Thiazole 噻唑

CAS 288-47-1 MFCD00005315

化学结构图

288-47-1
SMILES: C1CSCN1

化学属性

Mol. FormulaC3H3NS
Mol. Weight85
Density1.198
Boiling Point118°C(lit.)
TSCAT
Refractive index1.5340 to 1.5430
Flash Point26°C(lit.)
Melting Point-33°C
Solubility略溶于水
Stability对空气和光敏感

别名和识别编码

Chemical NameThiazole
MDL NumberMFCD00005315
CAS Number288-47-1
EC Number206-021-3
Beilstein Registry Number27,15
Alfabeta NameTHIAZOLE
Reaxys-RN103852
Merck Number9307
PubChem Substance ID87576178
Synonym MA300208 {uni_hamburg} THIAN-4-ONEOXIME thiazole 1,3-THIAZOLE 硫氮茂798 Thiazole,98% FEMA 3615 THIAZOLE 噻唑 硫氮(杂)茂 硫氮杂茂 FEMA NUMBER 3615 THIAZOLE 99+% 1,3-thiazole
Chemical Name Translation噻唑
Wiswesser Line NotationT5N CSJ
LabNetwork Molecule IDLN00007124
InChIInChI=1S/C3H3NS/c1-2-5-3-4-1/h1-3H
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分类

  • Alphabetical Listings, Certified Food Grade Products, Flavors and Fragrances, Halal Certified Products, Kosher Certified Products, O-Z, Q-Z
  • {SNA} Building Block
  • {SNA} Alphabetical Listings, Certified Food Grade Products, Flavors and Fragrances, Halal Certified Products, Kosher Certified Products,
  • {SNA} Alphabetical Listings, Flavors and Fragrances, Halal Certified Products, Kosher Certified Products, O-Z, Q-Z
  • {uni_hamburg} no charge; sulfur heterocycle; nitrogen heterocycle; aromatic; 5ring; 1fragment
  • {SNA} Alphabetical Listings, Flavors and Fragrances, Halal Certified Products, Kosher Certified Products, O - Z, O-Z, Q-Z

产品应用

  • 芝麻油和鸡肉中天然存在的化合物。

相关文献及参考

  • For an example of 2-lithiation, see: J. Med. Chem., 37, 3492 (1994). For other uses of 2-lithiothiazole, see 2-Bromothiazole, A14838.
  • Short: II/14a
  • Short: II/2
  • Short: II/24B

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
Risk Statements
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R10 Flammable 易燃
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P211 Do not spray on an open flame or other ignition source.? 不要喷洒在明火或其他点火源。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P312+P330
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Warnings FLAMMABLE
RTECSXJ1290000
UN Number 1993
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupIII
Storage condition Flammables area Air & Light Sensitive
Hazard Class3
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 983 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   DCTODJ Drug and Chemical Toxicology.  (Marcel Dekker, 270 Madison Ave., New
   York, NY 10016) V.1-    1977/78-  Volume(issue)/page/year: 3,249,1980

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 4 umol/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 321,213,1994

其他信息

  • 海关编码:29341000
  • FEMA:3615
  • 下游产品:头孢噻肟钠 --> 2,6-二氯苯并噻唑 --> 噻苯咪唑 --> 阳离子蓝X-GRRL --> 氨曲南 --> 头孢唑肟 --> 6-巯基嘌呤(一水合物)
  • Alfa Aesar:噻唑,99% Thiazole, 99%(288-47-1)
  • Sigma Aldrich:288-47-1(sigmaaldrich)
  • MSDS 信息:噻唑(288-47-1).msds
  • 检测方法:GC,NMR
  • 外观性质:无色或淡黄色、有特殊臭味、液体。
  • 用途一:用作有机合成试剂,用于合成药物、染料、橡胶促进剂、胶片成色剂等
  • 敏感性:Air & Light Sensitive
  • 噻唑价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0185 噻唑 Thiazole 25G 2710元 2014/06/02 T0185 噻唑 Thiazole 5G 865元 2010/06/21 166130050 噻唑 Thiazole 99% 5 GR 1662元
  • MOL 文件:288-47-1.mol
  • 食品添加剂最大允许使用量最大允许残留量标准:添加剂中文名称 允许使用该种添加剂的食品中文名称 添加剂功能 最大允许使用量(g/kg) 最大允许残留量(g/kg) 噻唑 食品 食品用香料 用于配制香精的各香料成分不得超过在GB 2760中的最大允许使用量和最大允许残留量
  • 图谱信息:噻唑(288-47-1)核磁图( 1 HNMR) 噻唑(288-47-1)质谱(MS) 噻唑(288-47-1)红外图谱(IR1)
  • F:8-10-23
  • TCI Shanghai:噻唑 Thiazole,>;98.0%(GC)(288-47-1)
  • TSCA:T
  • Acros Organics:噻唑 Thiazole, 99%(288-47-1)

系列性分类


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