(S)-(-)-2-Azetidinecarboxylic Acid (S)-(-)-2-羧基环丁胺

CAS 2133-34-8 MFCD00005166

化学结构图

2133-34-8
SMILES: O=C(O)[C@@H]1CCN1

化学属性

Mol. FormulaC4H7NO2
Mol. Weight101.10
Melting Point217°C
TSCANo
Solubility5 G/100 ML
Appearance 白色结晶。熔点217℃。
Refractive index-122 ° (C=4, H2O)
Density1.422
Boiling Point189.47 °C at 760 mmHg

别名和识别编码

Chemical Name(S)-(-)-2-Azetidinecarboxylic Acid
CAS Number2133-34-8
Alfabeta NameAZETIDINECARBOXYLICACID S2(())-----
MDL NumberMFCD00005166
Synonym L-Azetidine-2-carboxylic acid {LY} L-Azetidine-2-carboxylic acid {} {LY} L-Azetidine-2-carboxylic acid {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {} {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {} {} {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {} {} {} {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Azetidine-2-carbox
PubChem Substance ID16486
Beilstein Registry Number80678
EC Number218-362-5
Merck Number908
Chemical Name Translation(S)-(-)-2-羧基环丁胺
Reaxys-RN80678
Wiswesser Line NotationT4MTJ BVQ -L
LabNetwork Molecule IDLN00009449
InChIInChI=1S/C4H7NO2/c6-4(7)3-1-2-5-3/h3,5H,1-2H2,(H,6,7)/t3-/m0/s1
Canonical SMILESO=C([C@H]1NCC1)O
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分类

  • {SNA} AN-AZ, Angiogenesis Regulators, Bioactive Small Molecules, Cell Biology, Cell Signaling and Neuroscience, Cytoskeleton and Extracellular Matrix, Extracellular Matrix
  • {SNA} AN-AZ, Angiogenesis Regulators, Bioactive Small Molecules,
  • {SNA} Angiogenesis Regulators, Cytoskeleton and Extracellular Matrix, Extracellular Matrix, 细胞信号转导和神经科学, 细胞生物学
  • {SNA} AN-AZ, Asymmetric Synthesis, Bioactive Small Molecules, Cell Biology, Chemical Biology, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Others, Peptide Chemistry, Proline-Based Organocatalysts, Unnatural Amino

安全信息

Warnings IRRITANT
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
RTECSCM4310500
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Hazard Codes Xi
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr
Signal word Warning
GHS Symbol
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GDA2 "CRC Handbook of Antibiotic Compounds," Vols.1- ,  Berdy, J., Boca
   Raton, FL, CRC Press, 1980-  Volume(issue)/page/year: 8(1),101,1982

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 300 mg/kg
SEX/DURATION            : female 8-10 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   TJADAB Teratology, The International Journal of Abnormal Development. (Alan
   R. Liss, Inc., 41 E. 11th St., New York, NY 10003)  V.1-    1968-
   Volume(issue)/page/year: 14,248,1976

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 300 mg/kg
SEX/DURATION            : female 8 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured
   before birth)
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Effects on Embryo or Fetus - fetal death
REFERENCE :
   SEIJBO Senten Ijo.  Congenital Anomalies.  (Nippon Senten Ijo Gakkai, c/o
   Kinki Daigaku Igakubu Kaibagaku Kyoshitsu, 380 Nishiyama, Sayama-cho,
   Miram

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - hamster
DOSE                    : 300 mg/kg
SEX/DURATION            : female 11 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   TJADAB Teratology, The International Journal of Abnormal Development. (Alan
   R. Liss, Inc., 41 E. 11th St., New York, NY 10003)  V.1-    1968-
   Volume(issue)/page/year: 23,365,1981

TYPE OF TEST            : TDLo - Lowest published toxic do

Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激

其他信息

  • MSDS 信息:L-2-Azetidinecarboxylic acid(2133-34-8).msds
  • 可燃性危险特性:可燃; 燃烧产生有毒氮氧化物烟雾
  • Acros Organics:(S)-(-)-2-Azetidinecarboxylic acid, 99+%(2133-34-8)
  • 比旋光度:-125 ° (c=1, water 25 °C)
  • 类别:有毒物品
  • 毒性分级:中毒
  • Hazard Note:Irritant
  • 储运特性:通风低温干燥
  • (S)-(-)-2-羧基环丁胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A1043 L-氮杂环丁烷-2-羧酸[L-脯氨酸的拮抗物] L-Azetidine-2-carboxylic Acid [Antagonist of L-Proline] 100MG 727元 2014/06/02 A1043 L-氮杂环丁烷-2-羧酸[L-脯氨酸的拮抗物] L-Azetidine-2-carboxylic Acid [Antagonist of L-Proline] 1G 4160元 2010/06/21 105142500 (S)-(-)-2-羧基环丁胺 (S)-(-)-2-Azetidinecarboxylic acid 99+% 250 MG 1762元
  • (S)-(-)-2-羧基环丁胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 A1043 L-氮杂环丁烷-2-羧酸[L-脯氨酸的拮抗物] L-Azetidine-2-carboxylic Acid [Antagonist of L-Proline] 100MG 735元 2011/04/16 A1043 L-氮杂环丁烷-2-羧酸[L-脯氨酸的拮抗物] L-Azetidine-2-carboxylic Acid [Antagonist of L-Proline] 1G 4210元 2010/06/21 105142500 (S)-(-)-2-羧基环丁胺 (S)-(-)-2-Azetidinecarboxylic acid 99+% 250 MG 1762元
  • 灭火剂:干粉,泡沫,沙土,二氧化碳, 雾状水
  • TCI Shanghai:(S)-(-)-2-羧基环丁胺[L-脯氨酸的拮抗物] L-Azetidine-2-carboxylic Acid [Antagonist of L-Proline],>;98.0%(T)(2133-34-8)
  • 急性毒性:皮下-小鼠 LD50: 1000 毫克/公斤
  • 上游原料:盐酸 --> 乙酸乙酯 --> 甲醇 --> 乙醚 --> 四氢呋喃 --> 二氯甲烷 --> 氧氯化硫 --> 石油醚 --> 碳酸钾 --> 碳酸氢钠 --> 钯 --> 氯化铵 --> 乙腈 --> 二甲基亚砜 --> 叔丁醇钾 --> S-1-苯乙胺 --> 2-溴乙醇 --> 溴乙腈
  • Alfa Aesar:(S)-(-)-氮杂环丁烷-2-羧酸,99% (S)-(-)-Azetidine-2-carboxylic acid, 99%(2133-34-8)
  • MOL 文件:2133-34-8.mol
  • Sigma Aldrich:2133-34-8(sigmaaldrich)

系列性分类

  1. Life Science 生命科学
  2. Cell Biology 细胞生物学
  3. Bioactive Small Molecules - Cell Biology
  4. AN-AZ - Bioactive Small Molecules
  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Unnatural Amino Acid Derivatives 人工合成氨基酸
  5. Others - Unnatural Amino Acid Derivatives
  1. Life Science 生命科学
  2. Cell Biology 细胞生物学
  3. Cell Signaling and Neuroscience - Cell Biology
  4. Cytoskeleton and Extracellular Matrix - Cell Signaling and Neuroscience
  5. Extracellular Matrix - Cytoskeleton and Extracellular Matrix
  6. Angiogenesis Regulators - Extracellular Matrix
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Amino Acids 氨基酸
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Amino Acids 氨基酸
  4. Other Amino Acids
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Simple 4-Membered Ring Compounds
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes
  5. Solvias Ligands and Complexes
  6. Walphos Ligands
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Cell Signaling and Neuroscience
  4. Cytoskeleton and Extracellular Matrix
  5. Extracellular Matrix
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Cell Signaling and Neuroscience
  4. Peptides and Proteins
  5. Cytoskeleton and Extracellular Matrix Proteins
  6. Actin Inhibitors and Probes
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Proteins and Derivatives
  4. Proteins for Cell Biology
  5. Cytoskeleton and Extracellular Matrix Proteins
  6. Actin Inhibitors and Probes
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Cell Signaling and Neuroscience
  4. Peptides and Proteins
  5. Proteins for Cell Biology
  6. Apoptosis and Cell Cycle Proteins
  7. Apoptosis Inhibitors
  1. Medical Research Areas
  2. Metabolism
  3. Endogenous Metabolite  (内源性代谢物)

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