  • 图谱信息:吖啶酮(578-95-0)质谱(MS) 吖啶酮(578-95-0)红外图谱(IR2) 吖啶酮(578-95-0)红外图谱(IR1)
  • Alfa Aesar:9(10H)吖啶酮,99% 9(10H)-Acridone, 99%(578-95-0)
  • 吖啶酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0133 9(10H)-吖啶酮 9(10H)-Acridone 25G 2180元 2014/06/02 A0133 9(10H)-吖啶酮 9(10H)-Acridone 5G 792元 2010/06/21 400261000 吖啶酮 9(10H)-Acridone 96%, pract. 100 GR 7755元
  • 类别:有毒物品

系列性分类

  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Luminescent Compounds/Detection - Biochemicals and Reagents
  4. Stains and Dyes - Luminescent Compounds/Detection
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Acridines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones - Carbonyl Compounds
  6. C13 to C14 - Ketones
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones 酮
  6. C11 to C12

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