2-Mercaptobenzothiazole 2-巯基苯并噻唑

CAS 149-30-4 MFCD00005781

化学结构图

149-30-4
SMILES: S=c1[nH]c2ccccc2s1

化学属性

Mol. FormulaC7H5NS2
Mol. Weight167.25
Density1.42
Melting Point177-181°C
Flash Point200°C
Solubility难溶于水、汽油,微溶于热水,溶于醇、氯仿、丙酮、四氯化碳等。
TSCAYes
Stability对空气敏感;对光敏感
Boiling Point>260°C at 760 mmHg

别名和识别编码

Chemical Name2-Mercaptobenzothiazole
Synonym 2-Mercaptobenzothiazole {LY} 2-Mercaptobenzothiazole {} {LY} 2-Mercaptobenzothiazole {} {} {LY} 2-Mercaptobenzothiazole {} {} {} {LY} 2-Mercaptobenzothiazole {} {} {} {} {LY} 2-Mercaptobenzothiazole {} {} {} {} {} {LY} 2-Mercaptobenzothiazole {} {} {} {} {} {} {LY} 2-Mercaptobenzothiazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Mercaptobenzothiazole {} {} {} {} {} {} {} {} {LY} 2-Mercaptobenzothiazole {} {} {} {} {} {} {} {} {} {LY} 2-Mercaptobenzothiazole {} {} {} {} {} {} {} {} {} {} {LY} 2-Mercaptobenzothiazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Mercaptobenzothiazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Mercaptobenzothiazole {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Mercaptobenzothiazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Mercaptobenzothiazole {} {} {} {} {} {} {} {} {} {}
CAS Number149-30-4
EC Number205-736-8
Beilstein Registry Number119484
MDL NumberMFCD00005781
PubChem Substance ID697993
Merck Number5868
Chemical Name Translation2-巯基苯并噻唑
Reaxys-RN508810
Wiswesser Line NotationT56 BN DSJ CSH
LabNetwork Molecule IDLN00193945
InChIInChI=1S/C7H5NS2/c9-7-8-5-3-1-2-4-6(5)10-7/h1-4H,(H,8,9)
Canonical SMILESS=C1SC2=CC=CC=C2N1
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分类

  • {SNA} Analytical Reagents, Analytical/Chromatography, Mass Spectrometry, Mass Spectrometry (MS), Matrices for MALDI Analysis, Matrix Substances for MALDI-MS, Spectroscopy, 分子生物学,
  • {SNA} Indicators, Metal Titration Indicators, Titration, 分析/色谱, 分析试剂
  • {SNA} Mass Spectrometry (MS), Matrix Substances for MALDI-MS, Spectroscopy, 分子生物学, 分析/色谱,
  • {SA} Building Blocks, C3 to C7, Chemical Synthesis, Heterocyclic Building Blocks, Thiazoles
  • {SNA} Analytical Reagents, Analytical/Chromatography, Indicators, Metal Titration Indicators, Titration

产品应用

  • 检验铋、钴、铜、金、铅、汞、镍、铊和锌。测定银、镉、铱、铅、铂和铑。光度分析测定硒和碲。容量分析测定银。橡胶硫化促进剂。

相关文献及参考

  • Merck:14,5868 Beilstein: 27,IV,2709
  • Short: II/27B
  • Reagent for determination of Ag, Au, Bu, Cd, Hg, Ir, Pt, Tl.
  • Short: III/10a
  • Short: III/20a

安全信息

Signal word Warning
GHS Symbol
WGK Germany2
Safety Statements
  • S24 Avoid contact with skin 避免皮肤接触;
  • S37 Wear suitable gloves 戴适当手套;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R50/53
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P333+P313+P362+P364
  • P305+P351+P338
  • P308+P313
  • P333+P313
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
RTECSDL6475000
Packing GroupIII
UN Number 3077 UN 3077 9/PG 3 UN3077
Storage condition 2-8°C {LY} 2-8°C Air Sensitive {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Hazard Codes 9
Hazard Class9
TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 195 gm/kg/2Y-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Liver - tumors
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-332,1988

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 195 gm/kg/2Y-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Blood - leukemia
   Gastrointestinal - tumors
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-332,1988

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 35 gm/kg/78W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Liver - tumors
   Blood - tumors
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB223-159

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 215 mg/kg
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Blood - tumors
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB223-159

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1158 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   SRTCAC Science Reports of the Research Institutes, Tohoku University, Series
   C: Medicine. (Tohoku University, Research Institute for Tuberculosis and
   Cancer, 4-1 Seiryo-machi, Sendai, Japan)  V.1-   1949-
   Volume(issue)/page/year: 36(1-4),10,1989

TYPE OF TEST            : LD50 - Lethal do

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >1270 mg/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EPASR* United States Environmental Protection Agency, Office of Pesticides
   and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW,

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >7940 mg/kg
TOXIC EFFECTS :
   Behavioral - food intake (animal)
   Behavioral - changes in motor activity (specific assay)
REFERENCE :
   ATDAEI Acute Toxicity Data. Journal of the American C

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 351 mg/L
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-332,1988

{hazard_com

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 4176 mg/kg
SEX/DURATION            : female 6-14 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Specific Developmental Abnormalities - eye/ear
   Reproductive - Specific Developmental Abnormalities - gastrointestinal
   system
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB223-160

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Parenteral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 800 mg/kg
SEX/DURATION            : male 2 day(s) pre-mating
                          female 2 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Effects on Embryo or Fetus - fetal death
REFE

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Parenteral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 400 mg/kg
SEX/DURATION            : female 4-11 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproduc

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Parenteral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 800 mg/kg
SEX/DURATION            : male 2 day(s) pre-mating

其他信息

  • 用途四:本品是铜或铜合金的有效缓蚀剂之一,凡冷却系统中含有铜
  • 急性毒性:口服-大鼠 LD50: 100 毫克/公斤; 腹腔-小鼠 LD50: 100 毫克/公斤
  • 微臭,有苦的不愉快气味。25℃时溶解度(g/100ml):乙醇中为2.0,乙醚中为1.0,丙酮中为10.0,苯中为1.0 ,四氯化碳中小于0.2,粗汽油中小于0.5。溶于碱和碳酸碱溶液,适量溶于冰乙酸,几乎不溶于水。无毒。
  • 方法三:见水处理剂 03301。
  • 用途六:该品作为通用型硫化促进剂,广泛用于各种橡胶。对于天然橡胶和通常以硫磺硫化的合成胶具有快速促进作用。但使用进需要氧化锌、脂肪酸等活化。常与其他促进剂体系并用,如与二硫代秋兰姆和二硫代氨基甲酸碲并用可作丁基胶的促进剂;与三盐基顺丁稀二酸铅并用,可用于浅色耐水的氯磺化聚乙烯胶料。在胶乳中常与二硫代氨基甲酸盐并用,而与二乙基二硫代氨基甲酸二乙胺并用时,可室温硫化。该品在橡胶中易分散、不污染。但由于其有苦味,故不宜用于食品接触的橡胶制品。促进剂M是促进剂MZ,DM,NS,DIBS,CA,DZ,NOBS,MDB等的中间体,2-巯基苯并噻唑与1-氨基-4-硝基蒽醌和碳酸钾在二甲基甲酰胺中回流3h,可制得染料分散艳
  • 方法二:其制备方法是以邻氯硝基苯、多硫化钠、二硫化碳为原料,在110~130℃温度、343kPa压力下反应生成2-巯基苯并噻唑钠盐,再用硫酸进行酸化、水洗得产品。 也可以用苯胺、二硫化碳与硫磺在200℃左右反应,然后在7.85 MPa压力及250~260℃保温2.5 h,即得2-巯基苯并噻唑,用氢氧化钠溶解成钠盐,再进行酸化至p
  • Acros Organics:2-巯基苯并噻唑 2-Mercaptobenzothiazole, 98%(149-30-4)
  • Alfa Aesar:2-
  • 用途五:主要用作光亮硫酸铜的光亮剂。具有良好的整平作用。一般用量0.05~0.10 g/L。还
  • 用途四:本品是铜或铜合金的有效缓蚀剂之一,凡冷却系统中含有铜设备和原水中含在一定量的铜
  • 灭火剂:干粉,泡沫,沙土,二氧化碳, 雾状水
  • 上游原料:氢氧化钠 --> 硫酸 --> 氯 --> 硫磺 --> 氨基苯 --> 二硫化碳 --> 硫磺 --> 邻氯硝基苯 --> 硫氢化钠 --> 多硫化钠 --> 2-氨基苯硫醇 --> 四氢噻唑 --> 脂肪胺 --> N,N'-二苯基硫脲 --> 巯基苯并噻唑钠
  • 可燃性危险特性:接触酸分解硫氧化物和氮氧化物气体; 燃烧产生有毒氮氧化物和硫氧化物烟雾
  • 下游产品:缓蚀剂 --> 二硫化二苯并噻唑 --> 苯并噻唑 --> PBT
  • 2-巯基苯并噻唑价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0055 2-巯基苯并噻唑 2-Mercaptobenzothiazole 25G 136元
  • 微臭,有苦的不愉快气味。25℃时溶解度(g/100ml):乙醇中为2.0,乙醚中为1.0,丙酮中为10.0,苯中为1.0 ,四氯化碳中小于0.2,粗汽油中小于0.5。溶于碱和碳酸碱溶液,适量溶于冰乙酸,几乎
  • MSDS 信息:2-巯基苯并噻唑(149-30-4).msds
  • 所属类别一:农药中间体: 除草剂中间体: 酰胺类除草剂
  • 用途二:用作检定金、铋、镉、钴、汞、镍、铅、铊和锌的灵敏试剂及橡胶促进剂
  • 图谱信息:2-巯基苯并噻唑(149-30-4)红外图谱(IR2) 2-巯基苯并噻唑(149-3
  • 方法一:将苯胺,二硫化碳,硫黄依次加入缩合釜中。其投料比为(mol)︰1︰0.96︰0.36。在8.1MPa下加热至260℃左右。2h后缩合反应结束。得2-巯基苯并噻唑粗品。冷却降温,将其转移到中和釜 。加7~8°Bé的碱液中和,过滤,弃除杂质,滤液转入酸化釜内,加10°Bé的硫酸酸化至pH值为6~7。过滤,滤饼用水洗两次,干燥,粉碎,过筛包装得成品。
  • 方法二:其制备方法是以邻氯硝基苯、多硫化钠、二硫化碳为原料,在110~130℃温度、343

系列性分类