3-Glycidoxypropyltrimethoxysilane 3-缩水甘油醚氧基丙基三甲氧基硅烷

CAS 2530-83-8 MFCD00005144

化学结构图

2530-83-8
SMILES: CO[Si](CCCOCC1CO1)(OC)OC

化学属性

Mol. FormulaC9H20O5Si
Mol. Weight236.34
Density1.07
Boiling Point120 °C at 2 mmHg
Refractive index1.4270 to 1.4300
Flash Point137°C(lit.)
TSCAYes
Melting Point-50 °C
Appearance 3-(2,3-环氧丙氧)丙基三甲氧基硅烷(2530-83-8)为无色透明液体。3-(2,3-环氧丙氧)丙基三甲氧基硅烷(2530-83-8)易溶于多种有机溶剂中，易水解，缩合形成聚硅氧烷，过热，光照、过氧化物存在下易聚合。沸点120℃。
Stability易吸潮
Solubility溶于水，溶于丙酮、苯和醚。

别名和识别编码

Chemical Name3-Glycidoxypropyltrimethoxysilane
Synonym 3-Glycidoxy propyl trimethoxy silane {LY} 3-Glycidoxy propyl trimethoxy silane {} {LY} 3-Glycidoxy propyl trimethoxy silane {} {} {LY} 3-Glycidoxy propyl trimethoxy silane {} {} {} {LY} 3-Glycidoxy propyl trimethoxy silane {} {} {} {} {LY} 3-Glycidoxy propyl trimethoxy silane {} {} {} {} {} {LY} 3-Glycidoxy propyl trimethoxy silane {} {} {} {} {} {} {LY} 3-Glycidoxy propyl trimethoxy silane {} {} {} {} {} {} {} {LY} 3-Glycidoxy propyl trimethoxy silane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Glycidoxy propyl trimethoxy silane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Glycidoxy propyl trimethoxy silane {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} 3-Glycidoxy propyl trimethoxy silane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Glycidoxy propyl trimethoxy silane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Glycidoxy propyl trimethoxy silane {} {}
MDL NumberMFCD00005144
PubChem Substance ID87570394
Beilstein Registry Number4308125
CAS Number2530-83-8
EC Number219-784-2
Reaxys-RN4308125
Chemical Name Translation3-缩水甘油醚氧基丙基三甲氧基硅烷
Wiswesser Line NotationT3OTJ B1O3-SI-O1&O1&O1
LabNetwork Molecule IDLN00197815
Canonical SMILESCO[Si](OC)(CCCOCC1CO1)OC
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分类

  • Chemical Synthesis, Materials Science, Micro/NanoElectronics, Organometallic Reagents, Organosi
  • {SA} Chemical Synthesis, Materials Science, Micro/NanoElectronics, Organometallic Reagents, Organosilicon, Self Assembly & Contact Printing, Self-Assembly Materials, Silanes,

产品应用

  • Pre-treatment of carbon steel with 3-(Glycidoxypropyl)trimet?hoxysilane enhances the dry and wet adhesion while reducing the cathotic disbondment rate of an epoxy coating

相关文献及参考

  • J. Chem. Soc. Perkin Trans. I , 729, (1997)
  • Beilstein: 17,V,3,45

安全信息

WGK Germany2
RTECSVV4025000
Personal Protective Equipment Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US) Eyeshields, Gloves, half-mask respirator (EU), half-mask respirator (US), multi-purpose combination respirator cartridge (US) Eyeshields, Gloves
Signal word Danger Warning
Hazard statements
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
  • H318 Causes serious eye damage 严重伤害眼睛
  • H313 May be harmful in contact with skin 皮肤接触可能有害
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
UN Number UN1760
Risk Statements
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R21 Harmful in contact with skin 与皮肤接触有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R52 Harmful to aquatic organisms 对水生生物有害
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Storage condition -20°C {LY} -20°C 2-8°C 2-8°C储存 Moisture Sensitive {} {LY} -20°C {} {} {LY} -20°C {} {} {} {LY} -20°C {} {} {} {} {LY} -20°C {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
GHS Symbol
Hazard Codes Xn Xi
Packing GroupIII 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 22600 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   UCDS** Union Carbide Data Sheet.  (Union Carbide Corp., 39 Old Ridgebury
   Rd., Danbury, CT 06817)  Volume(issue)/page/year: 2/11/1964

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 3970 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5300 mg/m3/4H
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - lacrimation
   Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
   TSCAT* Office of Toxic Substances Report.  (U.S. Environmental Protection
   Agency, Office of Toxic Substances, 401 M St., SW, Washington, DC 20460)
   Volume(issue)/page/year: OTS215156

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 ug/plate
REFERENCE :
   TSCAT* Office of Toxic Substances Report.  (U.S. Environmental Protection
   Agency, Office of Toxic Substances, 401 M St., SW, Washington, DC 20460)
   Volume(issue)/page/year: OTS215156

其他信息

  • MSDS 信息:Glymo(2530-83-8).msds
  • 海关编码:29310095
  • Sigma Aldrich:2530-83-8(sigmaaldri
  • 溶于水，溶于丙酮、苯和醚。
  • 图谱信息:3-(2,3-环氧丙氧)丙基三甲氧基硅烷(2530-83-8)核磁图( 13 CNMR) 3-(2,3-环氧丙氧)丙基三甲氧基硅烷(2530-83-8)质谱(MS) 3-(2,3-环氧丙氧)丙基三甲氧基硅烷(2530-83-8)红外图谱(IR1)
  • Acros Organics:3-缩水甘油丙基三甲氧基硅烷/硅烷偶联剂kh560 3-Glycidoxypr
  • 上游原料:甲醇 --> 硅
  • MOL 文件:2530-83-8.mol
  • 用途三:1.主要用于不饱和聚酯复合材料中，可以提高复合材料机械性能、电气性能、透光性能，特别是能大幅度提高复合材料的湿态性能。 2.用(含该偶联剂的)浸润处理玻纤，可提高玻纤增强复合材料湿态的机械强度和电气性能。 3.电线电缆行业，用该偶联剂处理陶土填充过氧化物交联的EPDM体系，改善了消耗因子及比电感容抗。 4.与醋酸乙烯和丙烯酸酸或甲基丙烯酸单体共聚，这些聚合物广泛用于涂料、胶粘剂和密封剂中，提供优异的粘合力和耐久性。
  • 3-(2,3-环氧丙氧)丙基三甲氧基硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 TG021001 3-甘油氧代丙基三甲氧基硅烷 500g 1957元 2011/04/16 G0210 3-缩水甘油基氧丙基三甲氧基硅烷 3-Glycidyloxypropyltrimethoxysilane 25G 175元 2011/04/16 G0210 3-缩水甘油基氧丙基三甲氧基硅烷
  • 用途二:用作表面处理剂及添加剂
  • Pre-treatment of carbon steel with 3-(Glycidoxypropyl)trimethoxysilane enhances the dry and wet adhesion while reducing the cathotic disbondment rate of an epoxy coating.
  • 硅烷偶联剂KH-560:硅烷偶联剂KH-560是最早被广泛应用的偶联剂，到目前为止已有40多年的历史。其结构的一端有能与环氧、酚醛、聚酯等类合成树脂分子反应的活性基团，如氨基、乙烯基等。另一端是与硅相连的烷氧基（如甲氧基、乙氧基等）或氯原子，这些基团在水溶液或空气中水分的存在下，水解生成可与玻璃、矿物质、无机填充剂表面的羟基反应，生成反应性硅醇。因此，硅烷类偶联剂常用于硅酸盐类填充的环氧、酚醛、聚酯树脂等体系。另外,还可用于玻璃钢生产,以提高其机械强度及对潮湿环境的抵抗能力。硅烷偶联剂的有机基团对合成树脂的反应具有选择性，一般，这些有机基团与聚乙烯、聚丙烯、聚苯乙烯等合成树脂缺乏足够的反应性，因而偶联效果差。近年来，已开发了对聚烯烃有较好偶联作用的新品种硅烷偶联剂，但限于成本和其他性能，应用尚不普遍。 硅烷偶联剂又名硅烷处理剂; 底涂剂。通式为Y (CH2)nSiX3在分子中具有两种以上不同反应基的有机硅单体，它可以和有机与无机材料发生化学键合 (偶联)，增加两种材料的粘接性。通式中n为0～3的整数; X为可水解基团，如氯、甲氧基、乙氧基、乙酰氧基等，易水解生成硅醇，可与无机物质反应而结合; Y为有机官能团，如乙烯基、氨基、环氧基、甲基丙烯酰氧基、巯基等，可与有机物质反应而结合。典型硅烷偶联剂性能如下表：用于玻璃纤维、无机填料表面处理。用作密封剂、胶粘剂和涂料增稠剂。还应用于使固定化酶附着到玻璃基材表面、油井钻探防砂、使砖石表面具有憎水性、使荧光灯涂层具有较高的表面电阻、提高液体色谱中有机相对玻璃表面的吸湿性能等。由硅氯仿与带有活性基团
  • F:10-21
  • TCI Shanghai:3-(2,3-环氧丙氧)丙基三甲氧基硅烷 3-Glycidyloxypropyltrimethoxysilane,>;95.0%(GC)(2530-83-8)
  • 用途一:能使两种材料偶联，提高制品机械强度，改善复合材料电性能、耐候和耐蚀性，适用于玻璃钢/粘合剂等

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Trialkoxysilanes - Organosilicon
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Trialkoxysilanes - Organosilicon
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Self Assembly & Contact Printing - Micro/NanoElectronics
  4. Self-Assembly Materials - Self Assembly & Contact Printing
  5. Silanes - Self-Assembly Materials
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Simple 3-Membered Ring Compounds 简单三元环化合物
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Siloxanes 硅氧烷
  1. Materials Science 材料科学
  2. Silane Coupling Agents 硅烷偶联剂