1,2-Phenylene Phosphorochloridite 1，2-亚苯基-次氯酸化膦

CAS 1641-40-3 MFCD00005853

化学结构图

1641-40-3
SMILES: ClP1Oc2ccccc2O1

化学属性

Mol. FormulaC6H4ClO2P
Mol. Weight174.52
Density1.466 g/mL at 25 °C(lit.)
Refractive indexn20/D 1.571(lit.)
Flash Point>110°(230°F)
TSCAYes
Boiling Point80 °C/20 mmHg(lit.)
Melting Point30-35 °C(lit.)

别名和识别编码

Chemical Name1,2-Phenylene Phosphorochloridite
CAS Number1641-40-3
Synonym 1,3,2-Benzodioxaphosphole, 2-chloro- 2-chloro-benzo(1,3,2)dioxaphosphole 2-CHLORO-1,3,2-BENZODIOXAPHOSPHOLE 2-Chlor-1,3,2-benzodioxaphosphol Catechyl phosphorus chloride o-phenylene phosphrochloridite Pyrocatechol phosphoryl chloride 1,2-亚苯基-次氯酸化膦 Phosphorochloridous acid orthophenylene ester Phosphorochloridous acid, cyclic o-phenylene ester Phosphorigsäure-1,2-phenylenesterchlorid 1,2-Phenylene phosphorochloridite ((C6H4O2)ClP) 2-benzodioxaphosphole,2-chloro-3 Phosphorochloridous acid cyclic O-phenylene ester o-Phenylene chlorophosphite o-Phenylene phosphorochloridite 2-Chloro-1,3,2-benzodioxaphosphole o-Phenylene chlorophosphite Chloridophosphorous acid 1,2-phenylene ester 1,2-Phenylene phosphorochloridite, 98+% benzo chlorodioxaphospholane o-Phenylen-phosphorchloridit 1,3,2-Benzodioxaphosphole,2-chloro- 邻苯撑磷酰氯 2-Chloro-4,5-benzo-1,3,2-dioxaphospholane Chloro(1,2-phenylenedioxy)phosphine Phosphorochloridous Acid Orthophenylene Ester Cyclic o-phenylene phosphorochloridite O-PHENYLENE PHOSPHOROCHLORIDITE Catechyl phosphorus chloride~2-Chloro-1,3,2-benzodioxaphosphole o-Phenylene phosphorochloridite ((C6H4O2)ClP) o-Phenylene Phosphorochloridite 1,2-PHENYLENE PHOSPHOROCHLORIDITE 1,2- CATECHYL PHOSPHORUS CH Pyrocatechol, cyclic phosphorochloridite a-丙烯酸氯甲酯 2-Chloro-1,3,2-benzodioxaphospholane
MDL NumberMFCD00005853
EC Number216-690-3
Beilstein Registry Number135455
PubChem Substance ID74232
Chemical Name Translation1，2-亚苯基-次氯酸化膦
InChIKeyYUJYEGDMJZHLMY-UHFFFAOYSA-N
LabNetwork Molecule IDLN01295051
InChIInChI=1S/C6H4ClO2P/c7-10-8-5-3-1-2-4-6(5)9-10/h1-4H
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分类

  • {uni_hamburg} no charge; oxygen heterocycle; other heterocycle; carbocycle; aromatic; alicycle; large ring; fused rings; 5ring; 6ring; 9ring; 1fragment
  • Heterocycles
  • Phosphorylating and Phosphitylating Agents
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphorus Precursors
  • Aromatics

产品应用

  • Highly reactive cyclic phosphitylating reagent which provides fast coupling rates, and hydrolytic cleavage occurs more readily than with acyclic analogs.

相关文献及参考

  • Bannwarth,W. & Kung, E.: Tetrahedron Lett., 30, 4219 (1989)
  • Short: II/25D
  • Short: III/20b

安全信息

Packing GroupII
UN Number UN 3261 8/PG 2 UN3261
Risk Statements
  • R34 Causes burns 会导致灼伤
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
Storage condition Moisture Sensitive 0-6°C
GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Hazard Codes C
Hazard Class8

其他信息

  • a-丙烯酸氯甲酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 B22712 1，2-亚苯基-次氯酸化膦, 97% 1,2-Phenylene phosphorochloridite, 97% 5g 305元 2010/05/25 B22712 1，2-亚苯基-次氯酸化膦, 97% 1,2-Phenylene phosphorochloridite, 97% 25g 720元 2010/05/25 B22712 1，2-亚苯基-次氯酸化膦, 97% 1,2-Phenylene phosphorochloridite, 97% 100g 2170元
  • Sigma Aldrich:1641-40-3(sigmaaldrich)
  • 图谱信息:a-丙烯酸氯甲酯(1641-40-3)核磁图( 13 CNMR) a-丙烯酸氯甲酯(1641-40-3)红外图谱(IR3) a-丙烯酸氯甲酯(1641-40-3)红外图谱(IR1) a-丙烯酸氯甲酯(1641-40-3)红外图谱(IR2) a-丙烯酸氯甲酯(1641-40-3)质谱(MS) a-丙烯酸氯甲酯(1641-40-3)核磁图( 1 HNMR)
  • Acros Organics:邻苯撑磷酰氯 o-Phenylene phosphorochloridite, 97%(1641-40-3)
  • MOL 文件:1641-40-3.mol
  • F:10-21
  • Alfa Aesar:1，2-亚苯基-次氯酸化膦,97% 1,2-Phenylene phosphorochloridite, 97%(1641-40-3)
  • 敏感性:Moisture Sensitive

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphorus Precursors - Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphorus Precursors - Phosphorus Compounds

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