Ethylene Carbonate 碳酸乙烯酯

CAS 96-49-1 MFCD00005382

化学结构图

96-49-1
SMILES: O=C1OCCO1

化学属性

Mol. FormulaC3H4O3
Mol. Weight88.06
Boiling Point248.2°C at 760 mmHg
Density1.321
Melting Point35-38°C
Flash Point143°C
SolubilityMiscible (40%) with water, alchohol ethyl acetate, benzene and chloroform. Soluble in ether, n-Butanol, and carbon tetrachloride.
TSCAYes
Vapor Density3.04 (vs air)
Vapor Pressure0.02 mmHg ( 36.4 °C)
Stability易吸潮
Appearance 无色针状结晶。熔点38.5-39℃，沸点152℃（4.0kPa），100℃（1.07kPa），相对密度1.4259（20/4℃）。闪点152℃。易溶于水及有机溶剂。

别名和识别编码

Chemical NameEthylene Carbonate
Synonym Ethylene carbonate {LY} Ethylene carbonate {} {LY} Ethylene carbonate {} {} {LY} Ethylene carbonate {} {} {} {LY} Ethylene carbonate {} {} {} {} {LY} Ethylene carbonate {} {} {} {} {} {LY} Ethylene carbonate {} {} {} {} {} {} {LY} Ethylene carbonate {} {} {} {} {} {} {} {LY} Ethylene carbonate {} {} {} {} {} {} {} {} {LY} Ethylene carbonate {} {} {} {} {} {} {} {} {} {LY} Ethylene carbonate {} {} {} {} {} {} {} {} {} {} {LY} Ethylene carbonate {} {} {} {} {} {} {} {} {} {} {} {LY} Ethylene carbonate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethylene carbonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethylene carbonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethylene carbonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethylene carbonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number96-49-1
PubChem Substance ID7303
EC Number202-510-0
Beilstein Registry Number106249
MDL NumberMFCD00005382
Reaxys-RN106249
Chemical Name Translation碳酸乙烯酯
LabNetwork Molecule IDLN00196710
InChIInChI=1S/C3H4O3/c4-3-5-1-2-6-3/h1-2H2
Canonical SMILESO=C1OCCO1
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分类

  • {uni_hamburg} no charge; oxygen heterocycle; alicycle; 5ring; carbonate; 1fragment
  • {SNA} Aluminum Bottles, Building Blocks, Carbonates, Carbonyl Compounds, Chemical Synthesis, Heterocyclic Building Blocks, O-Containing, Organic Building Blocks, Others,
  • {SNA} Alternative Energy, Building Blocks, Carbonates,

相关文献及参考

  • Ethylene oxide equivalent for introduction of the 2-hydroxyethyl group, by reaction with various nucleophiles. Reacts with thiols (K2CO3/ 18-crown-6) to give 2-hydroxyethyl sulfides: Synthesis, 382 (1986).
  • Beilstein:19,100
  • Short: II/19b
  • Short: II/14a

安全信息

GHS Symbol
WGK Germany1
Hazard Codes Xn Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H302 Harmful if swallowed 吞食有害
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
RTECSFF9550000
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P305+P351+P338
  • P305+P351+P338+P337+P313
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37 Wear suitable gloves 戴适当手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • 碳酸乙烯酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 AE2625802 碳酸乙烯酯 500g 322元 2011/08/23 K0351902 碳酸乙烯酯 250g 262元 2011/04/16 E0076 碳酸乙烯酯 Ethylene Carbonate 25G 134元
  • 下游产品:碳酸二甲酯
  • 用途三:目前主要用于三方面。（1）用作水玻璃系浆料 以1,3-二氧杂环戊酮、碳酸氢钾分别作为固化剂和速结剂制备无公害的水玻璃系浆料，由于丙烯酰胺，尿素体系的浆料被禁用，水玻璃系浆料受到普遍的重视。（2）用于合成呋喃唑酮（C8H7N3O5，[67-45-8]；这是一种广谱抗菌药，用于预防鸡的球虫病。（3）用作纤维整理剂和其他加工助剂。
  • 蒸气压:0.02 mm Hg ( 36.4 °C)
  • 环氧乙烷水溶液和CO2合成碳酸乙烯酯:采用自行开发的NY-2催化剂，研究了环氧乙烷(EO)水溶液和CO2制备碳酸乙烯酯(EC)的反应性能。设计了正交实验以确定影响EO转化率和EC选择性的主要因素；探讨了溶剂EC用量、反应温度、反应压力、催化剂用量等因素对合成反应的影响。实验结果表明，n(H2O)∶n(EO)是影响EO转化率的最主要因素；温度和n(H2O)∶n(EO)是影响EC选择性的最主要因素；确定了采用NY-2催化剂、以EC为溶剂时， 合成反应的最佳工艺条件：反应温度100～120 ℃，反应压力3.0～4.0 MPa，催化剂质量分数2%，n(H2O)∶n(EO)=1∶2，n(EC)∶n(EO)=5。在此条件下，EO的转化率达到97.62%以上，EC的选择性达到92.55%左右。 作者：沈 玺，刘定华，刘晓勤 ------南京工业大学 材料化学工程国家重点实验室，江苏 南京 210009
  • 用途二:用于化肥、纤维、制药及有机合成等
  • 用途一:中间体。
  • 蒸气密度:3.04 (vs air)
  • MOL 文件:96-49-1.mol
  • 具有较强吸湿性。粘度(40℃)1.9mPa.S，介电常数96c/v.m。
  • 图谱信息:碳酸乙烯酯(96-49-1)质谱(MS) 碳酸乙烯酯(96-49-1)核磁图( 1 HNMR) 碳酸乙烯酯(96-49-1)红外图谱(IR3) 碳酸乙烯酯(96-49-1)核磁图( 13 CNMR) 碳酸乙烯酯(96-49-1)红外图谱(IR2) 碳酸乙烯酯(96-49-1)Raman光谱 碳酸乙烯酯(96-49-1)红外图谱(IR1)
  • MSDS 信息:1,3-Dioxolan-2-one(96-49-1).msds
  • Acros Organics:碳酸乙烯酯 Ethylene carbonate, 99+%(96-49-1)
  • TCI Shanghai:碳酸乙烯酯 Ethylene Carbonate,>;99.0%(GC)(96-49-1)
  • 海关编码:29209010
  • 方法一:由环氧乙烷与二氧化碳反应而得。
  • Alfa Aesar:碳酸亚乙酯,99% Ethylene carbonate, 99%(96-49-1)
  • Sigma Aldrich:96-49-1(sigmaaldrich)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  5. O-Containing - Others
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carbonates - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Amides
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Dioxanes & Dioxolanes