1-(p-Toluenesulfonyl)imidazole, 99% 1-对甲基苯磺酰咪唑

CAS 2232-08-8 MFCD00005285

化学结构图

2232-08-8
SMILES: Cc1ccc(S(=O)(=O)n2ccnc2)cc1

化学属性

Mol. FormulaC10H10N2O2S
Mol. Weight222.26
Density1.29
Melting Point76-78°C
TSCANo
Boiling Point409.1°C at 760 mmHg

别名和识别编码

Chemical Name1-(p-Toluenesulfonyl)imidazole, 99%
CAS Number2232-08-8
Alfabeta NameTOLUENESULFONYLIMIDAZOLE P1()--
MDL NumberMFCD00005285
EC Number218-771-9
Beilstein Registry Number23(5)4,446
Synonym 1-Tosylimidazole {LY} 1-Tosylimidazole {} {LY} 1-Tosylimidazole {} {} {LY} 1-Tosylimidazole {} {} {} {LY} 1-Tosylimidazole {} {} {} {} {LY} 1-Tosylimidazole {} {} {} {} {} {LY} 1-Tosylimidazole {} {} {} {} {} {} {LY} 1-Tosylimidazole {} {} {} {} {} {} {} {LY} 1-Tosylimidazole {} {} {} {} {} {} {} {} {LY} 1-Tosylimidazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Tosylimidazole {} {} {} {} {} {} {} {} {} {} {LY} 1-Tosylimidazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Tosylimidazole {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Tosylimidazole {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Tosylimidazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Tosylimidazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Tosylimidazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1
PubChem Substance ID75219
Reaxys-RN612451
Chemical Name Translation1-对甲基苯磺酰咪唑
InChIKeyYJYMYJRAQYREBT-UHFFFAOYSA-N
LabNetwork Molecule IDLN00010026
InChIInChI=1S/C10H10N2O2S/c1-9-2-4-10(5-3-9)15(13,14)12-7-6-11-8-12/h2-8H,1H3
Canonical SMILESCC1=CC=C(S(N2C=CN=C2)(=O)=O)C=C1
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分类

  • {SNA} Building Blocks, C9 to C30+, Chemical Synthesis, Heterocyclic Building Blocks, Imidazoles

产品应用

  • 寡聚核苷酸合成中的偶联试剂

相关文献及参考

  • Beilstein:23(5)4,446

安全信息

Warnings IRRITANT
Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • 存储注意事项:湿度敏感
  • 遇潮易分解。
  • Sigma Aldrich:2232-08-8(sigmaaldrich)
  • F:10-21
  • 用途一:寡聚核苷酸合成中的偶联试剂
  • Acros Organics:1-(对甲苯磺酰)咪唑 1-(p-Toluenesulfonyl)imidazole, 99%(2232-08-8)
  • TCI Shanghai:1-(对甲苯磺酰基)咪唑 1-(p-Toluenesulfonyl)imidazole,>;98.0%(LC)(N)(2232-08-8)
  • 检测方法:HPLC
  • MOL 文件:2232-08-8.mol
  • 1-对甲基苯磺酰咪唑价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1985 1-(对甲苯磺酰基)咪唑 1-(p-Toluenesulfonyl)imidazole 5G 467元 2014/06/02 T1985 1-(对甲苯磺酰基)咪唑 1-(p-Toluenesulfonyl)imidazole 25G 1410元
  • 上游原料:三氯甲烷 --> 4-甲苯磺酰氯 --> 咪唑

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Imidazoles 咪唑
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Condensation & Active Esterification
  1. Life Science 生命科学
  2. Biochemistry / Glyco-Chemistry
  3. DNA / RNA Synthesis

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