Tetramethylene Sulfoxide 四亚甲基亚砜

CAS 1600-44-8 MFCD00005477

化学结构图

1600-44-8
SMILES: O=S1CCCC1

化学属性

Mol. FormulaC4H8OS
Mol. Weight104
Density1.158 g/mL at 25 °C(lit.)
Boiling Point107°C/12mmHg(lit.)
Refractive indexn20/D 1.52(lit.)
Flash Point112°(233°F)
TSCAYes

别名和识别编码

Chemical NameTetramethylene Sulfoxide
Synonym TETRAMETHYLENE SULPHOXIDE Thiophene, tetrahydro, 1-oxide Tetrahydrothiophensulfoxid Tetramethylene sulfoxide, 98+% tetrahydro-thiophen1-oxide 丁撑亚砜 四甲基亚砜(环丁亚砜) Tetramethylene sulfoxide TETRAHYDROTHIOPHENE 1-OXIDE 四次甲基亚砜 tetrahydrothiophene S-oxide Tetrahydro-thiophene 1-oxide Thiophene-1-oxide, tetrahydro- thiolane-1-oxide 四甲撑亚砜 TETRAMETHYLENE SULFOXIDE Thiophane monoxide thiophanemonoxide thiophane1-oxide Tetramethylensulfoxid 四亚甲基亚砜 TETRAHYDROTHIOPHENE-S-OXIDE Tetrahydrothiophen-1-oxid 四甲(基)撑亚砜 Thiolane 1-oxide TETRAHYDROTHIOPHENE OXIDE Tetrahydrothiophene oxide Thiophene, tetrahydro-, 1-oxide Tetrahydrothiophene sulfoxide Tetrametylene sulfoxide Tetrahydrothiophene 1-oxide 四甲基亚砜 Thiophane 1-oxide tetrahydro-thiophene-1-oxide Thiophane oxide Tetramethylene sulphoxide Thiolane sulfoxide Thiophene sulfoxide
MDL NumberMFCD00005477
CAS Number1600-44-8
PubChem Substance ID87576148
Beilstein Registry Number105274
EC Number216-493-2
Chemical Name Translation四亚甲基亚砜
Reaxys-RN105274
InChIKeyISXOBTBCNRIIQO-UHFFFAOYSA-N
Wiswesser Line NotationT5STJ AO
LabNetwork Molecule IDLN00194019
InChIInChI=1S/C4H8OS/c5-6-3-1-2-4-6/h1-4H2
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分类

  • {SNA} Building Blocks, C4 to C6, Chemical Synthesis, Heterocyclic Building Blocks, Thiophenes
  • {uni_hamburg} no charge; sulfur heterocycle; alicycle; 5ring; sulfoxide; 1fragment

相关文献及参考

  • Short: II/25C Title: Structure Data Of Free Polyatomic Molecules: Molecules containing Three or Four Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25C Year: 2001 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-66774-1 ISBN: 978-3-540-66774-2 Internet Resource: DOI:10.1007/b71431 RefComment: VIII, 481 pages. Hardcover Abstract: This volume contains data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc.) of free polyatomic molecules including free radicals and molecular ions. This survey on structure data is made of four subvolume, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this third subvolume, the structure of molecules containing three for four carbon atoms are listed.
  • Short: III/35E Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Oxygen-17 Author: Duddeck, H.; Toth, G.; Simon, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35E Year: 2002 Keyword: Alipathic and Aromatic hydrocarbons; Coupling constant j; Nuclear Magnetic Resonance; chemical shifts δ ISBN: 3-540-42501-2 ISBN: 978-3-540-42501-4 Internet Resource: DOI:10.1007/b92953 RefComment: VII, 230 pages. With CD-ROM., Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling consta

安全信息

WGK Germany3
RTECSXN0830000
Personal Protective Equipment Eyeshields, Gloves
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   IJRBA3 International Journal of Radiation Biology and Related Studies in
   Physics, Chemistry and Medicine.  (Taylor & Francis Inc., 242 Cherry St.,
   Philadelphia, PA 19106)  V.1-    1959-  Volume(issue)/page/year: 3,41,1961

其他信息

  • 急性毒性:口服-大鼠 LD50: 1000 毫克/ 公斤; 腹腔-小鼠 LD50: 3500 毫克/ 公斤
  • 毒性分级:中毒
  • 图谱信息:四甲基亚砜(1600-44-8)核磁图( 1 HNMR) 四甲基亚砜(1600-44-8)质谱(MS) 四甲基亚砜(1600-44-8)红外图谱(IR1) 四甲基亚砜(1600-44-8)核磁图( 13 CNMR)
  • TSCA:T
  • 可燃性危险特性:明火可燃; 遇热分解有毒二氧化硫气体
  • TCI Shanghai:四氢噻吩S-氧化物 Tetramethylene Sulfoxide,>;95.0%(GC)(1600-44-8)
  • MOL 文件:1600-44-8.mol
  • Acros Organics:四甲基亚砜(环丁亚砜) Tetramethylene sulfoxide, 98+%(1600-44-8)
  • 下游产品:四氢噻吩亚磺酰亚胺
  • Sigma Aldrich:1600-44-8(sigmaaldrich)
  • 四甲基亚砜价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0146 四亚甲基亚砜 Tetramethylene Sulfoxide 25G 693元 2014/06/02 T0146 四亚甲基亚砜 Tetramethylene Sulfoxide 500G 5640元 2010/06/21 138440050 四甲基亚砜 Tetramethylene sulfoxide 98+% 5 GR 306元
  • 储运特性:库房通风低温干燥; 与食品、氧化剂分开储运
  • 灭火剂:干粉、二氧化碳、砂土
  • Alfa Aesar:四亚甲基亚砜,97% Tetrahydrothiophene 1-oxide, 97%(1600-44-8)
  • 类别:有毒物品

系列性分类


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