Glycidylisopropylether 异丙基缩水甘油醚

CAS 4016-14-2 MFCD00005139

化学结构图

4016-14-2
SMILES: CC(C)OCC1CO1

化学属性

Mol. FormulaC6H12O2
Mol. Weight116.15828
Refractive index1.4100 to 1.4120
Boiling Point131-132 °C at 760 mmHg
Density0.924 g/mL at 25 °C(lit.)
Flash Point33.33°C
Solubility溶于水、酮、乙醇。

别名和识别编码

Chemical NameGlycidylisopropylether
Synonym Isopropyl glycidyl ether {LY} Isopropyl glycidyl ether {} {LY} Isopropyl glycidyl ether {} {} {LY} Isopropyl glycidyl ether {} {} {} {LY} Isopropyl glycidyl ether {} {} {} {} {LY} Isopropyl glycidyl ether {} {} {} {} {} {LY} Isopropyl glycidyl ether {} {} {} {} {} {} {LY} Isopropyl glycidyl ether {} {} {} {} {} {} {} {LY} Isopropyl glycidyl ether {} {} {} {} {} {} {} {} {LY} Isopropyl glycidyl ether {} {} {} {} {} {} {} {} {} {LY} Isopropyl glycidyl ether {} {} {} {} {} {} {} {} {} {} {LY} Isopropyl glycidyl ether {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Isopropyl glycidyl ether {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Isopropyl glycidyl ether {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Isopropyl glycidyl ether {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Isopropyl glycidyl ether {} {} {} {} {} {} {} {} {} {} {
CAS Number4016-14-2
PubChem Substance ID19920
EC Number223-672-9
Beilstein Registry Number17(5)3,11
MDL NumberMFCD00005139
Reaxys-RN103028
Chemical Name Translation异丙基缩水甘油醚
Wiswesser Line NotationT3OTJ B1OY1&1
LabNetwork Molecule IDLN00238462
InChIInChI=1S/C6H12O2/c1-5(2)7-3-6-4-8-6/h5-6H,3-4H2,1-2H3
Canonical SMILESCC(C)OCC1OC1
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分类

  • {uni_hamburg} no charge; oxygen heterocycle; 3ring; ether; racemate; 1fragment
  • {SNA} Epoxide Monomers, Monomers, Polymer Science, 材料科学
  • {SNA} Epoxide Monomers, Materials Science, Monomers, Polymer Science
  • {SNA} Building Blocks, Chemical Synthesis, Epoxides, Organic Building Blocks, Oxygen Compounds

相关文献及参考

  • Beil. 17 ,V,3,11
  • Corp MSDS 1 (1), 1784:D / FT-IR 2 (1), 367:A / FT-NMR 1 (1), 372:C / RegBook 1 (1), 249:J / Structure Index 1 , 34:A:2 / Vapor Phase 3 , 306:A
  • Short: IV/20B Title: Vapor Pressure and Antoine Coefficients for Oxygen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20B Year: 2000 Keyword: organic compounds; vapor pressure ISBN: 3-540-64968-9 ISBN: 978-3-540-64968-7 Internet Resource: DOI:10.1007/b71424 RefComment: VII, 320 pages.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

GHS Symbol
WGK Germany2
Hazard Codes Xi
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSTZ3500000
Precautionary statements
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P332+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P307+P311
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P370+P378
  • P305+P351+P338
  • P337+P313
  • P302+P352+P332+P313+P362+P364
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P303+P361+P353
  • P403+P233
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
Signal word Warning {} {} {} {} {} {TCI}
UN Number 3271 UN 3271 3/PG 3
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R10 Flammable 易燃
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
Packing GroupIII
Hazard Class3
Storage condition -20°C 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 9650 mg/kg
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - acute pulmonary edema
REFERENCE :
   AMIHAB AMA Archives of Industrial Health.  (Chicago, IL)  V.11-21, 1955-60.
   For publisher information, see AEHLAU.  Volume(issue)/page/year: 14,250,1956

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4200 mg/kg
TOXIC EFFECTS :
   Brain and Coverings - recordings from specific areas of CNS
   Behavioral - somnolence (general depressed activity)
   Behavioral - ataxia
REFERENCE :
   AMIHAB AMA Archives of Industrial Health.  (Chicago, IL)  V.11-21, 1955-60.
   For publisher information, see AEHLAU.  Volume(issue)/page/year: 14,250,1956

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1100 ppm/8H
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - other changes
   Liver - other changes
REFERENCE :
   AMIHAB AMA Archives of Industrial Health.  (Chicago, IL)  V.11-21, 1955-60.
   For publisher information, see AEHLAU.  Volume(issue)/page/year: 14,250,1956

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1500 ppm/4H
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - other changes
   Liver - other changes
REFERENCE :
   AMIHAB AMA Archives of Industrial Health.  (Chicago, IL)  V.11-21, 1955-60.
   For publisher information, see AEHLAU.  Volume(issue)/page/year: 14,250,1956

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill

TYPE OF TEST            : Heritable translocation test
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 2900 ppm
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   23,51,1994

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 20 umol/L
REFERENCE :
   ARTODN Archives of Toxicology.  (Springer-Verlag, Heidelberger Pl. 3, D-1000
   Berlin 33, Fed. Rep. Ger.)  V.32-    1974-  Volume(issue)/page/year:
   46,277,1980

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 2500 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 249,55,1991

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 3300 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 231,205,1990

TYPE OF TEST            : Specific locus test
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 2900 ppm
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   23,51,1994

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1 mg/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science P

其他信息

  • TCI Shanghai:异丙基缩水甘油醚 Glycidyl Isopropyl Ether,>;96.0%(GC)(4016-14-2)
  • MOL 文件:4016-14-2.mol
  • 爆炸物危险特性:久置生成可爆炸之过氧化物
  • Acros Organics:异丙基缩水甘油醚 Isopropyl glycidyl ether, 98%(4016-14-2)
  • 刺激数据:皮肤-兔 459 毫克/3天 中度; 眼睛-兔 92 毫克 中度
  • 毒性分级:中毒
  • 上游原料:钠 --> 异丙醇 --> 环氧氯丙烷
  • 类别:易燃液体
  • 急性毒性:口服- 大鼠 LD50: 4200 毫克/ 公斤; 口服- 小鼠 LD50: 1300 毫克/ 公斤
  • 灭火剂:小火：二氧化碳、化学干粉、酒精泡沫。大火：喷水、水雾、聚合泡沫。
  • 储运特性:库房低温, 通风, 干燥 ; 不可久置;防火; 与氧化剂分开存放
  • 异丙基缩水甘油醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 G0255 异丙基缩水甘油醚 Glycidyl Isopropyl Ether 500ML 855元 2014/06/02 G0255 异丙基缩水甘油醚 Glycidyl Isopropyl Ether 25ML 242元
  • 外观性质:无色液体。
  • MSDS 信息:异丙基缩水甘油醚(4016-14-2).msds
  • Sigma Aldrich:4016-14-2(sigmaaldrich)
  • 职业标准:TWA 240 毫克/立方米; STEL 356 毫克/立方米
  • 可燃性危险特性:易燃; 火场释放辛辣刺激烟雾

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Monomers - Polymer Science
  4. Epoxide Monomers - Monomers
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Epoxides - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Epoxides - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Simple 3-Membered Ring Compounds 简单三元环化合物

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