4-Nitrophthalic anhydride 4-硝基邻苯二甲酸酐

CAS 5466-84-2 MFCD00005922

化学结构图

5466-84-2
SMILES: O=C1OC(=O)c2cc([N+](=O)[O-])ccc21

化学属性

Mol. FormulaC8H3NO5
Mol. Weight193.11
Melting Point116-120 °C
TSCAYes
Solubility水解
Boiling Point197 °C at 8 mmHg
Appearance 无色或灰黄色针状结晶。熔点119℃。溶于热醇、热乙酸和丙酮，不溶于水。

别名和识别编码

Chemical Name4-Nitrophthalic Anhydride
MDL NumberMFCD00005922
EC Number226-776-2
CAS Number5466-84-2
Beilstein Registry Number17,486
PubChem Substance ID230976
Synonym 5-Nitroisobenzofuran-1,3-dione {LY} 5-Nitroisobenzofuran-1,3-dione {} {LY} 5-Nitroisobenzofuran-1,3-dione {} {} {LY} 5-Nitroisobenzofuran-1,3-dione {} {} {} {LY} 5-Nitroisobenzofuran-1,3-dione {} {} {} {} {LY} 5-Nitroisobenzofuran-1,3-dione {} {} {} {} {} {LY} 5-Nitroisobenzofuran-1,3-dione {} {} {} {} {} {} {LY} 5-Nitroisobenzofuran-1,3-dione {} {} {} {} {} {} {} {LY} 5-Nitroisobenzofuran-1,3-dione {} {} {} {} {} {} {} {} {LY} 5-Nitroisobenzofuran-1,3-dione {} {} {} {} {} {} {} {} {} {LY} 5-Nitroisobenzofuran-1,3-dione {} {} {} {} {} {} {} {} {} {} {LY} 5-Nitroisobenzofuran-1,3-dione {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Nitroisobenzofuran-1,3-dione {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Nitroisobenzofuran-1,3-dione {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Nitroisobenzofuran-1,3-dione {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Nitroisobe
Reaxys-RN179682
Chemical Name Translation4-硝基邻苯二甲酸酐
LabNetwork Molecule IDLN00224285
InChIInChI=1S/C8H3NO5/c10-7-5-2-1-4(9(12)13)3-6(5)8(11)14-7/h1-3H
Canonical SMILESO=C1OC(C2=C1C=CC([N+]([O-])=O)=C2)=O
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分类

  • {SNA} Anhydride Monomers, Monomers, Polymer Science, 材料科学
  • {SNA} Anhydride Monomers, Materials Science, Monomers, Polymer Science

相关文献及参考

  • Reagent for the protection of primary amines as the corresponding phthalimides. Cleavage can be carried out with methylhydrazine: Synlett, 63 (1994).

安全信息

RTECSTI3328000
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
Storage condition 2-8°C {LY} 2-8°C Moisture Sensitive {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {}
WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Signal word
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xn Xi Xi,Xn 
TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1 mg/plate
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   11(Suppl 12),1,1988

其他信息

  • Acros Organics:4-硝基邻苯二甲酸酐 4-Nitrophthalic anhydride, 93%(5466-84-2)
  • 用途一:用作荧光染料异硫氰酸荧光素的中间体，也用于测定醇类。
  • 下游产品:异硫氰酸荧光素
  • Sigma Aldrich:5466-84-2(sigmaaldrich)
  • MOL 文件:5466-84-2.mol
  • 方法一:由4-硝基苯二甲酰亚胺水解生成4-硝基邻苯二甲酸（610-27-5），再经脱水而得。将4-硝基苯二甲酰亚胺加入氢氧化钠溶液，加热沸腾15min。用硝酸调整pH6-8，再加硝酸沸腾5min。冷却，过滤，滤液用乙醚提取，提取液经干燥后蒸去乙醚，即析出4-硝基苯二甲酸酐晶体。收率95%。
  • F:10-21
  • TCI Shanghai:4-硝基邻苯二甲酸酐 4-Nitrophthalic Anhydride,>;95.0%(T)(5466-84-2)
  • MSDS 信息:4-Nitrophthalic anhydride(5466-84-2).msds
  • Alfa Aesar:4-硝基邻苯二甲酸酐,tech.90% 4-Nitrophthalic anhydride, tech. 90%(5466-84-2)
  • 敏感性:Moisture Sensitive
  • 上游原料:4-硝基邻苯二甲酸 --> 4-硝基邻苯二甲酰亚胺
  • 4-硝基苯酐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 N0246 4-硝基邻苯二甲酸酐 4-Nitrophthalic Anhydride 25G 1530元 2014/06/02 N0246 4-硝基邻苯二甲酸酐 4-Nitrophthalic Anhydride 100G 4880元 2010/06/21 416130050 4-硝基苯酐 4-Nitrophthalic anhydride 93% 5 GR 801元

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Nitro Compounds 硝基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carboxylic Acid Anhydrides 羧酸酐
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Monomers - Polymer Science
  4. Anhydride Monomers - Monomers
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carbonates
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Monomers
  4. Amine Monomers
  5. Tertiary Amines
  1. Functional Group 官能团索引
  2. carboxylic acid anhydride

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