2,2'-Bioxirane 1,2:3,4-双环氧丁烷
CAS 1464-53-5 MFCD00005120
化学结构图
SMILES: C1OC1C1CO1
化学属性
| Mol. Formula | C4H6O2 |
|---|---|
| Mol. Weight | 86.09 g/mol |
| Refractive index | 1.4320 to 1.4350 |
| Boiling Point | 56-58°/25mm |
| Density | 1.112 |
| Melting Point | -19° |
| Flash Point | 45°C(lit.) |
| TSCA | Yes |
| Vapor Pressure | 25 mmHg ( 56 °C) |
| Appearance | 浅黄液体。熔点4℃, 沸点138℃, 密度 1.113 ;g/mL ;at 25 ;°C, 蒸气压 25 mm Hg , 折光率 n 20/D 1.434, 闪点 114 ;°F |
别名和识别编码
| Chemical Name | 2,2'-Bioxirane |
|---|---|
| Synonym | (±)-1,2;3,4-diepoxy-butane 1,1'-Bi[ethylene oxide] 1,1'-Bi[ethylene oxide] 1,1’-bi(ethyleneoxide) 1,2,3,4-DIEPOXYBUTANE 1,2,3,4-Diepoxy-butan 1,2,3,4-diepoxybutane 1,2,3,4-二环氧丁烷 1,2,3,4-二環氧丁烷 1,2-3,4-diepoxybutane 1,2:3,4-DIEPOXYBUTANE 1,2:3,4-Diepoxybutane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { |
| CAS Number | 1464-53-5 |
| PubChem Substance ID | 11254 |
| Beilstein Registry Number | 19,14 |
| MDL Number | MFCD00005120 |
| Reaxys-RN | 79831 |
| Merck Number | 3676 |
| EC Number | 215-979-1 |
| Chemical Name Translation | 1,2:3,4-双环氧丁烷 |
| LabNetwork Molecule ID | LN01740270 |
| InChI | InChI=1S/C4H6O2/c1-3(5-1)4-2-6-4/h3-4H,1-2H2 |
| Canonical SMILES | C1(C2OC2)CO1 |
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分类
- {uni_hamburg} no charge; oxygen heterocycle; alicycle; 3ring; ether; racemate; 1fragment
- {SNA} Epoxide Monomers, Materials Science, Monomers, Polymer Science
相关文献及参考
- Beil. 19 ,14 / Beil. 19 ,III/IV,110
- Aldrich MSDS 1 , 298:D / Corp MSDS 1 (1), 597:C / FT-IR 1 (1), 234:A / FT-IR 2 (1), 369:C / FT-NMR 1 (1), 374:B / RegBook 1 (1), 251:E / Sax 6 , 977 / Sigma FT-IR 1 (2), 455:D / Structure Index 1 , 34:D:3 / Vapor Phase 3 , 308:B
- Short: II/19b Title: Molecular Constants: Rotational, Centrifugal Distortion and Related Constants of Diamagnetic Asymmetric Top Molecules Author: Demaison, J.; Hüttner, W.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/19b Year: 1992 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-54578-6 ISBN: 978-3-540-54578-1 Internet Resource: DOI:10.1007/b44334 RefComment: XI, 488 pages. Abstract: Volume II/19 Molecular Constants mostly from Microwave, Molecular Beam and Sub-Doppler Laser Spectroscopy is a supplement to the earlier volumes II/4, II/6, and II/14. The slight change in the title reflects current trends in the applications of spectroscopic methods. Together, the four volumes collect all the critically evaluated data published up to 1989/90 on constants of free molecules obtained by classical and modern spectroscopy. Volume II/19 is divided into four parts to record the growing number of investigations, especially in the microwave and millimeter wave regions, where modern techniques like Fourier Transform Microwave Spectroscopy have made new objects of interest such as molecular complexes and clusters accessible to study. Subvolume II/19b contains corresponding data on diamagnetic asymmetric top molecules.
- Short: II/19c Title: Molecular Constants: Dipole Moments, Quadrupole Coupling Constants, Hindered Rotation and Magnetic Constants of Diamagnetic Molecules Author: Demaison, J.; Hüttner, W.; Tiemann, E.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/19c Year
安全信息
GHS Symbol
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H301 Toxic if swallowed 吞食有毒
- H310 Fatal in contact with skin 皮肤接触致命
- H311 Toxic in contact with skin 皮肤接触中毒
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H330 Fatal if inhaled 吸入致命
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H340 May cause genetic defects 可能导致遗传性缺陷
- H350 May cause cancer 可能致癌
- H351 Suspected of causing cancer 怀疑致癌
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
- P203
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P242 Use only non-sparking tools. 只能使用无火花工具。
- P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P264+P265
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P281 Use personal protective equipment as required. 使用所需的个人防护装备。
- P284 Wear respiratory protection.? 佩戴呼吸保护装置。
- P301+P310
- P301+P316
- P301+P330+P331
- P302+P350
- P302+P352
- P302+P352+P310+P361+P364
- P302+P361+P354
- P303+P361+P353
- P304+P340
- P304+P340+P310
- P305+P351+P338
- P305+P354+P338
- P308+P313
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P316
- P318
- P319
- P320 Specific treatment is urgent (see … on this label). 紧急具体治疗（见本标签上的）。
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
- P330 Rinse mouth. 漱口
- P332+P313
- P332+P317
- P337+P313
- P337+P317
- P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
- P361+P364
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P362+P364
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P370+P378
- P403+P233
- P403+P235
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- R45 May cause cancer 可能致癌
- R26 Very toxic by inhalation 吸入极毒
- R46 May cause inheritable genetic damage 可能引起遗传基因损害
- R24/25 Toxic in contact with skin and if swallowed 皮肤接触及吞食都有毒
- R34 Causes burns 会导致灼伤
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
其他信息
- 储运特性:通风低温干燥; 与库房食品原料分开存放
- F:8-10-18
- Sigma Aldrich:1464-53-5(sigmaaldrich)
- 毒性分级:高毒
- 类别:有毒物品
- 蒸气压:25 mm Hg ( 56 °C)
- TCI Shanghai:二环氧化-1,3-丁二烯 1,3-Butadiene Diepoxide,>;95.0%(GC)(1464-53-5)
- 急性毒性:口服-大鼠 LD50: 78 毫克/公斤; 口服-小鼠 LD50; 72 毫克/公斤
- 灭火剂:干粉,泡沫,沙土,二氧化碳, 雾状水
- MOL 文件:1464-53-5.mol
- 刺激数据:皮肤-兔子 10 毫克/24小时 重度; 眼睛-兔子 0.25 毫克 重度
- 图谱信息:双环氧化丁二烯(1464-53-5)核磁图( 1 HNMR) 双环氧化丁二烯(1464-53-5)红外图谱(IR1) 双环氧化丁二烯(1464-53-5)核磁图( 13 CNMR) 双环氧化丁二烯(1464-53-5)质谱(MS)
- Alfa Aesar:1,2,3,4-二环氧丁烷,95% Butadiene diepoxide, 95%(1464-53-5)
- 可燃性危险特性:可燃; 燃烧产生刺激烟雾
- 双环氧化丁二烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0234 1,3-丁二烯二环氧化物 1,2:3,4-Diepoxybutane 5ML 1020元 2010/05/25 L03919 1,2,3,4-二环氧丁烷, 95% Butadiene diepoxide, 95% 5g 603元 2010/05/25 L03919 1,2,3,4-二环氧丁烷, 95% Butadiene diepoxide, 95% 1g 193元
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