2-Chlorobenzo[d][1,3,2]dioxaphosphole 2-oxide 邻亚苯基氯膦酸

CAS 1499-17-8 MFCD00005854

化学结构图

1499-17-8
SMILES: O=P1(Cl)Oc2ccccc2O1

化学属性

Mol. FormulaC6H4ClO3P
Mol. Weight190.52
Boiling Point120 °C/9 mmHg(lit.)
Melting Point56-62 °C

别名和识别编码

Chemical Name2-Chlorobenzo[d][1,3,2]dioxaphosphole 2-oxide
Synonym 2-chloro-2-oxo-4,5-benzo-1,3,2-dioxaphospholane {uni_hamburg} Phosphorochloridic acid, cyclic o-phenylene ester Catechol cyclophosphorochloridate 2-chloro-benzo(1,3,2)dioxaphosphole-2-oxide 2-Chloro-1,3-dioxa-2-phosphaindan 2-oxide 2-氯-1,3,2-二氧环磷烯2-氧化物 pyrocatechol cyclochlorophosphate o-Phenylene chlorophosphate 邻亚苯基氯膦酸 氯磷酸-1,2-亚苯基二酯 Phosphorochloridic acid cyclic O-phenylene ester 2-氯-1,3,2-二氧环磷烯2-氧化物 Catechol cyclophosphorochloridate 氯磷酸-1,2-亚苯基二酯 1,2-Phenylen-chlorphosphat O,O-(o-Phenylene) chlorophosphate 1,3,2-Benzodioxaphosphole, 2-chloro-, 2-oxide Pyrocatechol, cyclic phosphorochloridate 1,2-Phe 2-Chloro-2-oxobenzo-1,3,2-dioxaphosphole
MDL NumberMFCD00005854
CAS Number1499-17-8
EC Number216-106-7
Beilstein Registry Number142368
PubChem Substance ID73909
Chemical Name Translation邻亚苯基氯膦酸
InChIKeyKMWSGKPLIWNTEF-UHFFFAOYSA-N
LabNetwork Molecule IDLN00197901
InChIInChI=1S/C6H4ClO3P/c7-11(8)9-5-3-1-2-4-6(5)10-11/h1-4H
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分类

  • {uni_hamburg} no charge; oxygen heterocycle; other heterocycle; carbocycle; aromatic; large ring; fused rings; 5ring; 6ring; 9ring; 1fragment
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphorus Precursors

相关文献及参考

  • Short: II/25D Title: Structure Data of Free Polyatomic Molecules: Molecules Containing Five or More Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25D Year: 2003 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-42860-7 ISBN: 978-3-540-42860-2 Internet Resource: DOI:10.1007/b75952 RefComment: VIII, 569 pages. Hardcover RefComment: Written for scientists and researchers in the fields of chemistry and physics Abstract: This fourth subvolume presents data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc) of free polyatomic molecules including free radicals and molecular ions. The survey on structure data consists of four subvolumes, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this fourth subvolume, the structure of molecules containing five to sixty carbon atoms is listed.
  • Short: III/20b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20b Year: 1988 Keyword: NQR ISBN: 3-540-18483-X ISBN: 978-3-540-18483-6 Internet Resource: DOI:10.1007/b86664 RefComment: IX,717 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for diffe

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Precautionary statements
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Signal word Danger
Hazard Codes C
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R14 Reacts violently with water 遇水会猛烈反应
  • R34 Causes burns 会导致灼伤

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphorus Precursors - Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphorus Precursors - Phosphorus Compounds

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