4-Nitrophthalic anhydride 4-硝基邻苯二甲酸酐

CAS 5466-84-2 MFCD00005922

化学结构图

5466-84-2
SMILES: O=C1OC(=O)c2cc([N+](=O)[O-])ccc21

化学属性

Mol. FormulaC8H3NO5
Mol. Weight193.11
Melting Point116-120 °C
TSCAYes
Solubility水解
Boiling Point197 °C at 8 mmHg
Appearance 无色或灰黄色针状结晶。熔点119℃。溶于热醇、热乙酸和丙酮,不溶于水。

别名和识别编码

Chemical Name4-Nitrophthalic anhydride
MDL NumberMFCD00005922
EC Number226-776-2
CAS Number5466-84-2
Beilstein Registry Number17,486
PubChem Substance ID230976
Synonym 5-Nitroisobenzofuran-1,3-dione {LY} 5-Nitroisobenzofuran-1,3-dione {} {LY} 5-Nitroisobenzofuran-1,3-dione {} {} {LY} 5-Nitroisobenzofuran-1,3-dione {} {} {} {LY} 5-Nitroisobenzofuran-1,3-dione {} {} {} {} {LY} 5-Nitroisobenzofuran-1,3-dione {} {} {} {} {} {LY} 5-Nitroisobenzofuran-1,3-dione {} {} {} {} {} {} {LY} 5-Nitroisobenzofuran-1,3-dione {} {} {} {} {} {} {} {LY} 5-Nitroisobenzofuran-1,3-dione {} {} {} {} {} {} {} {} {LY} 5-Nitroisobenzofuran-1,3-dione {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Nitroisobenzofuran-1,3-dione {} {} {} {} {} {} {} {} {} {} {LY} 5-Nitroisobenzofuran-1,3-dione {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Nitroisobenzofuran-1,3-dione {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Nitroisobenzofuran-1,3-dione {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Nitroisobenzofuran-1,3-dione {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Nitroisobenzofuran-
Reaxys-RN179682
Chemical Name Translation4-硝基邻苯二甲酸酐
LabNetwork Molecule IDLN00224285
InChIInChI=1S/C8H3NO5/c10-7-5-2-1-4(9(12)13)3-6(5)8(11)14-7/h1-3H
Canonical SMILESO=C1OC(C2=C1C=CC([N+]([O-])=O)=C2)=O
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分类

  • {SNA} Anhydride Monomers, Monomers, Polymer Science, 材料科学
  • {SNA} Anhydride Monomers, Materials Science, Monomers, Polymer Science

相关文献及参考

  • Reagent for the protection of primary amines as the corresponding phthalimides. Cleavage can be carried out with methylhydrazine: Synlett, 63 (1994).

安全信息

RTECSTI3328000
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
Storage condition 2-8°C {LY} 2-8°C Moisture Sensitive {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {}
WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Signal word
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xn Xi Xi,Xn
TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1 mg/plate
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   11(Suppl 12),1,1988

其他信息

  • Acros Organics:4-硝基邻苯二甲酸酐 4-Nitrophthalic anhydride, 93%(5466-84-2)
  • 用途一:用作荧光染料异硫氰酸荧光素的中间体,也用于测定醇类。
  • 下游产品:异硫氰酸荧光素
  • Sigma Aldrich:5466-84-2(sigmaaldrich)
  • MOL 文件:5466-84-2.mol
  • 方法一:由4-硝基苯二甲酰亚胺水解生成4-硝基邻苯二甲酸(610-27-5),再经脱水而得。将4-硝基苯二甲酰亚胺加入氢氧化钠溶液,加热沸腾15min。用硝酸调整pH6-8,再加硝酸沸腾5min。冷却,过滤,滤液用乙醚提取,提取液经干燥后蒸去乙醚,即析出4-硝基苯二甲酸酐晶体。收率95%。
  • F:10-21
  • TCI Shanghai:4-硝基邻苯二甲酸酐 4-Nitrophthalic Anhydride,>;95.0%(T)(5466-84-2)
  • MSDS 信息:4-Nitrophthalic anhydride(5466-84-2).msds
  • Alfa Aesar:4-硝基邻苯二甲酸酐,tech.90% 4-Nitrophthalic anhydride, tech. 90%(5466-84-2)
  • 敏感性:Moisture Sensitive
  • 上游原料:4-硝基邻苯二甲酸 --> 4-硝基邻苯二甲酰亚胺
  • 4-硝基苯酐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 N0246 4-硝基邻苯二甲酸酐 4-Nitrophthalic Anhydride 25G 1530元 2014/06/02 N0246 4-硝基邻苯二甲酸酐 4-Nitrophthalic Anhydride 100G 4880元 2010/06/21 416130050 4-硝基苯酐 4-Nitrophthalic anhydride 93% 5 GR 801元

系列性分类


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